Error propagation in geochemical modeling of trace elements in two-component mixing

This study presents error propagation equations for geochemical modeling of trace elements during mixing of two components or end-members. These equations can be used to estimate uncertainties in the concentration of an element or ratio of two elements in the mixture of two components, as a function...

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Main Author: Surendra P. Verma
Format: Article
Language:English
Published: Universidad Nacional Autónoma de México, Instituto de Geofísica 1998-08-01
Series:Geofísica Internacional
Subjects:
Online Access:http://www.geofisica.unam.mx/unid_apoyo/editorial/publicaciones/investigacion/geofisica_internacional/anteriores/1998/04/verma.pdf
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author Surendra P. Verma
author_facet Surendra P. Verma
author_sort Surendra P. Verma
collection DOAJ
description This study presents error propagation equations for geochemical modeling of trace elements during mixing of two components or end-members. These equations can be used to estimate uncertainties in the concentration of an element or ratio of two elements in the mixture of two components, as a function of the initial measurement uncertainties. Several examples illustrate the use of these equations in geochemical modeling. Although as expected the element concentrations and their ratios in the mixture always lie between those of the two end-members, it is not the case with the corresponding measurement uncertainties. The %Rsd (Relative standard deviation expressed in %) of the concentration of an element in the mixture is never larger than the %Rsd of the component with larger uncertainty for that element, but can be smaller than the component with smaller uncertainty. Similarly, error propagation using actual element concentration data on basalt and sediment samples from the Cocos plate was carried out to further exemplify the use of these new equations and their importance in petrogenetic problems.
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spelling doaj.art-997d3d69f6454fc38982f2bc21aac9a22023-09-02T09:58:29ZengUniversidad Nacional Autónoma de México, Instituto de GeofísicaGeofísica Internacional0016-71691998-08-01374327338Error propagation in geochemical modeling of trace elements in two-component mixingSurendra P. VermaThis study presents error propagation equations for geochemical modeling of trace elements during mixing of two components or end-members. These equations can be used to estimate uncertainties in the concentration of an element or ratio of two elements in the mixture of two components, as a function of the initial measurement uncertainties. Several examples illustrate the use of these equations in geochemical modeling. Although as expected the element concentrations and their ratios in the mixture always lie between those of the two end-members, it is not the case with the corresponding measurement uncertainties. The %Rsd (Relative standard deviation expressed in %) of the concentration of an element in the mixture is never larger than the %Rsd of the component with larger uncertainty for that element, but can be smaller than the component with smaller uncertainty. Similarly, error propagation using actual element concentration data on basalt and sediment samples from the Cocos plate was carried out to further exemplify the use of these new equations and their importance in petrogenetic problems.http://www.geofisica.unam.mx/unid_apoyo/editorial/publicaciones/investigacion/geofisica_internacional/anteriores/1998/04/verma.pdfTrace element modelinggeochemistryerror propagationmeasurement uncertaintymixingMexicoCocos plate.
spellingShingle Surendra P. Verma
Error propagation in geochemical modeling of trace elements in two-component mixing
Geofísica Internacional
Trace element modeling
geochemistry
error propagation
measurement uncertainty
mixing
Mexico
Cocos plate.
title Error propagation in geochemical modeling of trace elements in two-component mixing
title_full Error propagation in geochemical modeling of trace elements in two-component mixing
title_fullStr Error propagation in geochemical modeling of trace elements in two-component mixing
title_full_unstemmed Error propagation in geochemical modeling of trace elements in two-component mixing
title_short Error propagation in geochemical modeling of trace elements in two-component mixing
title_sort error propagation in geochemical modeling of trace elements in two component mixing
topic Trace element modeling
geochemistry
error propagation
measurement uncertainty
mixing
Mexico
Cocos plate.
url http://www.geofisica.unam.mx/unid_apoyo/editorial/publicaciones/investigacion/geofisica_internacional/anteriores/1998/04/verma.pdf
work_keys_str_mv AT surendrapverma errorpropagationingeochemicalmodelingoftraceelementsintwocomponentmixing