Achieving reversible superhydrophobic-superhydrophilic switching of lignocellulosic paper surface with modified Nano-TiO2 coating

Environmentally friendly flexible materials with functionalities such as reversibly tunable wettability have become much sought after because of their great potential for biological, chemical and electronic applications. We prepared a flexible superhydrophobic material by coating the hydrophobic nan...

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Main Authors: Yulei Li, Baoying Shi, Xiayu Luan, Zhanhua Hao, Yufeng Wang
Format: Article
Language:English
Published: Elsevier 2022-12-01
Series:Polymer Testing
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S0142941822003105
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author Yulei Li
Baoying Shi
Xiayu Luan
Zhanhua Hao
Yufeng Wang
author_facet Yulei Li
Baoying Shi
Xiayu Luan
Zhanhua Hao
Yufeng Wang
author_sort Yulei Li
collection DOAJ
description Environmentally friendly flexible materials with functionalities such as reversibly tunable wettability have become much sought after because of their great potential for biological, chemical and electronic applications. We prepared a flexible superhydrophobic material by coating the hydrophobic nano-TiO2 particles on lignocellulosic paper. The coated paper surfaces exhibited a reversible switching between superhydrophobicity and superhydrophilicity through UV irradiation and heating, respectively. After the UV irradiation treatment for about 100 min, the wettability of the coated paper is switched from superhydrophobicity to superhydrophilicity. After the coated paper with superhydrophilicity is heated for 25 h, the water contact angle (WCA) recovers to the original superhydrophobic state. Compared to the literatures, the switching time between two kinds of superwettability is significantly reduced. SEM images and XPS spectra indicate that the change in chemical composition of the coated paper surface is responsible for the reversible switching of wettability. The coated paper developed in this study is an attractive smart material with reversibly switchable wettability which has significant potential application in many fields which require tunable wettability.
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spelling doaj.art-98b5c47026de4506909d1a41750946c32022-12-22T02:24:11ZengElsevierPolymer Testing0142-94182022-12-01116107789Achieving reversible superhydrophobic-superhydrophilic switching of lignocellulosic paper surface with modified Nano-TiO2 coatingYulei Li0Baoying Shi1Xiayu Luan2Zhanhua Hao3Yufeng Wang4Tianjin University of Science and Technology, Tianjin, 300222, ChinaTianjin Tianshi College, Tianjin, 301700, ChinaTianjin University of Science and Technology, Tianjin, 300222, ChinaTianjin University of Science and Technology, Tianjin, 300222, ChinaTianjin University of Science and Technology, Tianjin, 300222, China; Corresponding author.Environmentally friendly flexible materials with functionalities such as reversibly tunable wettability have become much sought after because of their great potential for biological, chemical and electronic applications. We prepared a flexible superhydrophobic material by coating the hydrophobic nano-TiO2 particles on lignocellulosic paper. The coated paper surfaces exhibited a reversible switching between superhydrophobicity and superhydrophilicity through UV irradiation and heating, respectively. After the UV irradiation treatment for about 100 min, the wettability of the coated paper is switched from superhydrophobicity to superhydrophilicity. After the coated paper with superhydrophilicity is heated for 25 h, the water contact angle (WCA) recovers to the original superhydrophobic state. Compared to the literatures, the switching time between two kinds of superwettability is significantly reduced. SEM images and XPS spectra indicate that the change in chemical composition of the coated paper surface is responsible for the reversible switching of wettability. The coated paper developed in this study is an attractive smart material with reversibly switchable wettability which has significant potential application in many fields which require tunable wettability.http://www.sciencedirect.com/science/article/pii/S0142941822003105Reversible wettabilityLignocellulosic materialsCoated paperSuperhydrophobicitySuperhydrophilicityTiO2 nanoparticles
spellingShingle Yulei Li
Baoying Shi
Xiayu Luan
Zhanhua Hao
Yufeng Wang
Achieving reversible superhydrophobic-superhydrophilic switching of lignocellulosic paper surface with modified Nano-TiO2 coating
Polymer Testing
Reversible wettability
Lignocellulosic materials
Coated paper
Superhydrophobicity
Superhydrophilicity
TiO2 nanoparticles
title Achieving reversible superhydrophobic-superhydrophilic switching of lignocellulosic paper surface with modified Nano-TiO2 coating
title_full Achieving reversible superhydrophobic-superhydrophilic switching of lignocellulosic paper surface with modified Nano-TiO2 coating
title_fullStr Achieving reversible superhydrophobic-superhydrophilic switching of lignocellulosic paper surface with modified Nano-TiO2 coating
title_full_unstemmed Achieving reversible superhydrophobic-superhydrophilic switching of lignocellulosic paper surface with modified Nano-TiO2 coating
title_short Achieving reversible superhydrophobic-superhydrophilic switching of lignocellulosic paper surface with modified Nano-TiO2 coating
title_sort achieving reversible superhydrophobic superhydrophilic switching of lignocellulosic paper surface with modified nano tio2 coating
topic Reversible wettability
Lignocellulosic materials
Coated paper
Superhydrophobicity
Superhydrophilicity
TiO2 nanoparticles
url http://www.sciencedirect.com/science/article/pii/S0142941822003105
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AT baoyingshi achievingreversiblesuperhydrophobicsuperhydrophilicswitchingoflignocellulosicpapersurfacewithmodifiednanotio2coating
AT xiayuluan achievingreversiblesuperhydrophobicsuperhydrophilicswitchingoflignocellulosicpapersurfacewithmodifiednanotio2coating
AT zhanhuahao achievingreversiblesuperhydrophobicsuperhydrophilicswitchingoflignocellulosicpapersurfacewithmodifiednanotio2coating
AT yufengwang achievingreversiblesuperhydrophobicsuperhydrophilicswitchingoflignocellulosicpapersurfacewithmodifiednanotio2coating