The Oxide Scales Formed on Different Co-Ni Based Superalloys During Isothermal Oxidation at 800 and 900°C

In this investigation, the formation of oxide scales on different Co-Ni based superalloys of γ–γ′ type was analyzed. Co-20Ni-7Al-7W (at. %) alloy as well as its W-free modifications based on Co-Ni-Al-Mo-Nb and Co-Ni-Al-Ta systems was analyzed under conditions of high temperature oxidation at 800 and...

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Main Authors: D. Migas, M. Kierat, G. Moskal
Format: Article
Language:English
Published: Polish Academy of Sciences 2020-12-01
Series:Archives of Metallurgy and Materials
Subjects:
Online Access:https://journals.pan.pl/Content/117781/PDF/AMM-2021-1-01-Migas.pdf
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author D. Migas
M. Kierat
G. Moskal
author_facet D. Migas
M. Kierat
G. Moskal
author_sort D. Migas
collection DOAJ
description In this investigation, the formation of oxide scales on different Co-Ni based superalloys of γ–γ′ type was analyzed. Co-20Ni-7Al-7W (at. %) alloy as well as its W-free modifications based on Co-Ni-Al-Mo-Nb and Co-Ni-Al-Ta systems was analyzed under conditions of high temperature oxidation at 800 and 900°C. Therefore, the alloys were isothermally oxidized at selected temperatures for 100 h in laboratory furnace. Afterwards, the oxidation products were evaluated by means of X-ray diffraction (XRD), optical microscopy (OM) and scanning electron microscopy (SEM). The performed tests showed that W-free alloys exhibit worse oxidation resistance compared to those of Co-Ni-Al-W alloys. After oxidation at 900°C, all alloys were prone of oxide spallation. The scales characterized by oxide peeling were mostly composed of complex Co-based oxides, including CoWO4, CoTa2O6, Co2Mo3O8, CoNb2O6.
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spelling doaj.art-99937f8093af4135a593f0dd883494a42022-12-22T01:40:08ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092020-12-01vol. 66No 1514https://doi.org/10.24425/amm.2021.134752The Oxide Scales Formed on Different Co-Ni Based Superalloys During Isothermal Oxidation at 800 and 900°CD. Migashttps://orcid.org/0000-0003-0328-964XM. Kierathttps://orcid.org/0000-0002-6288-197XG. Moskalhttps://orcid.org/0000-0001-7396-6568In this investigation, the formation of oxide scales on different Co-Ni based superalloys of γ–γ′ type was analyzed. Co-20Ni-7Al-7W (at. %) alloy as well as its W-free modifications based on Co-Ni-Al-Mo-Nb and Co-Ni-Al-Ta systems was analyzed under conditions of high temperature oxidation at 800 and 900°C. Therefore, the alloys were isothermally oxidized at selected temperatures for 100 h in laboratory furnace. Afterwards, the oxidation products were evaluated by means of X-ray diffraction (XRD), optical microscopy (OM) and scanning electron microscopy (SEM). The performed tests showed that W-free alloys exhibit worse oxidation resistance compared to those of Co-Ni-Al-W alloys. After oxidation at 900°C, all alloys were prone of oxide spallation. The scales characterized by oxide peeling were mostly composed of complex Co-based oxides, including CoWO4, CoTa2O6, Co2Mo3O8, CoNb2O6.https://journals.pan.pl/Content/117781/PDF/AMM-2021-1-01-Migas.pdfγ–γ′ cobalt-based superalloyshigh temperature oxidationco-ni superalloyw-free cobalt superalloys
spellingShingle D. Migas
M. Kierat
G. Moskal
The Oxide Scales Formed on Different Co-Ni Based Superalloys During Isothermal Oxidation at 800 and 900°C
Archives of Metallurgy and Materials
γ–γ′ cobalt-based superalloys
high temperature oxidation
co-ni superalloy
w-free cobalt superalloys
title The Oxide Scales Formed on Different Co-Ni Based Superalloys During Isothermal Oxidation at 800 and 900°C
title_full The Oxide Scales Formed on Different Co-Ni Based Superalloys During Isothermal Oxidation at 800 and 900°C
title_fullStr The Oxide Scales Formed on Different Co-Ni Based Superalloys During Isothermal Oxidation at 800 and 900°C
title_full_unstemmed The Oxide Scales Formed on Different Co-Ni Based Superalloys During Isothermal Oxidation at 800 and 900°C
title_short The Oxide Scales Formed on Different Co-Ni Based Superalloys During Isothermal Oxidation at 800 and 900°C
title_sort oxide scales formed on different co ni based superalloys during isothermal oxidation at 800 and 900°c
topic γ–γ′ cobalt-based superalloys
high temperature oxidation
co-ni superalloy
w-free cobalt superalloys
url https://journals.pan.pl/Content/117781/PDF/AMM-2021-1-01-Migas.pdf
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