On the Enhancement of Energy Storage Performance in Modified Relaxor Ferroelectric Ceramics for Pulsed Power Applications

Relaxor-type ferroelectrics show important potential in energy storage fields due to their significantly enhanced energy performance and good temperature stability compared to normal ferroelectrics. Here, a novel, high-performance ternary composition, (0.4−x)BiFeO<sub>3</sub>-xBi(Mg<s...

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Main Authors: Hao Zhang, Zhe Zhu, Zhonghua Yao, Hua Hao, Lingyun Wang, Minghe Cao, Hanxing Liu
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/13/1/84
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author Hao Zhang
Zhe Zhu
Zhonghua Yao
Hua Hao
Lingyun Wang
Minghe Cao
Hanxing Liu
author_facet Hao Zhang
Zhe Zhu
Zhonghua Yao
Hua Hao
Lingyun Wang
Minghe Cao
Hanxing Liu
author_sort Hao Zhang
collection DOAJ
description Relaxor-type ferroelectrics show important potential in energy storage fields due to their significantly enhanced energy performance and good temperature stability compared to normal ferroelectrics. Here, a novel, high-performance ternary composition, (0.4−x)BiFeO<sub>3</sub>-xBi(Mg<sub>1/2</sub>Ti<sub>1/2</sub>)O<sub>3</sub>–0.6BaTiO<sub>3</sub> (x = 0.2, 0.25, 0.3, 0.35, 0.4), was designed by compositional modulation, which displays typical relaxor characteristics. The optimum energy storage properties can be attained at x = 0.35, accompanied by energy efficiency of 84.87%, a promising energy storage density of 2.3 J/cm<sup>3</sup> and good temperature stability of less than 10% over 20–160 °C. Moreover, the samples provide stable cycling fatigue after 10<sup>5</sup> cycles and a fast discharge time of <i>t</i><sub>0.9</sub> < 0.1 μs, indicative of promising applications in energy units.
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spelling doaj.art-9973db1217d947409d8214ae24a9b6692023-11-30T21:47:46ZengMDPI AGCrystals2073-43522023-01-011318410.3390/cryst13010084On the Enhancement of Energy Storage Performance in Modified Relaxor Ferroelectric Ceramics for Pulsed Power ApplicationsHao Zhang0Zhe Zhu1Zhonghua Yao2Hua Hao3Lingyun Wang4Minghe Cao5Hanxing Liu6School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, ChinaSchool of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, ChinaSchool of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, ChinaSchool of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, ChinaInstitute of Fluid Physics, CAEP, Mianyang 621900, ChinaSchool of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, ChinaSchool of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, ChinaRelaxor-type ferroelectrics show important potential in energy storage fields due to their significantly enhanced energy performance and good temperature stability compared to normal ferroelectrics. Here, a novel, high-performance ternary composition, (0.4−x)BiFeO<sub>3</sub>-xBi(Mg<sub>1/2</sub>Ti<sub>1/2</sub>)O<sub>3</sub>–0.6BaTiO<sub>3</sub> (x = 0.2, 0.25, 0.3, 0.35, 0.4), was designed by compositional modulation, which displays typical relaxor characteristics. The optimum energy storage properties can be attained at x = 0.35, accompanied by energy efficiency of 84.87%, a promising energy storage density of 2.3 J/cm<sup>3</sup> and good temperature stability of less than 10% over 20–160 °C. Moreover, the samples provide stable cycling fatigue after 10<sup>5</sup> cycles and a fast discharge time of <i>t</i><sub>0.9</sub> < 0.1 μs, indicative of promising applications in energy units.https://www.mdpi.com/2073-4352/13/1/84ceramicsperovskitesdielectricsenergy storagelead-free ceramics
spellingShingle Hao Zhang
Zhe Zhu
Zhonghua Yao
Hua Hao
Lingyun Wang
Minghe Cao
Hanxing Liu
On the Enhancement of Energy Storage Performance in Modified Relaxor Ferroelectric Ceramics for Pulsed Power Applications
Crystals
ceramics
perovskites
dielectrics
energy storage
lead-free ceramics
title On the Enhancement of Energy Storage Performance in Modified Relaxor Ferroelectric Ceramics for Pulsed Power Applications
title_full On the Enhancement of Energy Storage Performance in Modified Relaxor Ferroelectric Ceramics for Pulsed Power Applications
title_fullStr On the Enhancement of Energy Storage Performance in Modified Relaxor Ferroelectric Ceramics for Pulsed Power Applications
title_full_unstemmed On the Enhancement of Energy Storage Performance in Modified Relaxor Ferroelectric Ceramics for Pulsed Power Applications
title_short On the Enhancement of Energy Storage Performance in Modified Relaxor Ferroelectric Ceramics for Pulsed Power Applications
title_sort on the enhancement of energy storage performance in modified relaxor ferroelectric ceramics for pulsed power applications
topic ceramics
perovskites
dielectrics
energy storage
lead-free ceramics
url https://www.mdpi.com/2073-4352/13/1/84
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