Crystal structure of the η4-ketimine titanium complex (diphenylamido-κN){3-methyl-6-[(4-methylphenyl)(phenylazanidyl)methylidene]cyclohexa-2,4-dien-1-yl-κ2N,C1}(η5-pentamethylcyclopentadienyl)titanium(IV)

Crystal structure of the η4-ketimine titanium complex (diphenylamido-κN){3-methyl-6-[(4-methylphenyl)(phenylazanidyl)methylidene]cyclohexa-2,4-dien-1-yl-κ2N,C1}(η5-pentamethylcyclopentadienyl)titanium(IV)

The molecular structure of the title titanium(IV) half-sandwich complex, [Ti(η5-C10H15)(η4-C21H19N)(C12H10N)], shows a three-legged piano-stool geometry at the central TiIV atom, comprising of one pentamethylcyclopentadienyl ligand, one bidentate ketimine ligand in an η4-coordination mode and one mo...

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Bibliographic Details
Main Authors: Malte Fischer, Marc Schmidtmann, Rüdiger Beckhaus
Format: Article
Language:English
Published: International Union of Crystallography 2018-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
titanium
η4-ketimine complex
half-sandwich complex
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017017455

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