Crystal structure of dichlorido{4-[(E)-(methoxyimino-κN)methyl]-1,3-thiazol-2-amine-κN3}palladium(II)
In the title compound, [PdCl2(C5H7N3OS)], the PdII atom adopts a distorted square-planar coordination sphere defined by two N atoms of the bidentate ligand and two Cl atoms. The mean deviation from the coordination plane is 0.029 Å. The methyl group is not coplanar with the plane of the metallacycle...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-01-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989014026619 |
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| author | Viktorita V. Dyakonenko Olga O. Zholob Svitlana I. Orysyk Vasily I. Pekhnyo |
| author_facet | Viktorita V. Dyakonenko Olga O. Zholob Svitlana I. Orysyk Vasily I. Pekhnyo |
| author_sort | Viktorita V. Dyakonenko |
| collection | DOAJ |
| description | In the title compound, [PdCl2(C5H7N3OS)], the PdII atom adopts a distorted square-planar coordination sphere defined by two N atoms of the bidentate ligand and two Cl atoms. The mean deviation from the coordination plane is 0.029 Å. The methyl group is not coplanar with the plane of the metallacycle [torsion angle C—O—N—C = 20.2 (4)°]. Steric repulsion between the methyl group and atoms of the metallacycle is manifested by shortened intramolecular H...C contacts of 2.27, 2.38 and 2.64 Å, as compared with the sum of the van der Waals radii of 2.87 Å. The amino group participates via one H atom in the formation of an intramolecular N—H...Cl hydrogen bond. In the crystal, the other H atom of the amino group links molecules via bifurcated N—H...(Cl,O) hydrogen bonds into chains parallel to [001]. |
| first_indexed | 2024-12-20T23:04:43Z |
| format | Article |
| id | doaj.art-990a139c0ba5426db3684723bf48a500 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T23:04:43Z |
| publishDate | 2015-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-990a139c0ba5426db3684723bf48a5002022-12-21T19:23:54ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-01-01711m10m1110.1107/S2056989014026619wm5096Crystal structure of dichlorido{4-[(E)-(methoxyimino-κN)methyl]-1,3-thiazol-2-amine-κN3}palladium(II)Viktorita V. Dyakonenko0Olga O. Zholob1Svitlana I. Orysyk2Vasily I. Pekhnyo3State Scientific "Institution Institute for Single Crystals", National Academy of Science of Ukraine, 60 Lenina ave., Kharkiv 61001, UkraineV.I. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680 Kyiv, UkraineV.I. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680 Kyiv, UkraineV.I. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680 Kyiv, UkraineIn the title compound, [PdCl2(C5H7N3OS)], the PdII atom adopts a distorted square-planar coordination sphere defined by two N atoms of the bidentate ligand and two Cl atoms. The mean deviation from the coordination plane is 0.029 Å. The methyl group is not coplanar with the plane of the metallacycle [torsion angle C—O—N—C = 20.2 (4)°]. Steric repulsion between the methyl group and atoms of the metallacycle is manifested by shortened intramolecular H...C contacts of 2.27, 2.38 and 2.64 Å, as compared with the sum of the van der Waals radii of 2.87 Å. The amino group participates via one H atom in the formation of an intramolecular N—H...Cl hydrogen bond. In the crystal, the other H atom of the amino group links molecules via bifurcated N—H...(Cl,O) hydrogen bonds into chains parallel to [001].http://scripts.iucr.org/cgi-bin/paper?S2056989014026619crystal structurepalladiummulti-functional ligand4-[(methoxyimino)methyl]-1,3-thiazol-2-amine (MIMTA) |
| spellingShingle | Viktorita V. Dyakonenko Olga O. Zholob Svitlana I. Orysyk Vasily I. Pekhnyo Crystal structure of dichlorido{4-[(E)-(methoxyimino-κN)methyl]-1,3-thiazol-2-amine-κN3}palladium(II) Acta Crystallographica Section E: Crystallographic Communications crystal structure palladium multi-functional ligand 4-[(methoxyimino)methyl]-1,3-thiazol-2-amine (MIMTA) |
| title | Crystal structure of dichlorido{4-[(E)-(methoxyimino-κN)methyl]-1,3-thiazol-2-amine-κN3}palladium(II) |
| title_full | Crystal structure of dichlorido{4-[(E)-(methoxyimino-κN)methyl]-1,3-thiazol-2-amine-κN3}palladium(II) |
| title_fullStr | Crystal structure of dichlorido{4-[(E)-(methoxyimino-κN)methyl]-1,3-thiazol-2-amine-κN3}palladium(II) |
| title_full_unstemmed | Crystal structure of dichlorido{4-[(E)-(methoxyimino-κN)methyl]-1,3-thiazol-2-amine-κN3}palladium(II) |
| title_short | Crystal structure of dichlorido{4-[(E)-(methoxyimino-κN)methyl]-1,3-thiazol-2-amine-κN3}palladium(II) |
| title_sort | crystal structure of dichlorido 4 e methoxyimino κn methyl 1 3 thiazol 2 amine κn3 palladium ii |
| topic | crystal structure palladium multi-functional ligand 4-[(methoxyimino)methyl]-1,3-thiazol-2-amine (MIMTA) |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989014026619 |
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