Catalytic Dehydrogenation of para-Diethyl Benzene to para-Divinyl Benzene over Iron Oxide Supported Catalyst
The vapor-phase catalytic dehydrogenation of para-diethyl benzene (PDEB) to para-divinyl benzene (PDVB) with super-heated steam as a diluent was investigated using alumina supported iron oxide catalyst system. During the catalytic dehydrogenation reaction, ethyl styrene (EST) and thermal cracking pr...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2019-08-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
| Subjects: | |
| Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/2963 |
| _version_ | 1797677835738939392 |
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| author | Vivek Kumar Srivastava Nagesh Sharma Raksh V. Jasra |
| author_facet | Vivek Kumar Srivastava Nagesh Sharma Raksh V. Jasra |
| author_sort | Vivek Kumar Srivastava |
| collection | DOAJ |
| description | The vapor-phase catalytic dehydrogenation of para-diethyl benzene (PDEB) to para-divinyl benzene (PDVB) with super-heated steam as a diluent was investigated using alumina supported iron oxide catalyst system. During the catalytic dehydrogenation reaction, ethyl styrene (EST) and thermal cracking products were observed as side products. It was found that various reaction parameters influence the rate of dehydrogenation reaction. However, the reaction is favored by high temperature and low reaction pressure. Moreover, addition of potassium into iron-oxide catalyst acts as a promoter and thereby increases the efficiency of the catalyst. The conversion of PDEB and yield of PDVB also increases as the Water/PDEB flow ratio increases. |
| first_indexed | 2024-03-11T22:50:54Z |
| format | Article |
| id | doaj.art-97bea28c2a81473997386e8ff40ab4fc |
| institution | Directory Open Access Journal |
| issn | 1978-2993 |
| language | English |
| last_indexed | 2024-03-11T22:50:54Z |
| publishDate | 2019-08-01 |
| publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
| record_format | Article |
| series | Bulletin of Chemical Reaction Engineering & Catalysis |
| spelling | doaj.art-97bea28c2a81473997386e8ff40ab4fc2023-09-22T03:42:21ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932019-08-0114230130810.9767/bcrec.14.2.2963.301-3082038Catalytic Dehydrogenation of para-Diethyl Benzene to para-Divinyl Benzene over Iron Oxide Supported CatalystVivek Kumar Srivastava0Nagesh Sharma1Raksh V. Jasra2Reliance Research and Development Center, Vadodara Manufacturing Division, Reliance Industries Ltd., Vadodara-391346, Gujarat, IndiaReliance Research and Development Center, Vadodara Manufacturing Division, Reliance Industries Ltd., Vadodara-391346, Gujarat, IndiaReliance Research and Development Center, Vadodara Manufacturing Division, Reliance Industries Ltd., Vadodara-391346, Gujarat, IndiaThe vapor-phase catalytic dehydrogenation of para-diethyl benzene (PDEB) to para-divinyl benzene (PDVB) with super-heated steam as a diluent was investigated using alumina supported iron oxide catalyst system. During the catalytic dehydrogenation reaction, ethyl styrene (EST) and thermal cracking products were observed as side products. It was found that various reaction parameters influence the rate of dehydrogenation reaction. However, the reaction is favored by high temperature and low reaction pressure. Moreover, addition of potassium into iron-oxide catalyst acts as a promoter and thereby increases the efficiency of the catalyst. The conversion of PDEB and yield of PDVB also increases as the Water/PDEB flow ratio increases.https://journal.bcrec.id/index.php/bcrec/article/view/2963dehydrogenationpara-diethyl benzenepara-divinyl benzenesupported iron catalyst |
| spellingShingle | Vivek Kumar Srivastava Nagesh Sharma Raksh V. Jasra Catalytic Dehydrogenation of para-Diethyl Benzene to para-Divinyl Benzene over Iron Oxide Supported Catalyst Bulletin of Chemical Reaction Engineering & Catalysis dehydrogenation para-diethyl benzene para-divinyl benzene supported iron catalyst |
| title | Catalytic Dehydrogenation of para-Diethyl Benzene to para-Divinyl Benzene over Iron Oxide Supported Catalyst |
| title_full | Catalytic Dehydrogenation of para-Diethyl Benzene to para-Divinyl Benzene over Iron Oxide Supported Catalyst |
| title_fullStr | Catalytic Dehydrogenation of para-Diethyl Benzene to para-Divinyl Benzene over Iron Oxide Supported Catalyst |
| title_full_unstemmed | Catalytic Dehydrogenation of para-Diethyl Benzene to para-Divinyl Benzene over Iron Oxide Supported Catalyst |
| title_short | Catalytic Dehydrogenation of para-Diethyl Benzene to para-Divinyl Benzene over Iron Oxide Supported Catalyst |
| title_sort | catalytic dehydrogenation of para diethyl benzene to para divinyl benzene over iron oxide supported catalyst |
| topic | dehydrogenation para-diethyl benzene para-divinyl benzene supported iron catalyst |
| url | https://journal.bcrec.id/index.php/bcrec/article/view/2963 |
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