Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification
Two-dimensional graphene oxide (GO)-based lamellar membranes have been widely developed for desalination, water purification, gas separation, and pervaporation. However, membranes with a well-organized multilayer structure and controlled pore size remain a challenge. Herein, an easy and efficient me...
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MDPI AG
2023-01-01
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author | Faheeda Soomro Fida Hussain Memon Muhammad Ali Khan Muzaffar Iqbal Aliya Ibrar Ayaz Ali Memon Jong Hwan Lim Kyung Hyon Choi Khalid Hussain Thebo |
author_facet | Faheeda Soomro Fida Hussain Memon Muhammad Ali Khan Muzaffar Iqbal Aliya Ibrar Ayaz Ali Memon Jong Hwan Lim Kyung Hyon Choi Khalid Hussain Thebo |
author_sort | Faheeda Soomro |
collection | DOAJ |
description | Two-dimensional graphene oxide (GO)-based lamellar membranes have been widely developed for desalination, water purification, gas separation, and pervaporation. However, membranes with a well-organized multilayer structure and controlled pore size remain a challenge. Herein, an easy and efficient method is used to fabricate MoO<sub>2</sub>@GO and WO<sub>3</sub>@GO nanocomposite membranes with controlled structure and interlayer spacing. Such membranes show good separation for salt and heavy metal ions due to the intensive stacking interaction and electrostatic attraction. The as-prepared composite membranes showed high rejection rates (˃70%) toward small metal ions such as sodium (Na<sup>+</sup>) and magnesium (Mg<sup>2+</sup>) ions. In addition, both membranes also showed high rejection rates ˃99% for nickel (Ni<sup>2+</sup>) and lead (Pb<sup>2+</sup>) ions with good water permeability of 275 ± 10 L m<sup>−2</sup> h<sup>−1</sup> bar<sup>−1</sup>. We believe that our fabricated membranes will have a bright future in next generation desalination and water purification membranes. |
first_indexed | 2024-03-09T11:43:42Z |
format | Article |
id | doaj.art-978846a82d9341fd9a3f2abf72a873e2 |
institution | Directory Open Access Journal |
issn | 2077-0375 |
language | English |
last_indexed | 2024-03-09T11:43:42Z |
publishDate | 2023-01-01 |
publisher | MDPI AG |
record_format | Article |
series | Membranes |
spelling | doaj.art-978846a82d9341fd9a3f2abf72a873e22023-11-30T23:26:43ZengMDPI AGMembranes2077-03752023-01-011316410.3390/membranes13010064Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water PurificationFaheeda Soomro0Fida Hussain Memon1Muhammad Ali Khan2Muzaffar Iqbal3Aliya Ibrar4Ayaz Ali Memon5Jong Hwan Lim6Kyung Hyon Choi7Khalid Hussain Thebo8Department of Human and Rehabilitation Sciences, Faculty of Education, Linguists and Sciences, The Begum Nusrat Bhutto Women University, Rohri Bypass, Sukkur 65200, PakistanDepartment of Mechatronics Engineering, Jeju National University, Jeju 63243, Republic of KoreaInstitute of Chemical Sciences, Bahauddin Zakriya University, Multan 60800, PakistanDepartment of Chemistry, Faculty of Physical and Applied Sciences, The University of Haripur KPK, Haripur 22620, PakistanDepartment of Chemistry, Faculty of Physical and Applied Sciences, The University of Haripur KPK, Haripur 22620, PakistanNational Centre of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080, PakistanDepartment of Mechatronics Engineering, Jeju National University, Jeju 63243, Republic of KoreaDepartment of Mechatronics Engineering, Jeju National University, Jeju 63243, Republic of KoreaInstitute of Metal Research, Chinese Academy of Sciences (CAS), Shenyang 110016, ChinaTwo-dimensional graphene oxide (GO)-based lamellar membranes have been widely developed for desalination, water purification, gas separation, and pervaporation. However, membranes with a well-organized multilayer structure and controlled pore size remain a challenge. Herein, an easy and efficient method is used to fabricate MoO<sub>2</sub>@GO and WO<sub>3</sub>@GO nanocomposite membranes with controlled structure and interlayer spacing. Such membranes show good separation for salt and heavy metal ions due to the intensive stacking interaction and electrostatic attraction. The as-prepared composite membranes showed high rejection rates (˃70%) toward small metal ions such as sodium (Na<sup>+</sup>) and magnesium (Mg<sup>2+</sup>) ions. In addition, both membranes also showed high rejection rates ˃99% for nickel (Ni<sup>2+</sup>) and lead (Pb<sup>2+</sup>) ions with good water permeability of 275 ± 10 L m<sup>−2</sup> h<sup>−1</sup> bar<sup>−1</sup>. We believe that our fabricated membranes will have a bright future in next generation desalination and water purification membranes.https://www.mdpi.com/2077-0375/13/1/64graphene oxidemembranesdesalinationseparationpermeability |
spellingShingle | Faheeda Soomro Fida Hussain Memon Muhammad Ali Khan Muzaffar Iqbal Aliya Ibrar Ayaz Ali Memon Jong Hwan Lim Kyung Hyon Choi Khalid Hussain Thebo Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification Membranes graphene oxide membranes desalination separation permeability |
title | Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification |
title_full | Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification |
title_fullStr | Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification |
title_full_unstemmed | Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification |
title_short | Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification |
title_sort | ultrathin graphene oxide based nanocomposite membranes for water purification |
topic | graphene oxide membranes desalination separation permeability |
url | https://www.mdpi.com/2077-0375/13/1/64 |
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