Tunable architectures in Al/Al2O3 composites for enhanced damage tolerance using zirconium acetate-mediated ice-templating

Achieving lightweight, robust, and resilient materials is a sought-after goal, yet concurrently achieving these attributes presents a substantial challenge. A biomimetic design approach opens doors to innovative possibilities in this domain. In this paper, we use the ice-shaping properties of zircon...

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Main Authors: Meng-Qi Sun, Ping Shen
Format: Article
Language:English
Published: Elsevier 2024-01-01
Series:Materials & Design
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S0264127523010249
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author Meng-Qi Sun
Ping Shen
author_facet Meng-Qi Sun
Ping Shen
author_sort Meng-Qi Sun
collection DOAJ
description Achieving lightweight, robust, and resilient materials is a sought-after goal, yet concurrently achieving these attributes presents a substantial challenge. A biomimetic design approach opens doors to innovative possibilities in this domain. In this paper, we use the ice-shaping properties of zirconium acetate (ZRA) to obtain Al/Al2O3 composites with tunable architectures through freeze casting and pressure infiltration. The concentration of ZRA in the initial slurry is critical in controlling the final structure of the composites. The composites’ bending strength, compressive strength, and crack-initiation fracture toughness KIc improve with increasing ZRA concentration in the initial slurry. Interestingly, the crack-extension fracture toughness KJc demonstrates an initial decrease followed by subsequent improvement. In addition, the relationship between cracking mode and structural features in the composites is elucidated to explain the underlying strengthening and toughening mechanisms. This tunable and scale-able ice-templating and manufacturing approach opens new doors for developing high-performance metal-ceramic composites.
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spelling doaj.art-9878d588491f46ae8bd15ac1e63b31df2024-01-24T05:16:43ZengElsevierMaterials & Design0264-12752024-01-01237112608Tunable architectures in Al/Al2O3 composites for enhanced damage tolerance using zirconium acetate-mediated ice-templatingMeng-Qi Sun0Ping Shen1Key Laboratory of Automobile Materials (Ministry of Education), School of Materials Science and Engineering, Jilin University, No. 5988 Renmin Street, Changchun 130022, PR ChinaCorresponding author.; Key Laboratory of Automobile Materials (Ministry of Education), School of Materials Science and Engineering, Jilin University, No. 5988 Renmin Street, Changchun 130022, PR ChinaAchieving lightweight, robust, and resilient materials is a sought-after goal, yet concurrently achieving these attributes presents a substantial challenge. A biomimetic design approach opens doors to innovative possibilities in this domain. In this paper, we use the ice-shaping properties of zirconium acetate (ZRA) to obtain Al/Al2O3 composites with tunable architectures through freeze casting and pressure infiltration. The concentration of ZRA in the initial slurry is critical in controlling the final structure of the composites. The composites’ bending strength, compressive strength, and crack-initiation fracture toughness KIc improve with increasing ZRA concentration in the initial slurry. Interestingly, the crack-extension fracture toughness KJc demonstrates an initial decrease followed by subsequent improvement. In addition, the relationship between cracking mode and structural features in the composites is elucidated to explain the underlying strengthening and toughening mechanisms. This tunable and scale-able ice-templating and manufacturing approach opens new doors for developing high-performance metal-ceramic composites.http://www.sciencedirect.com/science/article/pii/S0264127523010249Metal-matrix composites (MMCs)MicrostructuresMechanical testingFreeze casting
spellingShingle Meng-Qi Sun
Ping Shen
Tunable architectures in Al/Al2O3 composites for enhanced damage tolerance using zirconium acetate-mediated ice-templating
Materials & Design
Metal-matrix composites (MMCs)
Microstructures
Mechanical testing
Freeze casting
title Tunable architectures in Al/Al2O3 composites for enhanced damage tolerance using zirconium acetate-mediated ice-templating
title_full Tunable architectures in Al/Al2O3 composites for enhanced damage tolerance using zirconium acetate-mediated ice-templating
title_fullStr Tunable architectures in Al/Al2O3 composites for enhanced damage tolerance using zirconium acetate-mediated ice-templating
title_full_unstemmed Tunable architectures in Al/Al2O3 composites for enhanced damage tolerance using zirconium acetate-mediated ice-templating
title_short Tunable architectures in Al/Al2O3 composites for enhanced damage tolerance using zirconium acetate-mediated ice-templating
title_sort tunable architectures in al al2o3 composites for enhanced damage tolerance using zirconium acetate mediated ice templating
topic Metal-matrix composites (MMCs)
Microstructures
Mechanical testing
Freeze casting
url http://www.sciencedirect.com/science/article/pii/S0264127523010249
work_keys_str_mv AT mengqisun tunablearchitecturesinalal2o3compositesforenhanceddamagetoleranceusingzirconiumacetatemediatedicetemplating
AT pingshen tunablearchitecturesinalal2o3compositesforenhanceddamagetoleranceusingzirconiumacetatemediatedicetemplating