6b-Hydroxy-17-methyl-15-(3-nitrophenyl)-6b,7,16,17-tetrahydro-7,14a-methanonaphtho[1′,8′:1,2,3]pyrrolo[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one dichloromethane hemisolvate
In the title compound, C34H25N3O4·0.5CH2Cl2, which crystallized as a dichloromethane hemisolvate, the central 1-methylpyrrolidine ring adopts an envelope conformation with the N atom as the flap. The cyclopentane ring adopts a twist conformation on the CH—CH2 bond and the cyclohexane ring has an env...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-05-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616008282 |
| _version_ | 1828519774461624320 |
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| author | J. M. Joseph Vijayan Viswanathan Devadasan Velmurugan |
| author_facet | J. M. Joseph Vijayan Viswanathan Devadasan Velmurugan |
| author_sort | J. M. Joseph |
| collection | DOAJ |
| description | In the title compound, C34H25N3O4·0.5CH2Cl2, which crystallized as a dichloromethane hemisolvate, the central 1-methylpyrrolidine ring adopts an envelope conformation with the N atom as the flap. The cyclopentane ring adopts a twist conformation on the CH—CH2 bond and the cyclohexane ring has an envelope conformation with the CH2 atom as the flap. The pyrrolidine ring mean plane makes dihedral angles of 40.09 (11), 69.21 (10) and 80.88 (8)° with the mean planes of the cyclopentane, cyclohexane and acenaphthylene rings, respectively. The 3-nitrobenzene ring is inclined to the acenaphthylene and quinoline ring systems by 69.32 (8) and 82.07 (7)°, respectively. There is an intramolecular O—H...N hydrogen bond present forming an S(5) ring motif. In the crystal, molecules are linked by C—H...O hydrogen bonds, forming sheets lying parallel to the ab plane, which enclose R22(18), R22(14), R22(12) and R22(16) ring motifs. |
| first_indexed | 2024-12-11T19:17:55Z |
| format | Article |
| id | doaj.art-972dcc0a434d4bc2a5cc6779450fcc13 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-11T19:17:55Z |
| publishDate | 2016-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-972dcc0a434d4bc2a5cc6779450fcc132022-12-22T00:53:36ZengInternational Union of CrystallographyIUCrData2414-31462016-05-0115x16082810.1107/S2414314616008282su40486b-Hydroxy-17-methyl-15-(3-nitrophenyl)-6b,7,16,17-tetrahydro-7,14a-methanonaphtho[1′,8′:1,2,3]pyrrolo[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one dichloromethane hemisolvateJ. M. Joseph0Vijayan Viswanathan1Devadasan Velmurugan2Centre of Advanced Study in Crystallography and Biophysics, University of Madras, Guindy Campus, Chennai 600 025, IndiaCentre of Advanced Study in Crystallography and Biophysics, University of Madras, Guindy Campus, Chennai 600 025, IndiaCentre of Advanced Study in Crystallography and Biophysics, University of Madras, Guindy Campus, Chennai 600 025, IndiaIn the title compound, C34H25N3O4·0.5CH2Cl2, which crystallized as a dichloromethane hemisolvate, the central 1-methylpyrrolidine ring adopts an envelope conformation with the N atom as the flap. The cyclopentane ring adopts a twist conformation on the CH—CH2 bond and the cyclohexane ring has an envelope conformation with the CH2 atom as the flap. The pyrrolidine ring mean plane makes dihedral angles of 40.09 (11), 69.21 (10) and 80.88 (8)° with the mean planes of the cyclopentane, cyclohexane and acenaphthylene rings, respectively. The 3-nitrobenzene ring is inclined to the acenaphthylene and quinoline ring systems by 69.32 (8) and 82.07 (7)°, respectively. There is an intramolecular O—H...N hydrogen bond present forming an S(5) ring motif. In the crystal, molecules are linked by C—H...O hydrogen bonds, forming sheets lying parallel to the ab plane, which enclose R22(18), R22(14), R22(12) and R22(16) ring motifs.http://scripts.iucr.org/cgi-bin/paper?S2414314616008282crystal structurepyrrolidinesacenaphthyleneC—H...O hydrogen bonding |
| spellingShingle | J. M. Joseph Vijayan Viswanathan Devadasan Velmurugan 6b-Hydroxy-17-methyl-15-(3-nitrophenyl)-6b,7,16,17-tetrahydro-7,14a-methanonaphtho[1′,8′:1,2,3]pyrrolo[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one dichloromethane hemisolvate IUCrData crystal structure pyrrolidines acenaphthylene C—H...O hydrogen bonding |
| title | 6b-Hydroxy-17-methyl-15-(3-nitrophenyl)-6b,7,16,17-tetrahydro-7,14a-methanonaphtho[1′,8′:1,2,3]pyrrolo[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one dichloromethane hemisolvate |
| title_full | 6b-Hydroxy-17-methyl-15-(3-nitrophenyl)-6b,7,16,17-tetrahydro-7,14a-methanonaphtho[1′,8′:1,2,3]pyrrolo[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one dichloromethane hemisolvate |
| title_fullStr | 6b-Hydroxy-17-methyl-15-(3-nitrophenyl)-6b,7,16,17-tetrahydro-7,14a-methanonaphtho[1′,8′:1,2,3]pyrrolo[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one dichloromethane hemisolvate |
| title_full_unstemmed | 6b-Hydroxy-17-methyl-15-(3-nitrophenyl)-6b,7,16,17-tetrahydro-7,14a-methanonaphtho[1′,8′:1,2,3]pyrrolo[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one dichloromethane hemisolvate |
| title_short | 6b-Hydroxy-17-methyl-15-(3-nitrophenyl)-6b,7,16,17-tetrahydro-7,14a-methanonaphtho[1′,8′:1,2,3]pyrrolo[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one dichloromethane hemisolvate |
| title_sort | 6b hydroxy 17 methyl 15 3 nitrophenyl 6b 7 16 17 tetrahydro 7 14a methanonaphtho 1 8 1 2 3 pyrrolo 3 2 8 8a azuleno 5 6 b quinolin 14 15h one dichloromethane hemisolvate |
| topic | crystal structure pyrrolidines acenaphthylene C—H...O hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314616008282 |
| work_keys_str_mv | AT jmjoseph 6bhydroxy17methyl153nitrophenyl6b71617tetrahydro714amethanonaphtho18123pyrrolo3288aazuleno56bquinolin1415honedichloromethanehemisolvate AT vijayanviswanathan 6bhydroxy17methyl153nitrophenyl6b71617tetrahydro714amethanonaphtho18123pyrrolo3288aazuleno56bquinolin1415honedichloromethanehemisolvate AT devadasanvelmurugan 6bhydroxy17methyl153nitrophenyl6b71617tetrahydro714amethanonaphtho18123pyrrolo3288aazuleno56bquinolin1415honedichloromethanehemisolvate |