Poly[tetraaqua-μ3-pyridine-3,5-dicarboxylato-strontium(II)]
The reaction of strontium(II) nitrate with the proton-transfer compound (pdaH2)(py-3,5-dc)·H2O (where pda = propane-1,3-diamine and py-3,5-dcH2 = pyridine-3,5-dicarboxylic acid) leads to the formation of the title polymeric compound, [Sr(C7H3NO4)(H2O)4]n. The propane-1,3-diaminium cation is...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808001335 |
| _version_ | 1798024489373532160 |
|---|---|
| author | Shirin Daneshvar Mohammad Ghadermazi Zohreh Derikvand Andya Nemati Hossein Aghabozorg |
| author_facet | Shirin Daneshvar Mohammad Ghadermazi Zohreh Derikvand Andya Nemati Hossein Aghabozorg |
| author_sort | Shirin Daneshvar |
| collection | DOAJ |
| description | The reaction of strontium(II) nitrate with the proton-transfer compound (pdaH2)(py-3,5-dc)·H2O (where pda = propane-1,3-diamine and py-3,5-dcH2 = pyridine-3,5-dicarboxylic acid) leads to the formation of the title polymeric compound, [Sr(C7H3NO4)(H2O)4]n. The propane-1,3-diaminium cation is not incorporated in this crystal structure. The SrII atom lies on an inversion centre and is eight-coordinated by four O atoms from three py-3,5-dc ligands and four O atoms from four coordinated water molecules. The coordination polyhedron of the SrII atom is a distorted dodecahedron. These binuclear units are connected via the carboxylate O atoms to build a one-dimensional polymeric chain. In the crystal structure, non-covalant interactions consisting of hydrogen bonds (X—H...O, with X = O and C) and π–π stacking interactions [3.4604 (19) Å] connect the various components to form a supramolecular structure. |
| first_indexed | 2024-04-11T18:03:14Z |
| format | Article |
| id | doaj.art-98dc6e7deb9049ce94c62a8ebc2d82da |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:03:14Z |
| publishDate | 2008-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-98dc6e7deb9049ce94c62a8ebc2d82da2022-12-22T04:10:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m376m37610.1107/S1600536808001335Poly[tetraaqua-μ3-pyridine-3,5-dicarboxylato-strontium(II)]Shirin DaneshvarMohammad GhadermaziZohreh DerikvandAndya NematiHossein AghabozorgThe reaction of strontium(II) nitrate with the proton-transfer compound (pdaH2)(py-3,5-dc)·H2O (where pda = propane-1,3-diamine and py-3,5-dcH2 = pyridine-3,5-dicarboxylic acid) leads to the formation of the title polymeric compound, [Sr(C7H3NO4)(H2O)4]n. The propane-1,3-diaminium cation is not incorporated in this crystal structure. The SrII atom lies on an inversion centre and is eight-coordinated by four O atoms from three py-3,5-dc ligands and four O atoms from four coordinated water molecules. The coordination polyhedron of the SrII atom is a distorted dodecahedron. These binuclear units are connected via the carboxylate O atoms to build a one-dimensional polymeric chain. In the crystal structure, non-covalant interactions consisting of hydrogen bonds (X—H...O, with X = O and C) and π–π stacking interactions [3.4604 (19) Å] connect the various components to form a supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S1600536808001335 |
| spellingShingle | Shirin Daneshvar Mohammad Ghadermazi Zohreh Derikvand Andya Nemati Hossein Aghabozorg Poly[tetraaqua-μ3-pyridine-3,5-dicarboxylato-strontium(II)] Acta Crystallographica Section E |
| title | Poly[tetraaqua-μ3-pyridine-3,5-dicarboxylato-strontium(II)] |
| title_full | Poly[tetraaqua-μ3-pyridine-3,5-dicarboxylato-strontium(II)] |
| title_fullStr | Poly[tetraaqua-μ3-pyridine-3,5-dicarboxylato-strontium(II)] |
| title_full_unstemmed | Poly[tetraaqua-μ3-pyridine-3,5-dicarboxylato-strontium(II)] |
| title_short | Poly[tetraaqua-μ3-pyridine-3,5-dicarboxylato-strontium(II)] |
| title_sort | poly tetraaqua 956 3 pyridine 3 5 dicarboxylato strontium ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808001335 |
| work_keys_str_mv | AT shirindaneshvar polytetraaqua9563pyridine35dicarboxylatostrontiumii AT mohammadghadermazi polytetraaqua9563pyridine35dicarboxylatostrontiumii AT zohrehderikvand polytetraaqua9563pyridine35dicarboxylatostrontiumii AT andyanemati polytetraaqua9563pyridine35dicarboxylatostrontiumii AT hosseinaghabozorg polytetraaqua9563pyridine35dicarboxylatostrontiumii |