Interatomic-distance dependence of resonant energy-transfer phenomena
It is well known that interatomic or intermolecular interactions driven by two-center electronic dipole-dipole correlations fall off rapidly with the intersite distance. We show, however, that the effective strength of interatomic reaction channels, which are triggered by a resonant field, can exhib...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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American Physical Society
2020-08-01
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| Series: | Physical Review Research |
| Online Access: | http://doi.org/10.1103/PhysRevResearch.2.033303 |
| _version_ | 1797211347420708864 |
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| author | F. Grüll A. B. Voitkiv C. Müller |
| author_facet | F. Grüll A. B. Voitkiv C. Müller |
| author_sort | F. Grüll |
| collection | DOAJ |
| description | It is well known that interatomic or intermolecular interactions driven by two-center electronic dipole-dipole correlations fall off rapidly with the intersite distance. We show, however, that the effective strength of interatomic reaction channels, which are triggered by a resonant field, can exhibit a nonmonotonous distance dependence, being strongly reduced when the atoms come closer. This surprising result is demonstrated by considering resonant two-center photoionization as an example. Our findings are supported by available experimental data. |
| first_indexed | 2024-04-24T10:25:03Z |
| format | Article |
| id | doaj.art-9741472a6a6f4dd3ac68436109842062 |
| institution | Directory Open Access Journal |
| issn | 2643-1564 |
| language | English |
| last_indexed | 2024-04-24T10:25:03Z |
| publishDate | 2020-08-01 |
| publisher | American Physical Society |
| record_format | Article |
| series | Physical Review Research |
| spelling | doaj.art-9741472a6a6f4dd3ac684361098420622024-04-12T16:59:25ZengAmerican Physical SocietyPhysical Review Research2643-15642020-08-012303330310.1103/PhysRevResearch.2.033303Interatomic-distance dependence of resonant energy-transfer phenomenaF. GrüllA. B. VoitkivC. MüllerIt is well known that interatomic or intermolecular interactions driven by two-center electronic dipole-dipole correlations fall off rapidly with the intersite distance. We show, however, that the effective strength of interatomic reaction channels, which are triggered by a resonant field, can exhibit a nonmonotonous distance dependence, being strongly reduced when the atoms come closer. This surprising result is demonstrated by considering resonant two-center photoionization as an example. Our findings are supported by available experimental data.http://doi.org/10.1103/PhysRevResearch.2.033303 |
| spellingShingle | F. Grüll A. B. Voitkiv C. Müller Interatomic-distance dependence of resonant energy-transfer phenomena Physical Review Research |
| title | Interatomic-distance dependence of resonant energy-transfer phenomena |
| title_full | Interatomic-distance dependence of resonant energy-transfer phenomena |
| title_fullStr | Interatomic-distance dependence of resonant energy-transfer phenomena |
| title_full_unstemmed | Interatomic-distance dependence of resonant energy-transfer phenomena |
| title_short | Interatomic-distance dependence of resonant energy-transfer phenomena |
| title_sort | interatomic distance dependence of resonant energy transfer phenomena |
| url | http://doi.org/10.1103/PhysRevResearch.2.033303 |
| work_keys_str_mv | AT fgrull interatomicdistancedependenceofresonantenergytransferphenomena AT abvoitkiv interatomicdistancedependenceofresonantenergytransferphenomena AT cmuller interatomicdistancedependenceofresonantenergytransferphenomena |