Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) methanol solvate

In the structure of the title complex, [Cu(C8H4O4)(C12H8N2)(H2O)]·CH4O, the CuII ion is pentacoordinated in a tetragonal–pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formylsalicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal plane...

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Bibliographic Details
Main Authors: Zhaowen Yu, Ling Chang, Qingxia Cui, Wu Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807067967
Description
Summary:In the structure of the title complex, [Cu(C8H4O4)(C12H8N2)(H2O)]·CH4O, the CuII ion is pentacoordinated in a tetragonal–pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formylsalicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal plane, and a water O atom located at the apical site. The structure displays O—H...O hydrogen bonding.
ISSN:1600-5368