Rhodium-catalyzed selective direct arylation of phosphines with aryl bromides
The widespread use of biaryl monophosphines is frequently hampered by the challenges associated with their modular preparation. Here, the authors report a protocol that appends arenes to arylphosphines to access a series of these compounds via rhodium-catalysed P(III)- directed ortho C–H activation,...
Main Authors: | Dingyi Wang, Mingjie Li, Chengdong Shuang, Yong Liang, Yue Zhao, Minyan Wang, Zhuangzhi Shi |
---|---|
Format: | Article |
Language: | English |
Published: |
Nature Portfolio
2022-05-01
|
Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-022-30697-7 |
Similar Items
-
Pd-Catalyzed Nucleophilic Fluorination of Aryl Bromides
by: Lee, Hong Geun, et al.
Published: (2015) -
Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
by: Pan, Jun, et al.
Published: (2013) -
The Pd-catalyzed fluorination of (hetero)aryl bromides and triflates
by: Milner, Phillip J
Published: (2015) -
Rhodium-catalyzed asymmetric hydroamination of gem-difluoroallenes with anilines
by: Xiaowei Han, et al.
Published: (2022-08-01) -
Cationic rhodium complexes with ortho-Aryl substituted DPEphos ligands and rhodium-diphosphine catalysed phosphine-borane dehydropolymerisation
by: Race, JJ
Published: (2022)