Shear Thinning in the Prandtl Model and Its Relation to Generalized Newtonian Fluids

The Prandtl model is certainly the simplest and most generic microscopic model describing solid friction. It consists of a single, thermalized atom attached to a spring, which is dragged past a sinusoidal potential representing the surface energy corrugation of a counterface. While it was primarily...

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Main Author: Martin H. Müser
Format: Article
Language:English
Published: MDPI AG 2020-03-01
Series:Lubricants
Subjects:
Online Access:https://www.mdpi.com/2075-4442/8/4/38
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author Martin H. Müser
author_facet Martin H. Müser
author_sort Martin H. Müser
collection DOAJ
description The Prandtl model is certainly the simplest and most generic microscopic model describing solid friction. It consists of a single, thermalized atom attached to a spring, which is dragged past a sinusoidal potential representing the surface energy corrugation of a counterface. While it was primarily introduced to rationalize how Coulomb&#8217;s friction law can arise from small-scale instabilities, Prandtl argued that his model also describes the shear thinning of liquids. Given its success regarding the interpretation of atomic-force-microscopy experiments, surprisingly little attention has been paid to the question how the Prandtl model relates to fluid rheology. Analyzing its Langevin and Brownian dynamics, we show that the Prandtl model produces friction&#8722;velocity relationships, which, converted to a dependence of effective (excess) viscosity on shear rate <inline-formula> <math display="inline"> <semantics> <mrow> <mi>&#951;</mi> <mo>(</mo> <mover accent="true"> <mi>&#947;</mi> <mo>˙</mo> </mover> <mo>)</mo> </mrow> </semantics> </math> </inline-formula>, is strikingly similar to the Carreau&#8722;Yasuda (CY) relation, which is obeyed by many non-Newtonian liquids. The two dimensionless parameters in the CY relation are found to span a broad range of values. When thermal energy is small compared to the corrugation of the sinusoidal potential, the leading-order <inline-formula> <math display="inline"> <semantics> <msup> <mover accent="true"> <mi>&#947;</mi> <mo>˙</mo> </mover> <mn>2</mn> </msup> </semantics> </math> </inline-formula> corrections to the equilibrium viscosity only matter in the initial part of the cross-over from Stokes friction to the regime, where <inline-formula> <math display="inline"> <semantics> <mi>&#951;</mi> </semantics> </math> </inline-formula> obeys approximately a sublinear power law of <inline-formula> <math display="inline"> <semantics> <mrow> <mn>1</mn> <mo>/</mo> <mover accent="true"> <mi>&#947;</mi> <mo>˙</mo> </mover> </mrow> </semantics> </math> </inline-formula>.
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spelling doaj.art-990d9a466625488c96a68f15644bc6a72022-12-22T04:19:51ZengMDPI AGLubricants2075-44422020-03-01843810.3390/lubricants8040038lubricants8040038Shear Thinning in the Prandtl Model and Its Relation to Generalized Newtonian FluidsMartin H. Müser0Department of Materials Science and Engineering, Universität des Saarlandes, 66123 Saarbrücken, GermanyThe Prandtl model is certainly the simplest and most generic microscopic model describing solid friction. It consists of a single, thermalized atom attached to a spring, which is dragged past a sinusoidal potential representing the surface energy corrugation of a counterface. While it was primarily introduced to rationalize how Coulomb&#8217;s friction law can arise from small-scale instabilities, Prandtl argued that his model also describes the shear thinning of liquids. Given its success regarding the interpretation of atomic-force-microscopy experiments, surprisingly little attention has been paid to the question how the Prandtl model relates to fluid rheology. Analyzing its Langevin and Brownian dynamics, we show that the Prandtl model produces friction&#8722;velocity relationships, which, converted to a dependence of effective (excess) viscosity on shear rate <inline-formula> <math display="inline"> <semantics> <mrow> <mi>&#951;</mi> <mo>(</mo> <mover accent="true"> <mi>&#947;</mi> <mo>˙</mo> </mover> <mo>)</mo> </mrow> </semantics> </math> </inline-formula>, is strikingly similar to the Carreau&#8722;Yasuda (CY) relation, which is obeyed by many non-Newtonian liquids. The two dimensionless parameters in the CY relation are found to span a broad range of values. When thermal energy is small compared to the corrugation of the sinusoidal potential, the leading-order <inline-formula> <math display="inline"> <semantics> <msup> <mover accent="true"> <mi>&#947;</mi> <mo>˙</mo> </mover> <mn>2</mn> </msup> </semantics> </math> </inline-formula> corrections to the equilibrium viscosity only matter in the initial part of the cross-over from Stokes friction to the regime, where <inline-formula> <math display="inline"> <semantics> <mi>&#951;</mi> </semantics> </math> </inline-formula> obeys approximately a sublinear power law of <inline-formula> <math display="inline"> <semantics> <mrow> <mn>1</mn> <mo>/</mo> <mover accent="true"> <mi>&#947;</mi> <mo>˙</mo> </mover> </mrow> </semantics> </math> </inline-formula>.https://www.mdpi.com/2075-4442/8/4/38frictionviscosityshear thinningtheorymolecular dynamicsfokker planck equationblood flow
spellingShingle Martin H. Müser
Shear Thinning in the Prandtl Model and Its Relation to Generalized Newtonian Fluids
Lubricants
friction
viscosity
shear thinning
theory
molecular dynamics
fokker planck equation
blood flow
title Shear Thinning in the Prandtl Model and Its Relation to Generalized Newtonian Fluids
title_full Shear Thinning in the Prandtl Model and Its Relation to Generalized Newtonian Fluids
title_fullStr Shear Thinning in the Prandtl Model and Its Relation to Generalized Newtonian Fluids
title_full_unstemmed Shear Thinning in the Prandtl Model and Its Relation to Generalized Newtonian Fluids
title_short Shear Thinning in the Prandtl Model and Its Relation to Generalized Newtonian Fluids
title_sort shear thinning in the prandtl model and its relation to generalized newtonian fluids
topic friction
viscosity
shear thinning
theory
molecular dynamics
fokker planck equation
blood flow
url https://www.mdpi.com/2075-4442/8/4/38
work_keys_str_mv AT martinhmuser shearthinningintheprandtlmodelanditsrelationtogeneralizednewtonianfluids