Structural and rheological analysis of nickel enriched peraluminous glasses
This study describes the role of nickel oxide (NiO) in peraluminous glass. Peraluminous glass is defined by an excess of aluminium ions (Al3+) compared to modifier elements such as Na+, Li+ or Ca2+ ions. The study investigates the effect NiO incorporation on peraluminous glass homogeneity and proces...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2021-09-01
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| Series: | Journal of Non-Crystalline Solids: X |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2590159121000108 |
| _version_ | 1818992225259880448 |
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| author | E. Hansen D. Perret I. Bardez-Giboire S. Mure C. Rapin |
| author_facet | E. Hansen D. Perret I. Bardez-Giboire S. Mure C. Rapin |
| author_sort | E. Hansen |
| collection | DOAJ |
| description | This study describes the role of nickel oxide (NiO) in peraluminous glass. Peraluminous glass is defined by an excess of aluminium ions (Al3+) compared to modifier elements such as Na+, Li+ or Ca2+ ions. The study investigates the effect NiO incorporation on peraluminous glass homogeneity and process ability. Quenched NiO-containing glass showed an incorporation limit greater than 12 wt% NiO (13.8 mol%), while slowly cooled glass showed a limit of 5 wt% NiO (5.8 mol%). Nickel oxide is also found to have a fludifying effect on peraluminous glasses. When the nickel oxide content is above its incorporation limit, the resulting crystals were found to have a significant effect on glass rheological properties. Finally, hypotheses are proposed as to the structural role of Ni in peraluminous glass based on the experimental results obtained. |
| first_indexed | 2024-12-20T20:22:46Z |
| format | Article |
| id | doaj.art-980af2df9f2d4cccb403f047e223da52 |
| institution | Directory Open Access Journal |
| issn | 2590-1591 |
| language | English |
| last_indexed | 2024-12-20T20:22:46Z |
| publishDate | 2021-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Non-Crystalline Solids: X |
| spelling | doaj.art-980af2df9f2d4cccb403f047e223da522022-12-21T19:27:32ZengElsevierJournal of Non-Crystalline Solids: X2590-15912021-09-0111100069Structural and rheological analysis of nickel enriched peraluminous glassesE. Hansen0D. Perret1I. Bardez-Giboire2S. Mure3C. Rapin4Laboratoire d'études de Développement des Matrices de Conditionnement, CEA Marcoule, FranceLaboratoire d'études de Développement des Matrices de Conditionnement, CEA Marcoule, France; Corresponding author at: CEA Marcoule, ISEC/DE2D/SEVT/LDMC, BP 17171, F-30207 Bagnols-sur-Cèze, France.Laboratoire d'études de Développement des Matrices de Conditionnement, CEA Marcoule, FranceLaboratoire d'études de Développement des Matrices de Conditionnement, CEA Marcoule, FranceInstitut Jean Lamour, Nancy, FranceThis study describes the role of nickel oxide (NiO) in peraluminous glass. Peraluminous glass is defined by an excess of aluminium ions (Al3+) compared to modifier elements such as Na+, Li+ or Ca2+ ions. The study investigates the effect NiO incorporation on peraluminous glass homogeneity and process ability. Quenched NiO-containing glass showed an incorporation limit greater than 12 wt% NiO (13.8 mol%), while slowly cooled glass showed a limit of 5 wt% NiO (5.8 mol%). Nickel oxide is also found to have a fludifying effect on peraluminous glasses. When the nickel oxide content is above its incorporation limit, the resulting crystals were found to have a significant effect on glass rheological properties. Finally, hypotheses are proposed as to the structural role of Ni in peraluminous glass based on the experimental results obtained.http://www.sciencedirect.com/science/article/pii/S2590159121000108Peraluminous glassIncorporation limitCrystallizationViscosityNickel oxide |
| spellingShingle | E. Hansen D. Perret I. Bardez-Giboire S. Mure C. Rapin Structural and rheological analysis of nickel enriched peraluminous glasses Journal of Non-Crystalline Solids: X Peraluminous glass Incorporation limit Crystallization Viscosity Nickel oxide |
| title | Structural and rheological analysis of nickel enriched peraluminous glasses |
| title_full | Structural and rheological analysis of nickel enriched peraluminous glasses |
| title_fullStr | Structural and rheological analysis of nickel enriched peraluminous glasses |
| title_full_unstemmed | Structural and rheological analysis of nickel enriched peraluminous glasses |
| title_short | Structural and rheological analysis of nickel enriched peraluminous glasses |
| title_sort | structural and rheological analysis of nickel enriched peraluminous glasses |
| topic | Peraluminous glass Incorporation limit Crystallization Viscosity Nickel oxide |
| url | http://www.sciencedirect.com/science/article/pii/S2590159121000108 |
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