Functionalization of Carbon Nanotubes Surface by Aryl Groups: A Review
The review is devoted to the methods of introducing aryl functional groups to the CNT surface. Arylated nanotubes are characterized by extended solubility, and are widely used in photoelectronics, semiconductor technology, and bioelectrocatalysis. The main emphasis is on arylation methods according...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-05-01
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| Series: | Nanomaterials |
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| Online Access: | https://www.mdpi.com/2079-4991/13/10/1630 |
| _version_ | 1797598863558705152 |
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| author | Pavel Oskin Iraida Demkina Elena Dmitrieva Sergey Alferov |
| author_facet | Pavel Oskin Iraida Demkina Elena Dmitrieva Sergey Alferov |
| author_sort | Pavel Oskin |
| collection | DOAJ |
| description | The review is devoted to the methods of introducing aryl functional groups to the CNT surface. Arylated nanotubes are characterized by extended solubility, and are widely used in photoelectronics, semiconductor technology, and bioelectrocatalysis. The main emphasis is on arylation methods according to the radical mechanism, such as the Gomberg–Bachmann and Billups reactions, and the decomposition of peroxides. At the same time, less common approaches are also considered. For each of the described reactions, a mechanism is presented in the context of the effect on the properties of functionalized nanotubes and their application. As a result, this will allow us to choose the optimal modification method for specific practical tasks. |
| first_indexed | 2024-03-11T03:26:37Z |
| format | Article |
| id | doaj.art-98f43bc480534fb1b1d03c3cd5643068 |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-03-11T03:26:37Z |
| publishDate | 2023-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Nanomaterials |
| spelling | doaj.art-98f43bc480534fb1b1d03c3cd56430682023-11-18T02:42:28ZengMDPI AGNanomaterials2079-49912023-05-011310163010.3390/nano13101630Functionalization of Carbon Nanotubes Surface by Aryl Groups: A ReviewPavel Oskin0Iraida Demkina1Elena Dmitrieva2Sergey Alferov3Laboratory of Ecological and Medical Biotechnology, Tula State University, Friedrich Engels Street 157, 300012 Tula, RussiaChemistry Department, Tula State University, Pr. Lenina 92, 300012 Tula, RussiaChemistry Department, Tula State University, Pr. Lenina 92, 300012 Tula, RussiaLaboratory of Ecological and Medical Biotechnology, Tula State University, Friedrich Engels Street 157, 300012 Tula, RussiaThe review is devoted to the methods of introducing aryl functional groups to the CNT surface. Arylated nanotubes are characterized by extended solubility, and are widely used in photoelectronics, semiconductor technology, and bioelectrocatalysis. The main emphasis is on arylation methods according to the radical mechanism, such as the Gomberg–Bachmann and Billups reactions, and the decomposition of peroxides. At the same time, less common approaches are also considered. For each of the described reactions, a mechanism is presented in the context of the effect on the properties of functionalized nanotubes and their application. As a result, this will allow us to choose the optimal modification method for specific practical tasks.https://www.mdpi.com/2079-4991/13/10/1630carbon nanomaterialssemiconductor nanotubesmetal nanotubescarbon nanotube functionalizationGomberg–Bachmann reactionBillups reaction |
| spellingShingle | Pavel Oskin Iraida Demkina Elena Dmitrieva Sergey Alferov Functionalization of Carbon Nanotubes Surface by Aryl Groups: A Review Nanomaterials carbon nanomaterials semiconductor nanotubes metal nanotubes carbon nanotube functionalization Gomberg–Bachmann reaction Billups reaction |
| title | Functionalization of Carbon Nanotubes Surface by Aryl Groups: A Review |
| title_full | Functionalization of Carbon Nanotubes Surface by Aryl Groups: A Review |
| title_fullStr | Functionalization of Carbon Nanotubes Surface by Aryl Groups: A Review |
| title_full_unstemmed | Functionalization of Carbon Nanotubes Surface by Aryl Groups: A Review |
| title_short | Functionalization of Carbon Nanotubes Surface by Aryl Groups: A Review |
| title_sort | functionalization of carbon nanotubes surface by aryl groups a review |
| topic | carbon nanomaterials semiconductor nanotubes metal nanotubes carbon nanotube functionalization Gomberg–Bachmann reaction Billups reaction |
| url | https://www.mdpi.com/2079-4991/13/10/1630 |
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