An Overview of Catalytic Carbonylative Double Cyclization Reactions
This short review is aimed at giving an overview of catalytic carbonylative double cyclization reactions, which are processes in which suitable organic substrates and carbon monoxide are sequentially activated by a promoting a catalyst to form two new cycles with the concomitant incorporation of car...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-06-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/13/6/1025 |
| _version_ | 1797595607320231936 |
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| author | Bartolo Gabriele Raffaella Mancuso Nicola Della Ca’ Lucia Veltri Ida Ziccarelli |
| author_facet | Bartolo Gabriele Raffaella Mancuso Nicola Della Ca’ Lucia Veltri Ida Ziccarelli |
| author_sort | Bartolo Gabriele |
| collection | DOAJ |
| description | This short review is aimed at giving an overview of catalytic carbonylative double cyclization reactions, which are processes in which suitable organic substrates and carbon monoxide are sequentially activated by a promoting a catalyst to form two new cycles with the concomitant incorporation of carbon monoxide as a carbonyl function in the final product. Paradigmatic examples of this powerful synthetic methodology, which allows the one-step synthesis of complex molecular architectures from simple building blocks using the simplest and readily available C-1 unit (CO), are illustrated and discussed. The review is divided into five sections: (1) Introduction, (2) Functionalized Olefinic Substrates, (3) Functionalized Acetylenic Substrates, (4) Functionalized Halides, (5) Conclusions and Future Perspectives. |
| first_indexed | 2024-03-11T02:39:54Z |
| format | Article |
| id | doaj.art-973ac9aef9ed4fcbabfeeb0a601084a3 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-11T02:39:54Z |
| publishDate | 2023-06-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-973ac9aef9ed4fcbabfeeb0a601084a32023-11-18T09:42:38ZengMDPI AGCatalysts2073-43442023-06-01136102510.3390/catal13061025An Overview of Catalytic Carbonylative Double Cyclization ReactionsBartolo Gabriele0Raffaella Mancuso1Nicola Della Ca’2Lucia Veltri3Ida Ziccarelli4Laboratory of Industrial and Synthetic Organic Chemistry (LISOC), Department of Chemistry and Chemical Technologies, University of Calabria, Via P. Bucci 12/C, Arcavacata, 87036 Rende, ItalyLaboratory of Industrial and Synthetic Organic Chemistry (LISOC), Department of Chemistry and Chemical Technologies, University of Calabria, Via P. Bucci 12/C, Arcavacata, 87036 Rende, ItalyDepartment of Chemistry, Life Sciences and Environmental Sustainability (SCVSA) University of Parma, Parco Area delle Scienze, 17/A, 43124 Parma, ItalyLaboratory of Industrial and Synthetic Organic Chemistry (LISOC), Department of Chemistry and Chemical Technologies, University of Calabria, Via P. Bucci 12/C, Arcavacata, 87036 Rende, ItalyLaboratory of Industrial and Synthetic Organic Chemistry (LISOC), Department of Chemistry and Chemical Technologies, University of Calabria, Via P. Bucci 12/C, Arcavacata, 87036 Rende, ItalyThis short review is aimed at giving an overview of catalytic carbonylative double cyclization reactions, which are processes in which suitable organic substrates and carbon monoxide are sequentially activated by a promoting a catalyst to form two new cycles with the concomitant incorporation of carbon monoxide as a carbonyl function in the final product. Paradigmatic examples of this powerful synthetic methodology, which allows the one-step synthesis of complex molecular architectures from simple building blocks using the simplest and readily available C-1 unit (CO), are illustrated and discussed. The review is divided into five sections: (1) Introduction, (2) Functionalized Olefinic Substrates, (3) Functionalized Acetylenic Substrates, (4) Functionalized Halides, (5) Conclusions and Future Perspectives.https://www.mdpi.com/2073-4344/13/6/1025carbonylationcyclizationdouble cyclizationfused heterocyclesheterocyclizationheterocycles |
| spellingShingle | Bartolo Gabriele Raffaella Mancuso Nicola Della Ca’ Lucia Veltri Ida Ziccarelli An Overview of Catalytic Carbonylative Double Cyclization Reactions Catalysts carbonylation cyclization double cyclization fused heterocycles heterocyclization heterocycles |
| title | An Overview of Catalytic Carbonylative Double Cyclization Reactions |
| title_full | An Overview of Catalytic Carbonylative Double Cyclization Reactions |
| title_fullStr | An Overview of Catalytic Carbonylative Double Cyclization Reactions |
| title_full_unstemmed | An Overview of Catalytic Carbonylative Double Cyclization Reactions |
| title_short | An Overview of Catalytic Carbonylative Double Cyclization Reactions |
| title_sort | overview of catalytic carbonylative double cyclization reactions |
| topic | carbonylation cyclization double cyclization fused heterocycles heterocyclization heterocycles |
| url | https://www.mdpi.com/2073-4344/13/6/1025 |
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