Bromidobis[3-(1H-pyrazol-1-yl-κN2)propionamide-κO]copper(II) bromide methanol monosolvate
The title copper(II) N-pyrazolylpropanamide (PPA) complex, [CuBr(PPA)2]Br, was obtained in 78% yield by treatment of CuBr2 with an excess of the ligand in methanol. Crystallization from the mother liquid afforded the title compound, i.e. the methanol solvate [CuBr(C6H9N3O)2]Br·CH3OH or...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812038111 |
| _version_ | 1819107616947699712 |
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| author | Thomas Wagner Cristian G. Hrib Volker Lorenz Frank T. Edelmann John W. Gilje |
| author_facet | Thomas Wagner Cristian G. Hrib Volker Lorenz Frank T. Edelmann John W. Gilje |
| author_sort | Thomas Wagner |
| collection | DOAJ |
| description | The title copper(II) N-pyrazolylpropanamide (PPA) complex, [CuBr(PPA)2]Br, was obtained in 78% yield by treatment of CuBr2 with an excess of the ligand in methanol. Crystallization from the mother liquid afforded the title compound, i.e. the methanol solvate [CuBr(C6H9N3O)2]Br·CH3OH or [CuBr(PPA)2]Br·MeOH, as bright green crystals. In the solid state, the title salt comprises isolated [CuBr(PPA)2]+ cations, separated bromide ions and methanol of crystallization. In the cation, the central CuII ion is coordinated by two N,O-chelating PPA ligands and one Br− ion. The coordination geometry around the CuII ion is distorted trigonal–bipyramidal with the bromide ligand and the amide O atoms occupying the equatorial positions [Cu—Br = 2.4443 (4) Å; Cu—O = 2.035 (2) and 2.179 (2) Å], while the pyrazole N atoms coordinate in the axial positions [Cu—N = 1.975 (2) and 1.976 (2) Å]. In the crystal, the three constituents are linked by N—H...Br, O—H...Br, and N—H...O hydrogen bonds, forming a three-dimensional network. |
| first_indexed | 2024-12-22T02:56:53Z |
| format | Article |
| id | doaj.art-99098b1faf38459685c169939c1970c0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:56:53Z |
| publishDate | 2012-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-99098b1faf38459685c169939c1970c02022-12-21T18:41:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810m1253m125410.1107/S1600536812038111Bromidobis[3-(1H-pyrazol-1-yl-κN2)propionamide-κO]copper(II) bromide methanol monosolvateThomas WagnerCristian G. HribVolker LorenzFrank T. EdelmannJohn W. GiljeThe title copper(II) N-pyrazolylpropanamide (PPA) complex, [CuBr(PPA)2]Br, was obtained in 78% yield by treatment of CuBr2 with an excess of the ligand in methanol. Crystallization from the mother liquid afforded the title compound, i.e. the methanol solvate [CuBr(C6H9N3O)2]Br·CH3OH or [CuBr(PPA)2]Br·MeOH, as bright green crystals. In the solid state, the title salt comprises isolated [CuBr(PPA)2]+ cations, separated bromide ions and methanol of crystallization. In the cation, the central CuII ion is coordinated by two N,O-chelating PPA ligands and one Br− ion. The coordination geometry around the CuII ion is distorted trigonal–bipyramidal with the bromide ligand and the amide O atoms occupying the equatorial positions [Cu—Br = 2.4443 (4) Å; Cu—O = 2.035 (2) and 2.179 (2) Å], while the pyrazole N atoms coordinate in the axial positions [Cu—N = 1.975 (2) and 1.976 (2) Å]. In the crystal, the three constituents are linked by N—H...Br, O—H...Br, and N—H...O hydrogen bonds, forming a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536812038111 |
| spellingShingle | Thomas Wagner Cristian G. Hrib Volker Lorenz Frank T. Edelmann John W. Gilje Bromidobis[3-(1H-pyrazol-1-yl-κN2)propionamide-κO]copper(II) bromide methanol monosolvate Acta Crystallographica Section E |
| title | Bromidobis[3-(1H-pyrazol-1-yl-κN2)propionamide-κO]copper(II) bromide methanol monosolvate |
| title_full | Bromidobis[3-(1H-pyrazol-1-yl-κN2)propionamide-κO]copper(II) bromide methanol monosolvate |
| title_fullStr | Bromidobis[3-(1H-pyrazol-1-yl-κN2)propionamide-κO]copper(II) bromide methanol monosolvate |
| title_full_unstemmed | Bromidobis[3-(1H-pyrazol-1-yl-κN2)propionamide-κO]copper(II) bromide methanol monosolvate |
| title_short | Bromidobis[3-(1H-pyrazol-1-yl-κN2)propionamide-κO]copper(II) bromide methanol monosolvate |
| title_sort | bromidobis 3 1h pyrazol 1 yl amp 954 n2 propionamide amp 954 o copper ii bromide methanol monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812038111 |
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