Bis[(18-crown-6-κ6O)sodium] (18-crown-6-1κ6O)-μ-thiocyanato-1:2κ2S:N-pentathiocyanato-2κ5N-indate(III)sodium 1,2-dichloroethane sesquisolvate
The title complex, [Na(C12H24O6)]2[InNa(NCS)6(C12H24O6)]·1.5C2H4Cl2, has been synthesized by the reaction of 18-crown-6 with InCl3 and NaSCN. The In atom has a six-coordinate octahedral environment, being bonded to the N atoms of six thiocyanate groups. The bond lengths and angles show...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-11-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809039282 |
| _version_ | 1818948447110168576 |
|---|---|
| author | Lingqian Kong |
| author_facet | Lingqian Kong |
| author_sort | Lingqian Kong |
| collection | DOAJ |
| description | The title complex, [Na(C12H24O6)]2[InNa(NCS)6(C12H24O6)]·1.5C2H4Cl2, has been synthesized by the reaction of 18-crown-6 with InCl3 and NaSCN. The In atom has a six-coordinate octahedral environment, being bonded to the N atoms of six thiocyanate groups. The bond lengths and angles show normal values. The crystal packing exhibits no significantly short intermolecular contacts. |
| first_indexed | 2024-12-20T08:46:56Z |
| format | Article |
| id | doaj.art-9818ba74120c4209bbfa1c5af5c2f69d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:46:56Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9818ba74120c4209bbfa1c5af5c2f69d2022-12-21T19:46:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1312m131210.1107/S1600536809039282Bis[(18-crown-6-κ6O)sodium] (18-crown-6-1κ6O)-μ-thiocyanato-1:2κ2S:N-pentathiocyanato-2κ5N-indate(III)sodium 1,2-dichloroethane sesquisolvateLingqian KongThe title complex, [Na(C12H24O6)]2[InNa(NCS)6(C12H24O6)]·1.5C2H4Cl2, has been synthesized by the reaction of 18-crown-6 with InCl3 and NaSCN. The In atom has a six-coordinate octahedral environment, being bonded to the N atoms of six thiocyanate groups. The bond lengths and angles show normal values. The crystal packing exhibits no significantly short intermolecular contacts.http://scripts.iucr.org/cgi-bin/paper?S1600536809039282 |
| spellingShingle | Lingqian Kong Bis[(18-crown-6-κ6O)sodium] (18-crown-6-1κ6O)-μ-thiocyanato-1:2κ2S:N-pentathiocyanato-2κ5N-indate(III)sodium 1,2-dichloroethane sesquisolvate Acta Crystallographica Section E |
| title | Bis[(18-crown-6-κ6O)sodium] (18-crown-6-1κ6O)-μ-thiocyanato-1:2κ2S:N-pentathiocyanato-2κ5N-indate(III)sodium 1,2-dichloroethane sesquisolvate |
| title_full | Bis[(18-crown-6-κ6O)sodium] (18-crown-6-1κ6O)-μ-thiocyanato-1:2κ2S:N-pentathiocyanato-2κ5N-indate(III)sodium 1,2-dichloroethane sesquisolvate |
| title_fullStr | Bis[(18-crown-6-κ6O)sodium] (18-crown-6-1κ6O)-μ-thiocyanato-1:2κ2S:N-pentathiocyanato-2κ5N-indate(III)sodium 1,2-dichloroethane sesquisolvate |
| title_full_unstemmed | Bis[(18-crown-6-κ6O)sodium] (18-crown-6-1κ6O)-μ-thiocyanato-1:2κ2S:N-pentathiocyanato-2κ5N-indate(III)sodium 1,2-dichloroethane sesquisolvate |
| title_short | Bis[(18-crown-6-κ6O)sodium] (18-crown-6-1κ6O)-μ-thiocyanato-1:2κ2S:N-pentathiocyanato-2κ5N-indate(III)sodium 1,2-dichloroethane sesquisolvate |
| title_sort | bis 18 crown 6 amp 954 6o sodium 18 crown 6 1 amp 954 6o amp 956 thiocyanato 1 2 amp 954 2s n pentathiocyanato 2 amp 954 5n indate iii sodium 1 2 dichloroethane sesquisolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809039282 |
| work_keys_str_mv | AT lingqiankong bis18crown6amp9546osodium18crown61amp9546oamp956thiocyanato12amp9542snpentathiocyanato2amp9545nindateiiisodium12dichloroethanesesquisolvate |