Crystal structure of O-benzyl-l-tyrosine N-carboxy anhydride
In the title compound, C17H15NO4 (alternative name; O-benzyl-l-tyrosine N-carboxy anhydride), the oxazolidine ring is planer, with an r.m.s. deviation of 0.039 Å. The benzyloxy and benzyl rings are almost coplanar, making a dihedral angle of 0.078 (10)°, and are inclined to the oxazolidine ring by 5...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-04-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989017004236 |
| _version_ | 1798031424300777472 |
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| author | Aya Inada Hitoshi Kanazawa |
| author_facet | Aya Inada Hitoshi Kanazawa |
| author_sort | Aya Inada |
| collection | DOAJ |
| description | In the title compound, C17H15NO4 (alternative name; O-benzyl-l-tyrosine N-carboxy anhydride), the oxazolidine ring is planer, with an r.m.s. deviation of 0.039 Å. The benzyloxy and benzyl rings are almost coplanar, making a dihedral angle of 0.078 (10)°, and are inclined to the oxazolidine ring by 59.16 (11) and 58.42 (11)°, respectively. In the crystal, molecules are linked by N—H...O and C—H...O hydrogen bonds, forming ribbons propagating along [010]. The ribbons are linked by C—H...π interactions, forming a three-dimensional supramolecular structure. The oxazolidine rings of adjacent ribbons are arranged into a layer parallel to the ab plane. This arrangement is favourable for the polymerization of the compound in the solid state. |
| first_indexed | 2024-04-11T19:57:13Z |
| format | Article |
| id | doaj.art-989c3efe1e364a35b5ecbb605d9308a6 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T19:57:13Z |
| publishDate | 2017-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-989c3efe1e364a35b5ecbb605d9308a62022-12-22T04:05:58ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-04-0173455355510.1107/S2056989017004236su5359Crystal structure of O-benzyl-l-tyrosine N-carboxy anhydrideAya Inada0Hitoshi Kanazawa1Faculty of Symbiotic Systems Science, Fukushima University, 1 Kanayagawa, Fukushima, 960-1296, JapanFaculty of Symbiotic Systems Science, Fukushima University, 1 Kanayagawa, Fukushima, 960-1296, JapanIn the title compound, C17H15NO4 (alternative name; O-benzyl-l-tyrosine N-carboxy anhydride), the oxazolidine ring is planer, with an r.m.s. deviation of 0.039 Å. The benzyloxy and benzyl rings are almost coplanar, making a dihedral angle of 0.078 (10)°, and are inclined to the oxazolidine ring by 59.16 (11) and 58.42 (11)°, respectively. In the crystal, molecules are linked by N—H...O and C—H...O hydrogen bonds, forming ribbons propagating along [010]. The ribbons are linked by C—H...π interactions, forming a three-dimensional supramolecular structure. The oxazolidine rings of adjacent ribbons are arranged into a layer parallel to the ab plane. This arrangement is favourable for the polymerization of the compound in the solid state.http://scripts.iucr.org/cgi-bin/paper?S2056989017004236crystal structureL-tyrosineL-amino acid N-carboxy anhydrideO-benzyl-L-tyrosine NCAsolid-state polymerizationhydrogen bondingC—H...π interactions |
| spellingShingle | Aya Inada Hitoshi Kanazawa Crystal structure of O-benzyl-l-tyrosine N-carboxy anhydride Acta Crystallographica Section E: Crystallographic Communications crystal structure L-tyrosine L-amino acid N-carboxy anhydride O-benzyl-L-tyrosine NCA solid-state polymerization hydrogen bonding C—H...π interactions |
| title | Crystal structure of O-benzyl-l-tyrosine N-carboxy anhydride |
| title_full | Crystal structure of O-benzyl-l-tyrosine N-carboxy anhydride |
| title_fullStr | Crystal structure of O-benzyl-l-tyrosine N-carboxy anhydride |
| title_full_unstemmed | Crystal structure of O-benzyl-l-tyrosine N-carboxy anhydride |
| title_short | Crystal structure of O-benzyl-l-tyrosine N-carboxy anhydride |
| title_sort | crystal structure of o benzyl l tyrosine n carboxy anhydride |
| topic | crystal structure L-tyrosine L-amino acid N-carboxy anhydride O-benzyl-L-tyrosine NCA solid-state polymerization hydrogen bonding C—H...π interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989017004236 |
| work_keys_str_mv | AT ayainada crystalstructureofobenzylltyrosinencarboxyanhydride AT hitoshikanazawa crystalstructureofobenzylltyrosinencarboxyanhydride |