Exploring the Effects of the Interaction of Carbon and MoS<sub>2</sub> Catalyst on CO<sub>2</sub> Hydrogenation to Methanol
Hydrogenation of CO<sub>2</sub> to form methanol utilizing green hydrogen is a promising route to realizing carbon neutrality. However, the development of catalyst with high activity and selectivity to methanol from the CO<sub>2</sub> hydrogenation is still a challenge due to...
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| Format: | Article |
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MDPI AG
2022-05-01
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| Series: | International Journal of Molecular Sciences |
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| Online Access: | https://www.mdpi.com/1422-0067/23/9/5220 |
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| author | Pingping Cui Ruyu Sun Linfei Xiao Wei Wu |
| author_facet | Pingping Cui Ruyu Sun Linfei Xiao Wei Wu |
| author_sort | Pingping Cui |
| collection | DOAJ |
| description | Hydrogenation of CO<sub>2</sub> to form methanol utilizing green hydrogen is a promising route to realizing carbon neutrality. However, the development of catalyst with high activity and selectivity to methanol from the CO<sub>2</sub> hydrogenation is still a challenge due to the chemical inertness of CO<sub>2</sub> and its characteristics of multi-path conversion. Herein, a series of highly active carbon-confining molybdenum sulfide (MoS<sub>2</sub>@C) catalysts were prepared by the in-situ pyrolysis method. In comparison with the bulk MoS<sub>2</sub> and MoS<sub>2</sub>/C, the stronger interaction between MoS<sub>2</sub> and the carbon layer was clearly generated. Under the optimized reaction conditions, MoS<sub>2</sub>@C showed better catalytic performance and long-term stability. The MoS<sub>2</sub>@C catalyst could sustain around 32.4% conversion of CO<sub>2</sub> with 94.8% selectivity of MeOH for at least 150 h. |
| first_indexed | 2024-03-10T04:03:29Z |
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| institution | Directory Open Access Journal |
| issn | 1661-6596 1422-0067 |
| language | English |
| last_indexed | 2024-03-10T04:03:29Z |
| publishDate | 2022-05-01 |
| publisher | MDPI AG |
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| series | International Journal of Molecular Sciences |
| spelling | doaj.art-98527863cfe748539211b411ef9635b62023-11-23T08:28:57ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672022-05-01239522010.3390/ijms23095220Exploring the Effects of the Interaction of Carbon and MoS<sub>2</sub> Catalyst on CO<sub>2</sub> Hydrogenation to MethanolPingping Cui0Ruyu Sun1Linfei Xiao2Wei Wu3National Center for International Research on Catalytic Technology, Key Laboratory of Chemical Engineering Process & Technology for High-Efficiency Conversion, College of Heilongjiang Province, School of Chemistry and Material Sciences, Heilongjiang University, Harbin 150080, ChinaNational Center for International Research on Catalytic Technology, Key Laboratory of Chemical Engineering Process & Technology for High-Efficiency Conversion, College of Heilongjiang Province, School of Chemistry and Material Sciences, Heilongjiang University, Harbin 150080, ChinaNational Center for International Research on Catalytic Technology, Key Laboratory of Chemical Engineering Process & Technology for High-Efficiency Conversion, College of Heilongjiang Province, School of Chemistry and Material Sciences, Heilongjiang University, Harbin 150080, ChinaNational Center for International Research on Catalytic Technology, Key Laboratory of Chemical Engineering Process & Technology for High-Efficiency Conversion, College of Heilongjiang Province, School of Chemistry and Material Sciences, Heilongjiang University, Harbin 150080, ChinaHydrogenation of CO<sub>2</sub> to form methanol utilizing green hydrogen is a promising route to realizing carbon neutrality. However, the development of catalyst with high activity and selectivity to methanol from the CO<sub>2</sub> hydrogenation is still a challenge due to the chemical inertness of CO<sub>2</sub> and its characteristics of multi-path conversion. Herein, a series of highly active carbon-confining molybdenum sulfide (MoS<sub>2</sub>@C) catalysts were prepared by the in-situ pyrolysis method. In comparison with the bulk MoS<sub>2</sub> and MoS<sub>2</sub>/C, the stronger interaction between MoS<sub>2</sub> and the carbon layer was clearly generated. Under the optimized reaction conditions, MoS<sub>2</sub>@C showed better catalytic performance and long-term stability. The MoS<sub>2</sub>@C catalyst could sustain around 32.4% conversion of CO<sub>2</sub> with 94.8% selectivity of MeOH for at least 150 h.https://www.mdpi.com/1422-0067/23/9/5220MoS<sub>2</sub>@Ccarbon dioxidehydrogenationmethanol |
| spellingShingle | Pingping Cui Ruyu Sun Linfei Xiao Wei Wu Exploring the Effects of the Interaction of Carbon and MoS<sub>2</sub> Catalyst on CO<sub>2</sub> Hydrogenation to Methanol International Journal of Molecular Sciences MoS<sub>2</sub>@C carbon dioxide hydrogenation methanol |
| title | Exploring the Effects of the Interaction of Carbon and MoS<sub>2</sub> Catalyst on CO<sub>2</sub> Hydrogenation to Methanol |
| title_full | Exploring the Effects of the Interaction of Carbon and MoS<sub>2</sub> Catalyst on CO<sub>2</sub> Hydrogenation to Methanol |
| title_fullStr | Exploring the Effects of the Interaction of Carbon and MoS<sub>2</sub> Catalyst on CO<sub>2</sub> Hydrogenation to Methanol |
| title_full_unstemmed | Exploring the Effects of the Interaction of Carbon and MoS<sub>2</sub> Catalyst on CO<sub>2</sub> Hydrogenation to Methanol |
| title_short | Exploring the Effects of the Interaction of Carbon and MoS<sub>2</sub> Catalyst on CO<sub>2</sub> Hydrogenation to Methanol |
| title_sort | exploring the effects of the interaction of carbon and mos sub 2 sub catalyst on co sub 2 sub hydrogenation to methanol |
| topic | MoS<sub>2</sub>@C carbon dioxide hydrogenation methanol |
| url | https://www.mdpi.com/1422-0067/23/9/5220 |
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