AZOLIGANDS AS BRIDGED IN MACROCYCLIC DINICKEL COMPLEXES

The coordination chemistry of dinickel macrocyclic hexaamine-dithiophenolate complexes of Robson-type with azoligands is presented in this microreview. All complexes have been characterised by IR-,UV/Visspectroscopy, and X-ray crystallography. The bioctahedral transition metal complexes of the typ...

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Main Author: Vasile Lozan
Format: Article
Language:English
Published: Academy of Sciences of Moldova, Institute of Chemistry 2010-06-01
Series:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:
Online Access:http://www.cjm.asm.md/sites/default/files/article_files/7-23%20Lozan.pdf
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author Vasile Lozan
author_facet Vasile Lozan
author_sort Vasile Lozan
collection DOAJ
description The coordination chemistry of dinickel macrocyclic hexaamine-dithiophenolate complexes of Robson-type with azoligands is presented in this microreview. All complexes have been characterised by IR-,UV/Visspectroscopy, and X-ray crystallography. The bioctahedral transition metal complexes of the type [(L6)Ni2(μ-L')]+ exhibit a rich coordination chemistry since the active coordination site L' is accessible for a wide range of exogenous coligands.
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2345-1688
language English
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spelling doaj.art-98ee1fa06d47487e8cb5c47c6c0b187d2022-12-21T22:21:41ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882010-06-0151723AZOLIGANDS AS BRIDGED IN MACROCYCLIC DINICKEL COMPLEXESVasile Lozan0Institute of Chemistry of Academy of Sciences of MoldovaThe coordination chemistry of dinickel macrocyclic hexaamine-dithiophenolate complexes of Robson-type with azoligands is presented in this microreview. All complexes have been characterised by IR-,UV/Visspectroscopy, and X-ray crystallography. The bioctahedral transition metal complexes of the type [(L6)Ni2(μ-L')]+ exhibit a rich coordination chemistry since the active coordination site L' is accessible for a wide range of exogenous coligands.http://www.cjm.asm.md/sites/default/files/article_files/7-23%20Lozan.pdfcoordination chemistrystructuresazoligandsnickel macrocyclic complexesamino-thiophenolate ligands
spellingShingle Vasile Lozan
AZOLIGANDS AS BRIDGED IN MACROCYCLIC DINICKEL COMPLEXES
Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
coordination chemistry
structures
azoligands
nickel macrocyclic complexes
amino-thiophenolate ligands
title AZOLIGANDS AS BRIDGED IN MACROCYCLIC DINICKEL COMPLEXES
title_full AZOLIGANDS AS BRIDGED IN MACROCYCLIC DINICKEL COMPLEXES
title_fullStr AZOLIGANDS AS BRIDGED IN MACROCYCLIC DINICKEL COMPLEXES
title_full_unstemmed AZOLIGANDS AS BRIDGED IN MACROCYCLIC DINICKEL COMPLEXES
title_short AZOLIGANDS AS BRIDGED IN MACROCYCLIC DINICKEL COMPLEXES
title_sort azoligands as bridged in macrocyclic dinickel complexes
topic coordination chemistry
structures
azoligands
nickel macrocyclic complexes
amino-thiophenolate ligands
url http://www.cjm.asm.md/sites/default/files/article_files/7-23%20Lozan.pdf
work_keys_str_mv AT vasilelozan azoligandsasbridgedinmacrocyclicdinickelcomplexes