Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) methanol solvate
In the structure of the title complex, [Cu(C8H4O4)(C12H8N2)(H2O)]·CH4O, the CuII ion is pentacoordinated in a tetragonal–pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formylsalicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal plane...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
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International Union of Crystallography
2008-02-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807067967 |
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author | Zhaowen Yu Ling Chang Qingxia Cui Wu Zhang |
author_facet | Zhaowen Yu Ling Chang Qingxia Cui Wu Zhang |
author_sort | Zhaowen Yu |
collection | DOAJ |
description | In the structure of the title complex, [Cu(C8H4O4)(C12H8N2)(H2O)]·CH4O, the CuII ion is pentacoordinated in a tetragonal–pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formylsalicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal plane, and a water O atom located at the apical site. The structure displays O—H...O hydrogen bonding. |
first_indexed | 2024-12-13T10:42:46Z |
format | Article |
id | doaj.art-9984739315724dbe990f1f3744a12e1f |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-13T10:42:46Z |
publishDate | 2008-02-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-9984739315724dbe990f1f3744a12e1f2022-12-21T23:50:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m294m29410.1107/S1600536807067967Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) methanol solvateZhaowen YuLing ChangQingxia CuiWu ZhangIn the structure of the title complex, [Cu(C8H4O4)(C12H8N2)(H2O)]·CH4O, the CuII ion is pentacoordinated in a tetragonal–pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formylsalicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal plane, and a water O atom located at the apical site. The structure displays O—H...O hydrogen bonding.http://scripts.iucr.org/cgi-bin/paper?S1600536807067967 |
spellingShingle | Zhaowen Yu Ling Chang Qingxia Cui Wu Zhang Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) methanol solvate Acta Crystallographica Section E |
title | Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) methanol solvate |
title_full | Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) methanol solvate |
title_fullStr | Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) methanol solvate |
title_full_unstemmed | Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) methanol solvate |
title_short | Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) methanol solvate |
title_sort | aqua 3 formyl 2 oxidobenzoato 954 2o1 o2 1 10 phenanthroline 954 2n n 8242 copper ii methanol solvate |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536807067967 |
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