First record of Oceanic Anoxic Event 2 in the Eastern Carpathians: implications for chemostratigraphic and biostratigraphic correlations

This study aims to investigate a marlstone and claystone succession located at the southern end of the Eastern Carpathians, a region where oceanic anoxic event 2 (OAE2) has not been pointed out so far. Toward the upper half of this succession, a 17-cm-thick black shale was identified. The investigat...

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Main Authors: Mihaela Melinte-Dobrinescu, Gabriel Ion, Eliza Anton, Vlad Apotrosoaei, Andrei Briceag, Constantin Lazăr
Format: Article
Language:English
Published: Frontiers Media S.A. 2023-09-01
Series:Frontiers in Earth Science
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/feart.2023.1155482/full
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author Mihaela Melinte-Dobrinescu
Mihaela Melinte-Dobrinescu
Gabriel Ion
Eliza Anton
Vlad Apotrosoaei
Vlad Apotrosoaei
Andrei Briceag
Constantin Lazăr
Constantin Lazăr
author_facet Mihaela Melinte-Dobrinescu
Mihaela Melinte-Dobrinescu
Gabriel Ion
Eliza Anton
Vlad Apotrosoaei
Vlad Apotrosoaei
Andrei Briceag
Constantin Lazăr
Constantin Lazăr
author_sort Mihaela Melinte-Dobrinescu
collection DOAJ
description This study aims to investigate a marlstone and claystone succession located at the southern end of the Eastern Carpathians, a region where oceanic anoxic event 2 (OAE2) has not been pointed out so far. Toward the upper half of this succession, a 17-cm-thick black shale was identified. The investigated depositional interval lies within the late Cenomanian–early Turonian, encompassing the UC3d up to UC7 nannofossil zones. The δ13C values fluctuated between 2.06‰ and 3.89‰, showing a positive isotope excursion that was assigned to OAE2. The δ13C isotope curve displays the following intervals: pre-excursion, first build-up, trough, second build-up, plateau, and post-excursion. Within the second build-up interval of OAE2, a substantial shift in CaCO3 values, accompanied by high concentrations of total organic carbon and a significant decline in the abundance and diversity of calcareous nannofossil assemblages, was observed. The nannofossil turnover related to OAE2 climax revealed predominance of Watznaueria barnesiae and temporary disappearance from the record of surface-water higher fertility taxa, such as Biscutum constans, Zeugrhabdotus erectus, and Discorhabdus ignotus. Above OAE2, peaks of Eprolithus floralis, followed by increased abundance of Eiffellithus turriseiffelii and Nannoconus spp., were identified. In the lower part of the studied succession (i.e., the upper Cenomanian UC3d nannofossil subzone), during the pre-excursion characterized by low δ13C values and less negative δ18O values, a small group of nannofossils more related to mid- and high-paleolatitudes, such as Crucibiscutum salebrosum, Repagulum parvidentatum, and Seribiscutum primitivum, is present, always showing a low abundance.
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spelling doaj.art-9976d0fe803449db8081ad8a9ed55e582023-09-06T17:43:22ZengFrontiers Media S.A.Frontiers in Earth Science2296-64632023-09-011110.3389/feart.2023.11554821155482First record of Oceanic Anoxic Event 2 in the Eastern Carpathians: implications for chemostratigraphic and biostratigraphic correlationsMihaela Melinte-Dobrinescu0Mihaela Melinte-Dobrinescu1Gabriel Ion2Eliza Anton3Vlad Apotrosoaei4Vlad Apotrosoaei5Andrei Briceag6Constantin Lazăr7Constantin Lazăr8National Institute of Marine Geology and Geo-ecology, Bucharest, RomaniaDoctoral School of Geology, University of Bucharest, Bucharest, RomaniaNational Institute of Marine Geology and Geo-ecology, Bucharest, RomaniaNational Institute of Marine Geology and Geo-ecology, Bucharest, RomaniaNational Institute of Marine Geology and Geo-ecology, Bucharest, RomaniaDoctoral School of Geology, University of Bucharest, Bucharest, RomaniaNational Institute of Marine Geology and Geo-ecology, Bucharest, RomaniaNational Institute of Marine Geology and Geo-ecology, Bucharest, RomaniaDoctoral School of Geology, University of Bucharest, Bucharest, RomaniaThis study aims to investigate a marlstone and claystone succession located at the southern end of the Eastern Carpathians, a region where oceanic anoxic event 2 (OAE2) has not been pointed out so far. Toward the upper half of this succession, a 17-cm-thick black shale was identified. The investigated depositional interval lies within the late Cenomanian–early Turonian, encompassing the UC3d up to UC7 nannofossil zones. The δ13C values fluctuated between 2.06‰ and 3.89‰, showing a positive isotope excursion that was assigned to OAE2. The δ13C isotope curve displays the following intervals: pre-excursion, first build-up, trough, second build-up, plateau, and post-excursion. Within the second build-up interval of OAE2, a substantial shift in CaCO3 values, accompanied by high concentrations of total organic carbon and a significant decline in the abundance and diversity of calcareous nannofossil assemblages, was observed. The nannofossil turnover related to OAE2 climax revealed predominance of Watznaueria barnesiae and temporary disappearance from the record of surface-water higher fertility taxa, such as Biscutum constans, Zeugrhabdotus erectus, and Discorhabdus ignotus. Above OAE2, peaks of Eprolithus floralis, followed by increased abundance of Eiffellithus turriseiffelii and Nannoconus spp., were identified. In the lower part of the studied succession (i.e., the upper Cenomanian UC3d nannofossil subzone), during the pre-excursion characterized by low δ13C values and less negative δ18O values, a small group of nannofossils more related to mid- and high-paleolatitudes, such as Crucibiscutum salebrosum, Repagulum parvidentatum, and Seribiscutum primitivum, is present, always showing a low abundance.https://www.frontiersin.org/articles/10.3389/feart.2023.1155482/fullCenomanian-Turonian boundarycalcareous nannofossilsδ13C positive excursionpaleoenvironmentpaleobiogeography
spellingShingle Mihaela Melinte-Dobrinescu
Mihaela Melinte-Dobrinescu
Gabriel Ion
Eliza Anton
Vlad Apotrosoaei
Vlad Apotrosoaei
Andrei Briceag
Constantin Lazăr
Constantin Lazăr
First record of Oceanic Anoxic Event 2 in the Eastern Carpathians: implications for chemostratigraphic and biostratigraphic correlations
Frontiers in Earth Science
Cenomanian-Turonian boundary
calcareous nannofossils
δ13C positive excursion
paleoenvironment
paleobiogeography
title First record of Oceanic Anoxic Event 2 in the Eastern Carpathians: implications for chemostratigraphic and biostratigraphic correlations
title_full First record of Oceanic Anoxic Event 2 in the Eastern Carpathians: implications for chemostratigraphic and biostratigraphic correlations
title_fullStr First record of Oceanic Anoxic Event 2 in the Eastern Carpathians: implications for chemostratigraphic and biostratigraphic correlations
title_full_unstemmed First record of Oceanic Anoxic Event 2 in the Eastern Carpathians: implications for chemostratigraphic and biostratigraphic correlations
title_short First record of Oceanic Anoxic Event 2 in the Eastern Carpathians: implications for chemostratigraphic and biostratigraphic correlations
title_sort first record of oceanic anoxic event 2 in the eastern carpathians implications for chemostratigraphic and biostratigraphic correlations
topic Cenomanian-Turonian boundary
calcareous nannofossils
δ13C positive excursion
paleoenvironment
paleobiogeography
url https://www.frontiersin.org/articles/10.3389/feart.2023.1155482/full
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