4,5-Bis(4-fluorophenyl)-5-hydroxy-3-(2-methylpropanoyl)-1-phenylpyrrolidin-2-one
The title compound, C26H23F2NO3, was synthesized by the reaction of 2-(4-fluorobenzylidene)-4-methyl-3-oxo-N-phenylpentanamide and 4-fluorobenzaldehyde. The dihedral angles between the mean plane through the pyrrolidine ring (nearly planar; maximum deviation of 0.145 Å for...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811008786 |
| _version_ | 1818906435857154048 |
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| author | Jian-Ying Huang Fengyan Zhou |
| author_facet | Jian-Ying Huang Fengyan Zhou |
| author_sort | Jian-Ying Huang |
| collection | DOAJ |
| description | The title compound, C26H23F2NO3, was synthesized by the reaction of 2-(4-fluorobenzylidene)-4-methyl-3-oxo-N-phenylpentanamide and 4-fluorobenzaldehyde. The dihedral angles between the mean plane through the pyrrolidine ring (nearly planar; maximum deviation of 0.145 Å for the C atom bearing the hydroxy group) with the phenyl and benzene rings are 37.22 (7), 51.88 (7) and 87.64 (9)°, respectively. The pyyolidine ring is near coplaner, with max offset of 0.145 A for C19 atom.uff09 In the crystal, molecules are linked by pairs of O—H...O hydrogen bonds into inversion dimers, which are further assembled into chains parallel to the b axis by weak C—H...O hydrogen bonds. |
| first_indexed | 2024-12-19T21:39:11Z |
| format | Article |
| id | doaj.art-9782043ee4da43b0aeca270087a12153 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:39:11Z |
| publishDate | 2011-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9782043ee4da43b0aeca270087a121532022-12-21T20:04:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674o873o87410.1107/S16005368110087864,5-Bis(4-fluorophenyl)-5-hydroxy-3-(2-methylpropanoyl)-1-phenylpyrrolidin-2-oneJian-Ying HuangFengyan ZhouThe title compound, C26H23F2NO3, was synthesized by the reaction of 2-(4-fluorobenzylidene)-4-methyl-3-oxo-N-phenylpentanamide and 4-fluorobenzaldehyde. The dihedral angles between the mean plane through the pyrrolidine ring (nearly planar; maximum deviation of 0.145 Å for the C atom bearing the hydroxy group) with the phenyl and benzene rings are 37.22 (7), 51.88 (7) and 87.64 (9)°, respectively. The pyyolidine ring is near coplaner, with max offset of 0.145 A for C19 atom.uff09 In the crystal, molecules are linked by pairs of O—H...O hydrogen bonds into inversion dimers, which are further assembled into chains parallel to the b axis by weak C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811008786 |
| spellingShingle | Jian-Ying Huang Fengyan Zhou 4,5-Bis(4-fluorophenyl)-5-hydroxy-3-(2-methylpropanoyl)-1-phenylpyrrolidin-2-one Acta Crystallographica Section E |
| title | 4,5-Bis(4-fluorophenyl)-5-hydroxy-3-(2-methylpropanoyl)-1-phenylpyrrolidin-2-one |
| title_full | 4,5-Bis(4-fluorophenyl)-5-hydroxy-3-(2-methylpropanoyl)-1-phenylpyrrolidin-2-one |
| title_fullStr | 4,5-Bis(4-fluorophenyl)-5-hydroxy-3-(2-methylpropanoyl)-1-phenylpyrrolidin-2-one |
| title_full_unstemmed | 4,5-Bis(4-fluorophenyl)-5-hydroxy-3-(2-methylpropanoyl)-1-phenylpyrrolidin-2-one |
| title_short | 4,5-Bis(4-fluorophenyl)-5-hydroxy-3-(2-methylpropanoyl)-1-phenylpyrrolidin-2-one |
| title_sort | 4 5 bis 4 fluorophenyl 5 hydroxy 3 2 methylpropanoyl 1 phenylpyrrolidin 2 one |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811008786 |
| work_keys_str_mv | AT jianyinghuang 45bis4fluorophenyl5hydroxy32methylpropanoyl1phenylpyrrolidin2one AT fengyanzhou 45bis4fluorophenyl5hydroxy32methylpropanoyl1phenylpyrrolidin2one |