In Situ Study of Cave 98 Murals on Dunhuang Grottoes Using Portable Laser-Induced Breakdown Spectroscopy

The investigation of painted layers on murals at Cave 98 from Dunhuang Grottoes was carried out in situ using portable laser-induced breakdown spectroscopy (LIBS) for the first time. The ablation effect of laser pulses on a mural surface was evaluated under fixed experimental parameters, and the res...

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Main Authors: Yaopeng Yin, Zongren Yu, Duixiong Sun, Zhongwei Shan, Qiang Cui, Yiming Zhang, Yaqi Feng, Biwen Shui, Zhuo Wang, Zhiyuan Yin, Bolong Chai, Wenyuan Zhang, Chenzhong Dong, Bomin Su
Format: Article
Language:English
Published: Frontiers Media S.A. 2022-03-01
Series:Frontiers in Physics
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fphy.2022.847036/full
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author Yaopeng Yin
Zongren Yu
Duixiong Sun
Zhongwei Shan
Qiang Cui
Yiming Zhang
Yaqi Feng
Biwen Shui
Zhuo Wang
Zhiyuan Yin
Bolong Chai
Wenyuan Zhang
Chenzhong Dong
Bomin Su
author_facet Yaopeng Yin
Zongren Yu
Duixiong Sun
Zhongwei Shan
Qiang Cui
Yiming Zhang
Yaqi Feng
Biwen Shui
Zhuo Wang
Zhiyuan Yin
Bolong Chai
Wenyuan Zhang
Chenzhong Dong
Bomin Su
author_sort Yaopeng Yin
collection DOAJ
description The investigation of painted layers on murals at Cave 98 from Dunhuang Grottoes was carried out in situ using portable laser-induced breakdown spectroscopy (LIBS) for the first time. The ablation effect of laser pulses on a mural surface was evaluated under fixed experimental parameters, and the results showed that the influence of laser ablation on ancient murals was acceptable. Then the pigments used in the red, green, and blue layers were indicated with the LIBS spectral data of the corresponding color coupled with a classifiable model of pigments based on the principal component analysis (PCA) method. Finally, the depth profiling of the multilayer structure composed with overlapped painted layers was determined based on the pigment size information of the superficial green layer and the relationship of laser shots and ablation depth, and the thickness of the superficial green layer was analyzed quantitatively, which fits well with the result of the cross-sectional analysis. Therefore, this work can shed light on the great potential for ancient mural applications in LIBS.
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spelling doaj.art-9841180c7b0545be94c75cb8f08b98992022-12-22T01:11:35ZengFrontiers Media S.A.Frontiers in Physics2296-424X2022-03-011010.3389/fphy.2022.847036847036In Situ Study of Cave 98 Murals on Dunhuang Grottoes Using Portable Laser-Induced Breakdown SpectroscopyYaopeng Yin0Zongren Yu1Duixiong Sun2Zhongwei Shan3Qiang Cui4Yiming Zhang5Yaqi Feng6Biwen Shui7Zhuo Wang8Zhiyuan Yin9Bolong Chai10Wenyuan Zhang11Chenzhong Dong12Bomin Su13National Research Center for Conservation of Ancient Wall Paintings and Earthen Sites, Dunhuang, ChinaNational Research Center for Conservation of Ancient Wall Paintings and Earthen Sites, Dunhuang, ChinaKey Laboratory of Atomic and Molecular Physics and Functional Materials of Gansu Province, College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou, ChinaNational Research Center for Conservation of Ancient Wall Paintings and Earthen Sites, Dunhuang, ChinaNational Research Center for Conservation of Ancient Wall Paintings and Earthen Sites, Dunhuang, ChinaKey Laboratory of Atomic and Molecular Physics and Functional Materials of Gansu Province, College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou, ChinaNational Research Center for Conservation of Ancient Wall Paintings and Earthen Sites, Dunhuang, ChinaNational Research Center for Conservation of Ancient Wall Paintings and Earthen Sites, Dunhuang, ChinaNational Research Center for Conservation of Ancient Wall Paintings and Earthen Sites, Dunhuang, ChinaNational Research Center for Conservation of Ancient Wall Paintings and Earthen Sites, Dunhuang, ChinaNational Research Center for Conservation of Ancient Wall Paintings and Earthen Sites, Dunhuang, ChinaNational Research Center for Conservation of Ancient Wall Paintings and Earthen Sites, Dunhuang, ChinaKey Laboratory of Atomic and Molecular Physics and Functional Materials of Gansu Province, College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou, ChinaNational Research Center for Conservation of Ancient Wall Paintings and Earthen Sites, Dunhuang, ChinaThe investigation of painted layers on murals at Cave 98 from Dunhuang Grottoes was carried out in situ using portable laser-induced breakdown spectroscopy (LIBS) for the first time. The ablation effect of laser pulses on a mural surface was evaluated under fixed experimental parameters, and the results showed that the influence of laser ablation on ancient murals was acceptable. Then the pigments used in the red, green, and blue layers were indicated with the LIBS spectral data of the corresponding color coupled with a classifiable model of pigments based on the principal component analysis (PCA) method. Finally, the depth profiling of the multilayer structure composed with overlapped painted layers was determined based on the pigment size information of the superficial green layer and the relationship of laser shots and ablation depth, and the thickness of the superficial green layer was analyzed quantitatively, which fits well with the result of the cross-sectional analysis. Therefore, this work can shed light on the great potential for ancient mural applications in LIBS.https://www.frontiersin.org/articles/10.3389/fphy.2022.847036/fullMogao GrottoesDunhuang muralsportable LIBSin situ analysispainted layers
spellingShingle Yaopeng Yin
Zongren Yu
Duixiong Sun
Zhongwei Shan
Qiang Cui
Yiming Zhang
Yaqi Feng
Biwen Shui
Zhuo Wang
Zhiyuan Yin
Bolong Chai
Wenyuan Zhang
Chenzhong Dong
Bomin Su
In Situ Study of Cave 98 Murals on Dunhuang Grottoes Using Portable Laser-Induced Breakdown Spectroscopy
Frontiers in Physics
Mogao Grottoes
Dunhuang murals
portable LIBS
in situ analysis
painted layers
title In Situ Study of Cave 98 Murals on Dunhuang Grottoes Using Portable Laser-Induced Breakdown Spectroscopy
title_full In Situ Study of Cave 98 Murals on Dunhuang Grottoes Using Portable Laser-Induced Breakdown Spectroscopy
title_fullStr In Situ Study of Cave 98 Murals on Dunhuang Grottoes Using Portable Laser-Induced Breakdown Spectroscopy
title_full_unstemmed In Situ Study of Cave 98 Murals on Dunhuang Grottoes Using Portable Laser-Induced Breakdown Spectroscopy
title_short In Situ Study of Cave 98 Murals on Dunhuang Grottoes Using Portable Laser-Induced Breakdown Spectroscopy
title_sort in situ study of cave 98 murals on dunhuang grottoes using portable laser induced breakdown spectroscopy
topic Mogao Grottoes
Dunhuang murals
portable LIBS
in situ analysis
painted layers
url https://www.frontiersin.org/articles/10.3389/fphy.2022.847036/full
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