Adsorption Method for the Remediation of Brilliant Green Dye Using Halloysite Nanotube: Isotherm, Kinetic and Modeling Studies
The first-ever use of halloysite nanotube (HNT), a relatively low-cost nanomaterial abundantly available with minor toxicity for removing brilliant green dye from aqueous media, is reported. The factors affecting adsorption were studied by assessing the adsorption capacity, kinetics, and equilibrium...
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MDPI AG
2021-08-01
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| author | Shareefraza J. Ukkund Prasad Puthiyillam Hashim M. Alshehri Marjan Goodarzi Syed Noeman Taqui Ali E. Anqi Mohammad Reza Safaei Masood Ashraf Ali Usman Taqui Syed Rayees Afzal Mir Ashraf Elfasakhany Emad M. Eed Md Irfanul Haque Siddiqui Imran Mokashi Manzoore Elahi M. Soudagar |
| author_facet | Shareefraza J. Ukkund Prasad Puthiyillam Hashim M. Alshehri Marjan Goodarzi Syed Noeman Taqui Ali E. Anqi Mohammad Reza Safaei Masood Ashraf Ali Usman Taqui Syed Rayees Afzal Mir Ashraf Elfasakhany Emad M. Eed Md Irfanul Haque Siddiqui Imran Mokashi Manzoore Elahi M. Soudagar |
| author_sort | Shareefraza J. Ukkund |
| collection | DOAJ |
| description | The first-ever use of halloysite nanotube (HNT), a relatively low-cost nanomaterial abundantly available with minor toxicity for removing brilliant green dye from aqueous media, is reported. The factors affecting adsorption were studied by assessing the adsorption capacity, kinetics, and equilibrium thermodynamic properties. All the experiments were designed at a pH level of around 7. The Redlich-Peterson isotherm model fits best amongst the nine isotherm models studied. The kinetic studies data confirmed a pseudo model of the second order. Robotic investigations propose a rate-controlling advance being overwhelmed by intraparticle dispersion. The adsorbent features were interpreted using infrared spectroscopy and electron microscopy. Process optimization was carried out using Response Surface Methodology (RSM) through a dual section Fractional Factorial Experimental Design to contemplate the impact of boundaries on the course of adsorption. The examination of fluctuation (ANOVA) was utilized to consider the joined impact of the boundaries. The possibilities of the use of dye adsorbing HNT (“sludge”) for the fabrication of the composites using plastic waste are suggested. |
| first_indexed | 2024-03-10T08:15:49Z |
| format | Article |
| id | doaj.art-97a9b070869348608d1f95f70bfdd4c3 |
| institution | Directory Open Access Journal |
| issn | 2076-3417 |
| language | English |
| last_indexed | 2024-03-10T08:15:49Z |
| publishDate | 2021-08-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Applied Sciences |
| spelling | doaj.art-97a9b070869348608d1f95f70bfdd4c32023-11-22T10:21:22ZengMDPI AGApplied Sciences2076-34172021-08-011117808810.3390/app11178088Adsorption Method for the Remediation of Brilliant Green Dye Using Halloysite Nanotube: Isotherm, Kinetic and Modeling StudiesShareefraza J. Ukkund0Prasad Puthiyillam1Hashim M. Alshehri2Marjan Goodarzi3Syed Noeman Taqui4Ali E. Anqi5Mohammad Reza Safaei6Masood Ashraf Ali7Usman Taqui Syed8Rayees Afzal Mir9Ashraf Elfasakhany10Emad M. Eed11Md Irfanul Haque Siddiqui12Imran Mokashi13Manzoore Elahi M. Soudagar14Department of Nano-Biotechnology, College of Engineering and Technology, Srinivas University, Mangalore 574146, IndiaDepartment of Nano-Biotechnology, College of Engineering and Technology, Srinivas University, Mangalore 574146, IndiaDepartment of Mathematics, Faculty of Science, King Abdulaziz University, Jeddah 21521, Saudi ArabiaDepartment of Mathematics, Faculty of Science, King Abdulaziz University, Jeddah 21521, Saudi ArabiaCSIR-Central Food Technological Research Institute, Mysore 570020, IndiaDepartment of Mechanical Engineering, College of Engineering, King Khalid University, Abha 61421, Saudi ArabiaDepartment of Mechanical Engineering, Florida International University, Miami, FL 33174, USADepartment of Mechanical Engineering, College of Engineering, Prince Sattam Bin Abdulaziz University, Al Kharj 16273, Saudi ArabiaLAQV-REQUIMTE, Department of Chemistry, Faculty of Science and Technology, NOVA University of Lisbon, 2829-516 Caparica, PortugalGlocal School of Agricultural Science, Glocal University, Mirzapur Pole, Saharanpur 247121, IndiaMechanical Engineering Department, College of Engineering, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Clinical Laboratory Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi ArabiaDepartment of Mechanical Engineering, College of Engineering, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Mechanical Engineering, Bearys Institute of Technology, Visvesvaraya Technological University, Mangaluru 575001, IndiaDepartment of Mechanical Engineering, School of Technology, Glocal University, Delhi-Yamunotri Marg, SH-57, Mirzapur Pole, Saharanpur 247121, IndiaThe first-ever use of halloysite nanotube (HNT), a relatively low-cost nanomaterial abundantly available with minor toxicity for removing brilliant green dye from aqueous media, is reported. The factors affecting adsorption were studied by assessing the adsorption capacity, kinetics, and equilibrium thermodynamic properties. All the experiments were designed at a pH level of around 7. The Redlich-Peterson isotherm model fits best amongst the nine isotherm models studied. The kinetic studies data confirmed a pseudo model of the second order. Robotic investigations propose a rate-controlling advance being overwhelmed by intraparticle dispersion. The adsorbent features were interpreted using infrared spectroscopy and electron microscopy. Process optimization was carried out using Response Surface Methodology (RSM) through a dual section Fractional Factorial Experimental Design to contemplate the impact of boundaries on the course of adsorption. The examination of fluctuation (ANOVA) was utilized to consider the joined impact of the boundaries. The possibilities of the use of dye adsorbing HNT (“sludge”) for the fabrication of the composites using plastic waste are suggested.https://www.mdpi.com/2076-3417/11/17/8088halloysite nanotubebrilliant greenadsorption studieskineticsmodeling |
| spellingShingle | Shareefraza J. Ukkund Prasad Puthiyillam Hashim M. Alshehri Marjan Goodarzi Syed Noeman Taqui Ali E. Anqi Mohammad Reza Safaei Masood Ashraf Ali Usman Taqui Syed Rayees Afzal Mir Ashraf Elfasakhany Emad M. Eed Md Irfanul Haque Siddiqui Imran Mokashi Manzoore Elahi M. Soudagar Adsorption Method for the Remediation of Brilliant Green Dye Using Halloysite Nanotube: Isotherm, Kinetic and Modeling Studies Applied Sciences halloysite nanotube brilliant green adsorption studies kinetics modeling |
| title | Adsorption Method for the Remediation of Brilliant Green Dye Using Halloysite Nanotube: Isotherm, Kinetic and Modeling Studies |
| title_full | Adsorption Method for the Remediation of Brilliant Green Dye Using Halloysite Nanotube: Isotherm, Kinetic and Modeling Studies |
| title_fullStr | Adsorption Method for the Remediation of Brilliant Green Dye Using Halloysite Nanotube: Isotherm, Kinetic and Modeling Studies |
| title_full_unstemmed | Adsorption Method for the Remediation of Brilliant Green Dye Using Halloysite Nanotube: Isotherm, Kinetic and Modeling Studies |
| title_short | Adsorption Method for the Remediation of Brilliant Green Dye Using Halloysite Nanotube: Isotherm, Kinetic and Modeling Studies |
| title_sort | adsorption method for the remediation of brilliant green dye using halloysite nanotube isotherm kinetic and modeling studies |
| topic | halloysite nanotube brilliant green adsorption studies kinetics modeling |
| url | https://www.mdpi.com/2076-3417/11/17/8088 |
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