Transport of Organic Contaminants in Composite Vertical Cut-Off Wall with Defective HDPE Geomembrane

Soil-bentonite vertical cut-off wall is an emergency technique used for contaminant control in geo-environmental engineering, high-density polyethylene (HDPE) geomembrane (GM) with an extremely low-permeability coefficient is expected to enhance the contaminant barrier effect of the vertical cut-off...

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Main Authors: Hai Lin, Wenzhou Huang, Liangni Wang, Zhanlei Liu
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/14/3031
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author Hai Lin
Wenzhou Huang
Liangni Wang
Zhanlei Liu
author_facet Hai Lin
Wenzhou Huang
Liangni Wang
Zhanlei Liu
author_sort Hai Lin
collection DOAJ
description Soil-bentonite vertical cut-off wall is an emergency technique used for contaminant control in geo-environmental engineering, high-density polyethylene (HDPE) geomembrane (GM) with an extremely low-permeability coefficient is expected to enhance the contaminant barrier effect of the vertical cut-off wall. To evaluate the barrier performance of the composite barrier composed of GM and soil-bentonite mixture towards organic contaminant, while also quantitively revealing the impact of GM defects and placement, a one-dimensional transport model for organic contaminants in composite barrier is solved under semi-infinite boundary conditions. The proposed transport model is validated by numerical simulations using COMSOL Multiphysics 5.4, and the effects of GM defect rate, placement within the composite isolation wall, and contact level with soil-bentonite on contaminant transport behavior are further studied. The results show that as the average frequency of GM defects increases from 2.5 to 50 holes per hectare, the breakthrough time of organic contaminants through composite barrier decreases by almost 70%. Poor contact level between GM and soil-bentonite mixture may reduce the breakthrough time of the composite cut-off wall by 65%. Although the selection of GM placement has limited impact on the transient flux of contaminants, it does affect the total flux of contaminants over a certain period of time. The effects of permeability coefficient, effective diffusion coefficient, distribution coefficient, and hydraulic head of the composite cut-off wall can be considered by the proposed analytical solution, which would provide guidance and reference for the design and service performance evaluation of the composite cut-off wall.
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spelling doaj.art-9740ba58f5bd4096be238bfc769cde5b2023-11-18T21:02:21ZengMDPI AGPolymers2073-43602023-07-011514303110.3390/polym15143031Transport of Organic Contaminants in Composite Vertical Cut-Off Wall with Defective HDPE GeomembraneHai Lin0Wenzhou Huang1Liangni Wang2Zhanlei Liu3School of Infrastructure Engineering, Nanchang University, Nanchang 330031, ChinaSchool of Infrastructure Engineering, Nanchang University, Nanchang 330031, ChinaSchool of Infrastructure Engineering, Nanchang University, Nanchang 330031, ChinaKey Laboratory of Ministry of Education for Geomechanics and Embankment Engineering, Hohai University, Nanjing 210024, ChinaSoil-bentonite vertical cut-off wall is an emergency technique used for contaminant control in geo-environmental engineering, high-density polyethylene (HDPE) geomembrane (GM) with an extremely low-permeability coefficient is expected to enhance the contaminant barrier effect of the vertical cut-off wall. To evaluate the barrier performance of the composite barrier composed of GM and soil-bentonite mixture towards organic contaminant, while also quantitively revealing the impact of GM defects and placement, a one-dimensional transport model for organic contaminants in composite barrier is solved under semi-infinite boundary conditions. The proposed transport model is validated by numerical simulations using COMSOL Multiphysics 5.4, and the effects of GM defect rate, placement within the composite isolation wall, and contact level with soil-bentonite on contaminant transport behavior are further studied. The results show that as the average frequency of GM defects increases from 2.5 to 50 holes per hectare, the breakthrough time of organic contaminants through composite barrier decreases by almost 70%. Poor contact level between GM and soil-bentonite mixture may reduce the breakthrough time of the composite cut-off wall by 65%. Although the selection of GM placement has limited impact on the transient flux of contaminants, it does affect the total flux of contaminants over a certain period of time. The effects of permeability coefficient, effective diffusion coefficient, distribution coefficient, and hydraulic head of the composite cut-off wall can be considered by the proposed analytical solution, which would provide guidance and reference for the design and service performance evaluation of the composite cut-off wall.https://www.mdpi.com/2073-4360/15/14/3031vertical cut-off walldefect of geomembraneorganic contaminantsthe migration behavior of contaminantsanalytical solution
spellingShingle Hai Lin
Wenzhou Huang
Liangni Wang
Zhanlei Liu
Transport of Organic Contaminants in Composite Vertical Cut-Off Wall with Defective HDPE Geomembrane
Polymers
vertical cut-off wall
defect of geomembrane
organic contaminants
the migration behavior of contaminants
analytical solution
title Transport of Organic Contaminants in Composite Vertical Cut-Off Wall with Defective HDPE Geomembrane
title_full Transport of Organic Contaminants in Composite Vertical Cut-Off Wall with Defective HDPE Geomembrane
title_fullStr Transport of Organic Contaminants in Composite Vertical Cut-Off Wall with Defective HDPE Geomembrane
title_full_unstemmed Transport of Organic Contaminants in Composite Vertical Cut-Off Wall with Defective HDPE Geomembrane
title_short Transport of Organic Contaminants in Composite Vertical Cut-Off Wall with Defective HDPE Geomembrane
title_sort transport of organic contaminants in composite vertical cut off wall with defective hdpe geomembrane
topic vertical cut-off wall
defect of geomembrane
organic contaminants
the migration behavior of contaminants
analytical solution
url https://www.mdpi.com/2073-4360/15/14/3031
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AT wenzhouhuang transportoforganiccontaminantsincompositeverticalcutoffwallwithdefectivehdpegeomembrane
AT liangniwang transportoforganiccontaminantsincompositeverticalcutoffwallwithdefectivehdpegeomembrane
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