Selective sulfonylation and isonitrilation of para-quinone methides employing TosMIC as a source of sulfonyl group or isonitrile group

Selective sulfonylation and isonitrilation of para-quinone methides employing TosMIC as a source of sulfonyl group or isonitrile group

Chemoselective sulfonylation and isonitrilation reactions for the divergent synthesis of valuable diarylmethyl sulfones and isonitrile diarylmethanes starting from easy-to-synthesize para-quinone methides (p-QMs) and commercially abundant p-toluenesulfonylmethyl isocyanide (TosMIC) by using respecti...

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Bibliographic Details
Main Authors: Chuanhua Qu, Run Huang, Yong Li, Tong Liu, Yuan Chen, Guiting Song
Format: Article
Language:English
Published: Beilstein-Institut 2021-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
chemoselective reactions
diarylmethyl sulfones
dual role
isonitrile diarylmethane
synthetic utility
Online Access:https://doi.org/10.3762/bjoc.17.193

Internet

https://doi.org/10.3762/bjoc.17.193

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