CO2 electroreduction to multicarbon products in strongly acidic electrolyte via synergistically modulating the local microenvironment
Attaining high selectivity for CO2 electroreduction in acid is usually difficult due to competing hydrogen evolution. Here, the authors demonstrate efficient CO2 reduction to multicarbon products in strongly acidic medium (pH ≤ 1) on a porous Cu catalyst by combining confinement and cation effects....
| Main Authors: | , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-12-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-35415-x |
| _version_ | 1811301830982893568 |
|---|---|
| author | Zesong Ma Zhilong Yang Wenchuan Lai Qiyou Wang Yan Qiao Haolan Tao Cheng Lian Min Liu Chao Ma Anlian Pan Hongwen Huang |
| author_facet | Zesong Ma Zhilong Yang Wenchuan Lai Qiyou Wang Yan Qiao Haolan Tao Cheng Lian Min Liu Chao Ma Anlian Pan Hongwen Huang |
| author_sort | Zesong Ma |
| collection | DOAJ |
| description | Attaining high selectivity for CO2 electroreduction in acid is usually difficult due to competing hydrogen evolution. Here, the authors demonstrate efficient CO2 reduction to multicarbon products in strongly acidic medium (pH ≤ 1) on a porous Cu catalyst by combining confinement and cation effects. |
| first_indexed | 2024-04-13T07:16:58Z |
| format | Article |
| id | doaj.art-9966965c4e3a49abb38f9ead52ea6425 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-13T07:16:58Z |
| publishDate | 2022-12-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-9966965c4e3a49abb38f9ead52ea64252022-12-22T02:56:44ZengNature PortfolioNature Communications2041-17232022-12-0113111110.1038/s41467-022-35415-xCO2 electroreduction to multicarbon products in strongly acidic electrolyte via synergistically modulating the local microenvironmentZesong Ma0Zhilong Yang1Wenchuan Lai2Qiyou Wang3Yan Qiao4Haolan Tao5Cheng Lian6Min Liu7Chao Ma8Anlian Pan9Hongwen Huang10College of Materials Science and Engineering, Hunan UniversityCollege of Materials Science and Engineering, Hunan UniversityCollege of Materials Science and Engineering, Hunan UniversityState Key Laboratory of Powder Metallurgy, School of Physical and Electronics, Central South UniversityCollege of Materials Science and Engineering, Hunan UniversityState Key Laboratory of Chemical Engineering and Shanghai Engineering Research Center of Hierarchical Nanomaterials, School of Chemistry and Molecular Engineering, East China University of Science and TechnologyState Key Laboratory of Chemical Engineering and Shanghai Engineering Research Center of Hierarchical Nanomaterials, School of Chemistry and Molecular Engineering, East China University of Science and TechnologyState Key Laboratory of Powder Metallurgy, School of Physical and Electronics, Central South UniversityCollege of Materials Science and Engineering, Hunan UniversityCollege of Materials Science and Engineering, Hunan UniversityCollege of Materials Science and Engineering, Hunan UniversityAttaining high selectivity for CO2 electroreduction in acid is usually difficult due to competing hydrogen evolution. Here, the authors demonstrate efficient CO2 reduction to multicarbon products in strongly acidic medium (pH ≤ 1) on a porous Cu catalyst by combining confinement and cation effects.https://doi.org/10.1038/s41467-022-35415-x |
| spellingShingle | Zesong Ma Zhilong Yang Wenchuan Lai Qiyou Wang Yan Qiao Haolan Tao Cheng Lian Min Liu Chao Ma Anlian Pan Hongwen Huang CO2 electroreduction to multicarbon products in strongly acidic electrolyte via synergistically modulating the local microenvironment Nature Communications |
| title | CO2 electroreduction to multicarbon products in strongly acidic electrolyte via synergistically modulating the local microenvironment |
| title_full | CO2 electroreduction to multicarbon products in strongly acidic electrolyte via synergistically modulating the local microenvironment |
| title_fullStr | CO2 electroreduction to multicarbon products in strongly acidic electrolyte via synergistically modulating the local microenvironment |
| title_full_unstemmed | CO2 electroreduction to multicarbon products in strongly acidic electrolyte via synergistically modulating the local microenvironment |
| title_short | CO2 electroreduction to multicarbon products in strongly acidic electrolyte via synergistically modulating the local microenvironment |
| title_sort | co2 electroreduction to multicarbon products in strongly acidic electrolyte via synergistically modulating the local microenvironment |
| url | https://doi.org/10.1038/s41467-022-35415-x |
| work_keys_str_mv | AT zesongma co2electroreductiontomulticarbonproductsinstronglyacidicelectrolyteviasynergisticallymodulatingthelocalmicroenvironment AT zhilongyang co2electroreductiontomulticarbonproductsinstronglyacidicelectrolyteviasynergisticallymodulatingthelocalmicroenvironment AT wenchuanlai co2electroreductiontomulticarbonproductsinstronglyacidicelectrolyteviasynergisticallymodulatingthelocalmicroenvironment AT qiyouwang co2electroreductiontomulticarbonproductsinstronglyacidicelectrolyteviasynergisticallymodulatingthelocalmicroenvironment AT yanqiao co2electroreductiontomulticarbonproductsinstronglyacidicelectrolyteviasynergisticallymodulatingthelocalmicroenvironment AT haolantao co2electroreductiontomulticarbonproductsinstronglyacidicelectrolyteviasynergisticallymodulatingthelocalmicroenvironment AT chenglian co2electroreductiontomulticarbonproductsinstronglyacidicelectrolyteviasynergisticallymodulatingthelocalmicroenvironment AT minliu co2electroreductiontomulticarbonproductsinstronglyacidicelectrolyteviasynergisticallymodulatingthelocalmicroenvironment AT chaoma co2electroreductiontomulticarbonproductsinstronglyacidicelectrolyteviasynergisticallymodulatingthelocalmicroenvironment AT anlianpan co2electroreductiontomulticarbonproductsinstronglyacidicelectrolyteviasynergisticallymodulatingthelocalmicroenvironment AT hongwenhuang co2electroreductiontomulticarbonproductsinstronglyacidicelectrolyteviasynergisticallymodulatingthelocalmicroenvironment |