Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification

Two-dimensional graphene oxide (GO)-based lamellar membranes have been widely developed for desalination, water purification, gas separation, and pervaporation. However, membranes with a well-organized multilayer structure and controlled pore size remain a challenge. Herein, an easy and efficient me...

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Main Authors: Faheeda Soomro, Fida Hussain Memon, Muhammad Ali Khan, Muzaffar Iqbal, Aliya Ibrar, Ayaz Ali Memon, Jong Hwan Lim, Kyung Hyon Choi, Khalid Hussain Thebo
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/13/1/64
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author Faheeda Soomro
Fida Hussain Memon
Muhammad Ali Khan
Muzaffar Iqbal
Aliya Ibrar
Ayaz Ali Memon
Jong Hwan Lim
Kyung Hyon Choi
Khalid Hussain Thebo
author_facet Faheeda Soomro
Fida Hussain Memon
Muhammad Ali Khan
Muzaffar Iqbal
Aliya Ibrar
Ayaz Ali Memon
Jong Hwan Lim
Kyung Hyon Choi
Khalid Hussain Thebo
author_sort Faheeda Soomro
collection DOAJ
description Two-dimensional graphene oxide (GO)-based lamellar membranes have been widely developed for desalination, water purification, gas separation, and pervaporation. However, membranes with a well-organized multilayer structure and controlled pore size remain a challenge. Herein, an easy and efficient method is used to fabricate MoO<sub>2</sub>@GO and WO<sub>3</sub>@GO nanocomposite membranes with controlled structure and interlayer spacing. Such membranes show good separation for salt and heavy metal ions due to the intensive stacking interaction and electrostatic attraction. The as-prepared composite membranes showed high rejection rates (˃70%) toward small metal ions such as sodium (Na<sup>+</sup>) and magnesium (Mg<sup>2+</sup>) ions. In addition, both membranes also showed high rejection rates ˃99% for nickel (Ni<sup>2+</sup>) and lead (Pb<sup>2+</sup>) ions with good water permeability of 275 ± 10 L m<sup>−2</sup> h<sup>−1</sup> bar<sup>−1</sup>. We believe that our fabricated membranes will have a bright future in next generation desalination and water purification membranes.
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spelling doaj.art-978846a82d9341fd9a3f2abf72a873e22023-11-30T23:26:43ZengMDPI AGMembranes2077-03752023-01-011316410.3390/membranes13010064Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water PurificationFaheeda Soomro0Fida Hussain Memon1Muhammad Ali Khan2Muzaffar Iqbal3Aliya Ibrar4Ayaz Ali Memon5Jong Hwan Lim6Kyung Hyon Choi7Khalid Hussain Thebo8Department of Human and Rehabilitation Sciences, Faculty of Education, Linguists and Sciences, The Begum Nusrat Bhutto Women University, Rohri Bypass, Sukkur 65200, PakistanDepartment of Mechatronics Engineering, Jeju National University, Jeju 63243, Republic of KoreaInstitute of Chemical Sciences, Bahauddin Zakriya University, Multan 60800, PakistanDepartment of Chemistry, Faculty of Physical and Applied Sciences, The University of Haripur KPK, Haripur 22620, PakistanDepartment of Chemistry, Faculty of Physical and Applied Sciences, The University of Haripur KPK, Haripur 22620, PakistanNational Centre of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080, PakistanDepartment of Mechatronics Engineering, Jeju National University, Jeju 63243, Republic of KoreaDepartment of Mechatronics Engineering, Jeju National University, Jeju 63243, Republic of KoreaInstitute of Metal Research, Chinese Academy of Sciences (CAS), Shenyang 110016, ChinaTwo-dimensional graphene oxide (GO)-based lamellar membranes have been widely developed for desalination, water purification, gas separation, and pervaporation. However, membranes with a well-organized multilayer structure and controlled pore size remain a challenge. Herein, an easy and efficient method is used to fabricate MoO<sub>2</sub>@GO and WO<sub>3</sub>@GO nanocomposite membranes with controlled structure and interlayer spacing. Such membranes show good separation for salt and heavy metal ions due to the intensive stacking interaction and electrostatic attraction. The as-prepared composite membranes showed high rejection rates (˃70%) toward small metal ions such as sodium (Na<sup>+</sup>) and magnesium (Mg<sup>2+</sup>) ions. In addition, both membranes also showed high rejection rates ˃99% for nickel (Ni<sup>2+</sup>) and lead (Pb<sup>2+</sup>) ions with good water permeability of 275 ± 10 L m<sup>−2</sup> h<sup>−1</sup> bar<sup>−1</sup>. We believe that our fabricated membranes will have a bright future in next generation desalination and water purification membranes.https://www.mdpi.com/2077-0375/13/1/64graphene oxidemembranesdesalinationseparationpermeability
spellingShingle Faheeda Soomro
Fida Hussain Memon
Muhammad Ali Khan
Muzaffar Iqbal
Aliya Ibrar
Ayaz Ali Memon
Jong Hwan Lim
Kyung Hyon Choi
Khalid Hussain Thebo
Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification
Membranes
graphene oxide
membranes
desalination
separation
permeability
title Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification
title_full Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification
title_fullStr Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification
title_full_unstemmed Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification
title_short Ultrathin Graphene Oxide-Based Nanocomposite Membranes for Water Purification
title_sort ultrathin graphene oxide based nanocomposite membranes for water purification
topic graphene oxide
membranes
desalination
separation
permeability
url https://www.mdpi.com/2077-0375/13/1/64
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AT muzaffariqbal ultrathingrapheneoxidebasednanocompositemembranesforwaterpurification
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