Poly[[triaqua(μ3-pyridine-2,4,6-tricarboxylato)gadolinium(III)] monohydrate]

The title compound, {[Gd(C8H2NO6)(H2O)3]·H2O}n, was obtained in water under hydrothermal conditions. The GdIII ions are nine-coordinated by two O and one N atoms from one pyridine-2,4,6-tricarboxylate ligand, two O atoms from another ligand, one O atom from a third ligand and three coor...

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Main Authors: Hong-Sheng Wang, Wan-Qiang Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809038793
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author Hong-Sheng Wang
Wan-Qiang Zhang
author_facet Hong-Sheng Wang
Wan-Qiang Zhang
author_sort Hong-Sheng Wang
collection DOAJ
description The title compound, {[Gd(C8H2NO6)(H2O)3]·H2O}n, was obtained in water under hydrothermal conditions. The GdIII ions are nine-coordinated by two O and one N atoms from one pyridine-2,4,6-tricarboxylate ligand, two O atoms from another ligand, one O atom from a third ligand and three coordinated water molecules. Each ligand binds three metal centers. Two-dimensional layers are formed through the Gd—O bonds and the layers are linked by O—H...O hydrogen bonds, forming a three-dimensional network.
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spelling doaj.art-984bd305e3304dd4be3885a221c5cd2e2022-12-21T19:46:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1271m127110.1107/S1600536809038793Poly[[triaqua(μ3-pyridine-2,4,6-tricarboxylato)gadolinium(III)] monohydrate]Hong-Sheng WangWan-Qiang ZhangThe title compound, {[Gd(C8H2NO6)(H2O)3]·H2O}n, was obtained in water under hydrothermal conditions. The GdIII ions are nine-coordinated by two O and one N atoms from one pyridine-2,4,6-tricarboxylate ligand, two O atoms from another ligand, one O atom from a third ligand and three coordinated water molecules. Each ligand binds three metal centers. Two-dimensional layers are formed through the Gd—O bonds and the layers are linked by O—H...O hydrogen bonds, forming a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536809038793
spellingShingle Hong-Sheng Wang
Wan-Qiang Zhang
Poly[[triaqua(μ3-pyridine-2,4,6-tricarboxylato)gadolinium(III)] monohydrate]
Acta Crystallographica Section E
title Poly[[triaqua(μ3-pyridine-2,4,6-tricarboxylato)gadolinium(III)] monohydrate]
title_full Poly[[triaqua(μ3-pyridine-2,4,6-tricarboxylato)gadolinium(III)] monohydrate]
title_fullStr Poly[[triaqua(μ3-pyridine-2,4,6-tricarboxylato)gadolinium(III)] monohydrate]
title_full_unstemmed Poly[[triaqua(μ3-pyridine-2,4,6-tricarboxylato)gadolinium(III)] monohydrate]
title_short Poly[[triaqua(μ3-pyridine-2,4,6-tricarboxylato)gadolinium(III)] monohydrate]
title_sort poly triaqua amp 956 3 pyridine 2 4 6 tricarboxylato gadolinium iii monohydrate
url http://scripts.iucr.org/cgi-bin/paper?S1600536809038793
work_keys_str_mv AT hongshengwang polytriaquaamp9563pyridine246tricarboxylatogadoliniumiiimonohydrate
AT wanqiangzhang polytriaquaamp9563pyridine246tricarboxylatogadoliniumiiimonohydrate