Corn Starch-Chitosan Nanocomposite Film Containing Nettle Essential Oil Nanoemulsions and Starch Nanocrystals: Optimization and Characterization

In the current study, nanocomposite films were produced based on corn starch:chitosan (CS:CH) biopolymers and the films were reinforced with nettle essential oil nanoemulsions (NEONEs) and starch nanocrystals (SNCs) to improve their physicochemical and mechanical properties. CS: CH at 70:30, 50:50,...

Full description

Bibliographic Details
Main Authors: Fatemeh Kalateh-Seifari, Shima Yousefi, Hamed Ahari, Seyed Hedayat Hosseini
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/13/13/2113
_version_ 1797528608789495808
author Fatemeh Kalateh-Seifari
Shima Yousefi
Hamed Ahari
Seyed Hedayat Hosseini
author_facet Fatemeh Kalateh-Seifari
Shima Yousefi
Hamed Ahari
Seyed Hedayat Hosseini
author_sort Fatemeh Kalateh-Seifari
collection DOAJ
description In the current study, nanocomposite films were produced based on corn starch:chitosan (CS:CH) biopolymers and the films were reinforced with nettle essential oil nanoemulsions (NEONEs) and starch nanocrystals (SNCs) to improve their physicochemical and mechanical properties. CS: CH at 70:30, 50:50, and 30:70 (<i>w</i>/<i>w</i>) ratios; SNCs at 2, 4, and 6% (<i>w</i>/<i>w</i>), and NEONEs at 0.5, 1, and 1.5% (<i>w</i>/<i>w</i>) were selected as variables. Then the various physical and mechanical attributes of chitosan-starch blended film containing SNCs and NEONEs were optimized using response surface methodology. The desirability function technique for the second-order polynomial models revealed that the following results could be achieved as the optimized treatment: water solubility of 51.56%; water absorption capacity of 128.75%; surface color of L (89.60), a (0.96), and b (1.90); water vapor permeability of 0.335 g/s Pa m, oxygen permeability of 2.60 cm<sup>3</sup> μm/m<sup>2</sup> d kPa; thickness of 154.41 µm, elongation at break of 53.54%; and tensile strength of 0.20 MPa at CS:CH of 38:62, SNC of 6.0%, and NEONEs of 0.41%. The nanocomposite film obtained can be employed as a novel biofunctional film with boosted physical mechanical and physical characteristics for food packaging applications.
first_indexed 2024-03-10T10:00:51Z
format Article
id doaj.art-993a6020e8744d0a8941ed1c7ca46ba1
institution Directory Open Access Journal
issn 2073-4360
language English
last_indexed 2024-03-10T10:00:51Z
publishDate 2021-06-01
publisher MDPI AG
record_format Article
series Polymers
spelling doaj.art-993a6020e8744d0a8941ed1c7ca46ba12023-11-22T01:58:24ZengMDPI AGPolymers2073-43602021-06-011313211310.3390/polym13132113Corn Starch-Chitosan Nanocomposite Film Containing Nettle Essential Oil Nanoemulsions and Starch Nanocrystals: Optimization and CharacterizationFatemeh Kalateh-Seifari0Shima Yousefi1Hamed Ahari2Seyed Hedayat Hosseini3Department of Agriculture and Food Science, Science and Research Branch, Islamic Azad University, Tehran 476714171, IranDepartment of Agriculture and Food Science, Science and Research Branch, Islamic Azad University, Tehran 476714171, IranDepartment of Agriculture and Food Science, Science and Research Branch, Islamic Azad University, Tehran 476714171, IranDepartment of Food Science and Technology, Shahid Beheshti University of Medical Science, Tehran 1983969411, IranIn the current study, nanocomposite films were produced based on corn starch:chitosan (CS:CH) biopolymers and the films were reinforced with nettle essential oil nanoemulsions (NEONEs) and starch nanocrystals (SNCs) to improve their physicochemical and mechanical properties. CS: CH at 70:30, 50:50, and 30:70 (<i>w</i>/<i>w</i>) ratios; SNCs at 2, 4, and 6% (<i>w</i>/<i>w</i>), and NEONEs at 0.5, 1, and 1.5% (<i>w</i>/<i>w</i>) were selected as variables. Then the various physical and mechanical attributes of chitosan-starch blended film containing SNCs and NEONEs were optimized using response surface methodology. The desirability function technique for the second-order polynomial models revealed that the following results could be achieved as the optimized treatment: water solubility of 51.56%; water absorption capacity of 128.75%; surface color of L (89.60), a (0.96), and b (1.90); water vapor permeability of 0.335 g/s Pa m, oxygen permeability of 2.60 cm<sup>3</sup> μm/m<sup>2</sup> d kPa; thickness of 154.41 µm, elongation at break of 53.54%; and tensile strength of 0.20 MPa at CS:CH of 38:62, SNC of 6.0%, and NEONEs of 0.41%. The nanocomposite film obtained can be employed as a novel biofunctional film with boosted physical mechanical and physical characteristics for food packaging applications.https://www.mdpi.com/2073-4360/13/13/2113chitosan-starch compositenettle essential oilstarch nanocrystalsoptimization
spellingShingle Fatemeh Kalateh-Seifari
Shima Yousefi
Hamed Ahari
Seyed Hedayat Hosseini
Corn Starch-Chitosan Nanocomposite Film Containing Nettle Essential Oil Nanoemulsions and Starch Nanocrystals: Optimization and Characterization
Polymers
chitosan-starch composite
nettle essential oil
starch nanocrystals
optimization
title Corn Starch-Chitosan Nanocomposite Film Containing Nettle Essential Oil Nanoemulsions and Starch Nanocrystals: Optimization and Characterization
title_full Corn Starch-Chitosan Nanocomposite Film Containing Nettle Essential Oil Nanoemulsions and Starch Nanocrystals: Optimization and Characterization
title_fullStr Corn Starch-Chitosan Nanocomposite Film Containing Nettle Essential Oil Nanoemulsions and Starch Nanocrystals: Optimization and Characterization
title_full_unstemmed Corn Starch-Chitosan Nanocomposite Film Containing Nettle Essential Oil Nanoemulsions and Starch Nanocrystals: Optimization and Characterization
title_short Corn Starch-Chitosan Nanocomposite Film Containing Nettle Essential Oil Nanoemulsions and Starch Nanocrystals: Optimization and Characterization
title_sort corn starch chitosan nanocomposite film containing nettle essential oil nanoemulsions and starch nanocrystals optimization and characterization
topic chitosan-starch composite
nettle essential oil
starch nanocrystals
optimization
url https://www.mdpi.com/2073-4360/13/13/2113
work_keys_str_mv AT fatemehkalatehseifari cornstarchchitosannanocompositefilmcontainingnettleessentialoilnanoemulsionsandstarchnanocrystalsoptimizationandcharacterization
AT shimayousefi cornstarchchitosannanocompositefilmcontainingnettleessentialoilnanoemulsionsandstarchnanocrystalsoptimizationandcharacterization
AT hamedahari cornstarchchitosannanocompositefilmcontainingnettleessentialoilnanoemulsionsandstarchnanocrystalsoptimizationandcharacterization
AT seyedhedayathosseini cornstarchchitosannanocompositefilmcontainingnettleessentialoilnanoemulsionsandstarchnanocrystalsoptimizationandcharacterization