Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione

In the title compound, C27H24N2O3, the dihedral angle between the mean planes of the dihydrofuran and 3,4-dihydroquinoline ring systems is 70.65 (9)°. The dihydrofuran ring adopts an envelope conformation with the C atom adjacent to the methylene C atom of the pyrrolidine ring as the flap. The five-...

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Main Authors: M. P. Savithri, M. Suresh, R. Raghunathan, R. Raja, A. SubbiahPandi
Format: Article
Language:English
Published: International Union of Crystallography 2015-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015002017
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author M. P. Savithri
M. Suresh
R. Raghunathan
R. Raja
A. SubbiahPandi
author_facet M. P. Savithri
M. Suresh
R. Raghunathan
R. Raja
A. SubbiahPandi
author_sort M. P. Savithri
collection DOAJ
description In the title compound, C27H24N2O3, the dihedral angle between the mean planes of the dihydrofuran and 3,4-dihydroquinoline ring systems is 70.65 (9)°. The dihydrofuran ring adopts an envelope conformation with the C atom adjacent to the methylene C atom of the pyrrolidine ring as the flap. The five-membered pyrrolidine ring adopts a twist conformation on the N—C(tetrasubstituted) bond. In the crystal, molecules are linked via pairs of N—H...O hydrogen bonds, forming inversion dimers with an R22(8) ring motif. The dimers are linked via pairs of C—H...O hydrogen bonds, forming ribbons enclosing R22(12) ring motifs lying in a plane parallel to (01-1).
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spelling doaj.art-97d9288bb9a54db7b98aaebb7338084f2022-12-22T04:09:40ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-03-01713o150o15110.1107/S2056989015002017su5066Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dioneM. P. Savithri0M. Suresh1R. Raghunathan2R. Raja3A. SubbiahPandi4Department of Physics, Queen Mary's College (Autonomous), Chennai 600 004, IndiaDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, IndiaDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, IndiaDepartment of Physics, Presidency College (Autonomous), Chennai 600 005, IndiaDepartment of Physics, Presidency College (Autonomous), Chennai 600 005, IndiaIn the title compound, C27H24N2O3, the dihedral angle between the mean planes of the dihydrofuran and 3,4-dihydroquinoline ring systems is 70.65 (9)°. The dihydrofuran ring adopts an envelope conformation with the C atom adjacent to the methylene C atom of the pyrrolidine ring as the flap. The five-membered pyrrolidine ring adopts a twist conformation on the N—C(tetrasubstituted) bond. In the crystal, molecules are linked via pairs of N—H...O hydrogen bonds, forming inversion dimers with an R22(8) ring motif. The dimers are linked via pairs of C—H...O hydrogen bonds, forming ribbons enclosing R22(12) ring motifs lying in a plane parallel to (01-1).http://scripts.iucr.org/cgi-bin/paper?S2056989015002017crystal structurequinolinepyrrolidinehydrogen bonds
spellingShingle M. P. Savithri
M. Suresh
R. Raghunathan
R. Raja
A. SubbiahPandi
Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
quinoline
pyrrolidine
hydrogen bonds
title Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione
title_full Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione
title_fullStr Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione
title_full_unstemmed Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione
title_short Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione
title_sort crystal structure of 15 naphthalen 1 yl 7 7a 8 9 10 11 hexahydro 6a 12a methanoepoxymethano indolizino 2 3 c quinoline 6 13 5h dione
topic crystal structure
quinoline
pyrrolidine
hydrogen bonds
url http://scripts.iucr.org/cgi-bin/paper?S2056989015002017
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