Recovery of Chromium (III) from Tannery wastewater

Three aqueous oxidants, Hydrogen peroxide, Sodium Hypochlorite and Calcium Hypochlorite were employed independently in oxidizing Chromium (III) containing tannery wastewaters to soluble chromate (CrO42-) under alkaline conditions. The amount of chromate recovered was determined via spectrophotometry...

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Main Authors: M. ALI AWAN, M.A. BAIG, JAVED IQBAL, M.R. ASLAM, nAVEED IJAZ
Format: Article
Language:English
Published: Joint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP) 2004-03-01
Series:Journal of Applied Sciences and Environmental Management
Online Access:https://www.ajol.info/index.php/jasem/article/view/17204
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author M. ALI AWAN
M.A. BAIG
JAVED IQBAL
M.R. ASLAM
nAVEED IJAZ
author_facet M. ALI AWAN
M.A. BAIG
JAVED IQBAL
M.R. ASLAM
nAVEED IJAZ
author_sort M. ALI AWAN
collection DOAJ
description Three aqueous oxidants, Hydrogen peroxide, Sodium Hypochlorite and Calcium Hypochlorite were employed independently in oxidizing Chromium (III) containing tannery wastewaters to soluble chromate (CrO42-) under alkaline conditions. The amount of chromate recovered was determined via spectrophotometry. Hydrogen peroxide was potentially a suitable oxidant as it could recover chromate (CrO42-) up to 98% (from synthetic Cr3+ solution) and 88% (from effluent I). The percentage recoveries by the hypochlorites were lower than those by hydrogen peroxide i.e. for NaOCl the recoveries were up to 94% (from synthetic Cr3+ solution) and 67% (from effluent I), similarly for Ca(OCl)2 90% (from synthetic Cr3+ solution) and 49% (from effluent I). For all three oxidants complete (100%) recovery could not be achieved despite different experimental conditions (temperatures and oxidation time). The results clearly indicate that hydrogen peroxide is the most efficient among the three oxidants. Journal of Applied Sciences and Environmental Management Vol. 7(2) 2003: 5-8
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spelling doaj.art-98662d9ea33e4e49b80b328330a657c12024-04-02T19:55:04ZengJoint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP)Journal of Applied Sciences and Environmental Management2659-15022659-14992004-03-017210.4314/jasem.v7i2.17204Recovery of Chromium (III) from Tannery wastewaterM. ALI AWAN0M.A. BAIG1JAVED IQBAL2M.R. ASLAM3nAVEED IJAZ4Institute of Environmental Science and Engineering (IESE), National University of Sciences & Technology (NUST), Rawalpindi, PakistanInstitute of Environmental Science and Engineering (IESE), National University of Sciences & Technology (NUST), Rawalpindi, PakistanPakistan Environmental Protection Agency (PEPA), Islamabad, PakistanInstitute of Environmental Science and Engineering (IESE), National University of Sciences & Technology (NUST), Rawalpindi, PakistanInstitute of Environmental Science and Engineering (IESE), National University of Sciences & Technology (NUST), Rawalpindi, PakistanThree aqueous oxidants, Hydrogen peroxide, Sodium Hypochlorite and Calcium Hypochlorite were employed independently in oxidizing Chromium (III) containing tannery wastewaters to soluble chromate (CrO42-) under alkaline conditions. The amount of chromate recovered was determined via spectrophotometry. Hydrogen peroxide was potentially a suitable oxidant as it could recover chromate (CrO42-) up to 98% (from synthetic Cr3+ solution) and 88% (from effluent I). The percentage recoveries by the hypochlorites were lower than those by hydrogen peroxide i.e. for NaOCl the recoveries were up to 94% (from synthetic Cr3+ solution) and 67% (from effluent I), similarly for Ca(OCl)2 90% (from synthetic Cr3+ solution) and 49% (from effluent I). For all three oxidants complete (100%) recovery could not be achieved despite different experimental conditions (temperatures and oxidation time). The results clearly indicate that hydrogen peroxide is the most efficient among the three oxidants. Journal of Applied Sciences and Environmental Management Vol. 7(2) 2003: 5-8https://www.ajol.info/index.php/jasem/article/view/17204
spellingShingle M. ALI AWAN
M.A. BAIG
JAVED IQBAL
M.R. ASLAM
nAVEED IJAZ
Recovery of Chromium (III) from Tannery wastewater
Journal of Applied Sciences and Environmental Management
title Recovery of Chromium (III) from Tannery wastewater
title_full Recovery of Chromium (III) from Tannery wastewater
title_fullStr Recovery of Chromium (III) from Tannery wastewater
title_full_unstemmed Recovery of Chromium (III) from Tannery wastewater
title_short Recovery of Chromium (III) from Tannery wastewater
title_sort recovery of chromium iii from tannery wastewater
url https://www.ajol.info/index.php/jasem/article/view/17204
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AT mabaig recoveryofchromiumiiifromtannerywastewater
AT javediqbal recoveryofchromiumiiifromtannerywastewater
AT mraslam recoveryofchromiumiiifromtannerywastewater
AT naveedijaz recoveryofchromiumiiifromtannerywastewater