Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione
In the title compound, C27H24N2O3, the dihedral angle between the mean planes of the dihydrofuran and 3,4-dihydroquinoline ring systems is 70.65 (9)°. The dihydrofuran ring adopts an envelope conformation with the C atom adjacent to the methylene C atom of the pyrrolidine ring as the flap. The five-...
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International Union of Crystallography
2015-03-01
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Series: | Acta Crystallographica Section E: Crystallographic Communications |
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Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015002017 |
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author | M. P. Savithri M. Suresh R. Raghunathan R. Raja A. SubbiahPandi |
author_facet | M. P. Savithri M. Suresh R. Raghunathan R. Raja A. SubbiahPandi |
author_sort | M. P. Savithri |
collection | DOAJ |
description | In the title compound, C27H24N2O3, the dihedral angle between the mean planes of the dihydrofuran and 3,4-dihydroquinoline ring systems is 70.65 (9)°. The dihydrofuran ring adopts an envelope conformation with the C atom adjacent to the methylene C atom of the pyrrolidine ring as the flap. The five-membered pyrrolidine ring adopts a twist conformation on the N—C(tetrasubstituted) bond. In the crystal, molecules are linked via pairs of N—H...O hydrogen bonds, forming inversion dimers with an R22(8) ring motif. The dimers are linked via pairs of C—H...O hydrogen bonds, forming ribbons enclosing R22(12) ring motifs lying in a plane parallel to (01-1). |
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issn | 2056-9890 |
language | English |
last_indexed | 2024-04-11T18:24:22Z |
publishDate | 2015-03-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E: Crystallographic Communications |
spelling | doaj.art-97d9288bb9a54db7b98aaebb7338084f2022-12-22T04:09:40ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-03-01713o150o15110.1107/S2056989015002017su5066Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dioneM. P. Savithri0M. Suresh1R. Raghunathan2R. Raja3A. SubbiahPandi4Department of Physics, Queen Mary's College (Autonomous), Chennai 600 004, IndiaDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, IndiaDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, IndiaDepartment of Physics, Presidency College (Autonomous), Chennai 600 005, IndiaDepartment of Physics, Presidency College (Autonomous), Chennai 600 005, IndiaIn the title compound, C27H24N2O3, the dihedral angle between the mean planes of the dihydrofuran and 3,4-dihydroquinoline ring systems is 70.65 (9)°. The dihydrofuran ring adopts an envelope conformation with the C atom adjacent to the methylene C atom of the pyrrolidine ring as the flap. The five-membered pyrrolidine ring adopts a twist conformation on the N—C(tetrasubstituted) bond. In the crystal, molecules are linked via pairs of N—H...O hydrogen bonds, forming inversion dimers with an R22(8) ring motif. The dimers are linked via pairs of C—H...O hydrogen bonds, forming ribbons enclosing R22(12) ring motifs lying in a plane parallel to (01-1).http://scripts.iucr.org/cgi-bin/paper?S2056989015002017crystal structurequinolinepyrrolidinehydrogen bonds |
spellingShingle | M. P. Savithri M. Suresh R. Raghunathan R. Raja A. SubbiahPandi Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione Acta Crystallographica Section E: Crystallographic Communications crystal structure quinoline pyrrolidine hydrogen bonds |
title | Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione |
title_full | Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione |
title_fullStr | Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione |
title_full_unstemmed | Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione |
title_short | Crystal structure of 15-(naphthalen-1-yl)-7,7a,8,9,10,11-hexahydro-6a,12a-(methanoepoxymethano)indolizino[2,3-c]quinoline-6,13(5H)-dione |
title_sort | crystal structure of 15 naphthalen 1 yl 7 7a 8 9 10 11 hexahydro 6a 12a methanoepoxymethano indolizino 2 3 c quinoline 6 13 5h dione |
topic | crystal structure quinoline pyrrolidine hydrogen bonds |
url | http://scripts.iucr.org/cgi-bin/paper?S2056989015002017 |
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