Fabrication and Growth Mechanism of Nano-Octahedrons: A Study on Cu2O Core-Shell Structures for Oxygen Evolution Reaction

This paper explores the process and growth mechanism involved in fabricating nano-octahedrons. Using two key components, CTAB and hydrazine hydrate, leads to the formation of octahedral shapes. A Cu _2 O octahedral core–shell structure was successfully created by employing a coating technique, and i...

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Main Author: Anand Parkash
Format: Article
Language:English
Published: IOP Publishing 2023-01-01
Series:ECS Advances
Subjects:
Online Access:https://doi.org/10.1149/2754-2734/acec5d
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author Anand Parkash
author_facet Anand Parkash
author_sort Anand Parkash
collection DOAJ
description This paper explores the process and growth mechanism involved in fabricating nano-octahedrons. Using two key components, CTAB and hydrazine hydrate, leads to the formation of octahedral shapes. A Cu _2 O octahedral core–shell structure was successfully created by employing a coating technique, and its performance in the oxygen evolution reaction (OER) was thoroughly evaluated. Due to its high dispersibility in ammonia solution, Cu _2 O serves as an excellent representative for other components. Additionally, this chapter provides a detailed account of the production of octahedral nanocages through the ammonia etching method. Notably, the Cu _2 O nano octahedra demonstrate superior OER performance compared to commercial RuO _2 , exhibiting a significantly low overpotential of only 370 mV at 10 mA cm ^−2 . These findings bear important implications for designing stable core/shell nanostructures and hollow structures by implementing appropriate chemicals while also deepening our understanding of the formation of octahedral shapes.
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spelling doaj.art-98588e5de7a34b798907219d611d80ea2023-08-09T14:48:12ZengIOP PublishingECS Advances2754-27342023-01-012303100210.1149/2754-2734/acec5dFabrication and Growth Mechanism of Nano-Octahedrons: A Study on Cu2O Core-Shell Structures for Oxygen Evolution ReactionAnand Parkash0https://orcid.org/0000-0001-7262-6721School of Chemistry and Chemical Engineering, Shaanxi Normal University , Chang’an West Street 620, Xi’an 710119, People’s Republic of ChinaThis paper explores the process and growth mechanism involved in fabricating nano-octahedrons. Using two key components, CTAB and hydrazine hydrate, leads to the formation of octahedral shapes. A Cu _2 O octahedral core–shell structure was successfully created by employing a coating technique, and its performance in the oxygen evolution reaction (OER) was thoroughly evaluated. Due to its high dispersibility in ammonia solution, Cu _2 O serves as an excellent representative for other components. Additionally, this chapter provides a detailed account of the production of octahedral nanocages through the ammonia etching method. Notably, the Cu _2 O nano octahedra demonstrate superior OER performance compared to commercial RuO _2 , exhibiting a significantly low overpotential of only 370 mV at 10 mA cm ^−2 . These findings bear important implications for designing stable core/shell nanostructures and hollow structures by implementing appropriate chemicals while also deepening our understanding of the formation of octahedral shapes.https://doi.org/10.1149/2754-2734/acec5dCu2O nano octahedraCTABhydrazine hydratestabilityOER
spellingShingle Anand Parkash
Fabrication and Growth Mechanism of Nano-Octahedrons: A Study on Cu2O Core-Shell Structures for Oxygen Evolution Reaction
ECS Advances
Cu2O nano octahedra
CTAB
hydrazine hydrate
stability
OER
title Fabrication and Growth Mechanism of Nano-Octahedrons: A Study on Cu2O Core-Shell Structures for Oxygen Evolution Reaction
title_full Fabrication and Growth Mechanism of Nano-Octahedrons: A Study on Cu2O Core-Shell Structures for Oxygen Evolution Reaction
title_fullStr Fabrication and Growth Mechanism of Nano-Octahedrons: A Study on Cu2O Core-Shell Structures for Oxygen Evolution Reaction
title_full_unstemmed Fabrication and Growth Mechanism of Nano-Octahedrons: A Study on Cu2O Core-Shell Structures for Oxygen Evolution Reaction
title_short Fabrication and Growth Mechanism of Nano-Octahedrons: A Study on Cu2O Core-Shell Structures for Oxygen Evolution Reaction
title_sort fabrication and growth mechanism of nano octahedrons a study on cu2o core shell structures for oxygen evolution reaction
topic Cu2O nano octahedra
CTAB
hydrazine hydrate
stability
OER
url https://doi.org/10.1149/2754-2734/acec5d
work_keys_str_mv AT anandparkash fabricationandgrowthmechanismofnanooctahedronsastudyoncu2ocoreshellstructuresforoxygenevolutionreaction