HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials

Surface water contamination by synthetic dyes generates human and wildlife adverse health effects and causes photosynthesis decrease due to intense sun-light absorption of these pollutants. 50% of total discharged industrial effluents contain azo dyes. Congo Red is a benzidine based anionic azo dye...

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Main Authors: Alina Tatarus, Claudia Maria Simionescu, Roxana Elena Scutariu, Vasile Ion Iancu, Florinela Pirvu, Diana Puiu, Toma Galaon
Format: Article
Language:English
Published: Estfalia 2020-12-01
Series:Romanian Journal of Ecology & Environmental Chemistry
Subjects:
Online Access:http://www.rjeec.ro/Read/69?id=HPLC%20detection%20of%20synthetic%20dyes%20in%20residual%20waters%20from%20wastewater%20treatment%20using%20adsorption%20on%20magnetic%20materials
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author Alina Tatarus
Claudia Maria Simionescu
Roxana Elena Scutariu
Vasile Ion Iancu
Florinela Pirvu
Diana Puiu
Toma Galaon
author_facet Alina Tatarus
Claudia Maria Simionescu
Roxana Elena Scutariu
Vasile Ion Iancu
Florinela Pirvu
Diana Puiu
Toma Galaon
author_sort Alina Tatarus
collection DOAJ
description Surface water contamination by synthetic dyes generates human and wildlife adverse health effects and causes photosynthesis decrease due to intense sun-light absorption of these pollutants. 50% of total discharged industrial effluents contain azo dyes. Congo Red is a benzidine based anionic azo dye that is usually employed in rubber, paper and plastic industries. Congo Red can cause eye and skin irritation and is potentially carcinogenic in nature. This study explores the development of a new HPLC method to detect synthetic dyes in residual waters coming from wastewater treatment technologies based on magnetic material adsorption. Cobalt ferrite (CoFe2O4) and chitosan coated cobalt ferrite (CoFe2O4-Chit) prepared by a simple co-precipitation method were tested as adsorbents for Congo Red (CR). Effect of contact time, solution pH, and initial dye concentration were studied with respect to Congo Red adsorption efficiency. The adsorption experiments were performed at pH = 4.5 and 10.8. Highest value for the removal efficiency using magnetic material of cobalt ferrite coated with chitosan (CoFe2O4-Chit) was obtained at pH 10.8.
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spelling doaj.art-99995e632cc74f659079ab99a671e1eb2023-11-09T10:23:57ZengEstfaliaRomanian Journal of Ecology & Environmental Chemistry2668-54182668-85302020-12-01222229https://doi.org/10.21698/rjeec.2020.203HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materialsAlina Tatarus0Claudia Maria Simionescu1Roxana Elena Scutariu2https://orcid.org/0000-0001-7753-2206Vasile Ion Iancu3https://orcid.org/0000-0002-7980-0371Florinela Pirvu4https://orcid.org/0000-0002-8556-8943Diana Puiu5https://orcid.org/0000-0003-4510-747XToma Galaon6https://orcid.org/0000-0001-8621-922XNational Research and Development Institute for Industrial Ecology ECOINDUniversity Politehnica of BucharestNational Research and Development Institute for Industrial Ecology ECOINDNational Research and Development Institute for Industrial Ecology ECOINDNational Research and Development Institute for Industrial Ecology ECOINDNational Research and Development Institute for Industrial Ecology ECOINDNational Research and Development Institute for Industrial Ecology ECOINDSurface water contamination by synthetic dyes generates human and wildlife adverse health effects and causes photosynthesis decrease due to intense sun-light absorption of these pollutants. 50% of total discharged industrial effluents contain azo dyes. Congo Red is a benzidine based anionic azo dye that is usually employed in rubber, paper and plastic industries. Congo Red can cause eye and skin irritation and is potentially carcinogenic in nature. This study explores the development of a new HPLC method to detect synthetic dyes in residual waters coming from wastewater treatment technologies based on magnetic material adsorption. Cobalt ferrite (CoFe2O4) and chitosan coated cobalt ferrite (CoFe2O4-Chit) prepared by a simple co-precipitation method were tested as adsorbents for Congo Red (CR). Effect of contact time, solution pH, and initial dye concentration were studied with respect to Congo Red adsorption efficiency. The adsorption experiments were performed at pH = 4.5 and 10.8. Highest value for the removal efficiency using magnetic material of cobalt ferrite coated with chitosan (CoFe2O4-Chit) was obtained at pH 10.8.http://www.rjeec.ro/Read/69?id=HPLC%20detection%20of%20synthetic%20dyes%20in%20residual%20waters%20from%20wastewater%20treatment%20using%20adsorption%20on%20magnetic%20materialsadsorptionhplcmagnetic materialssynthetic dyeswastewater treatment
spellingShingle Alina Tatarus
Claudia Maria Simionescu
Roxana Elena Scutariu
Vasile Ion Iancu
Florinela Pirvu
Diana Puiu
Toma Galaon
HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials
Romanian Journal of Ecology & Environmental Chemistry
adsorption
hplc
magnetic materials
synthetic dyes
wastewater treatment
title HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials
title_full HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials
title_fullStr HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials
title_full_unstemmed HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials
title_short HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials
title_sort hplc detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials
topic adsorption
hplc
magnetic materials
synthetic dyes
wastewater treatment
url http://www.rjeec.ro/Read/69?id=HPLC%20detection%20of%20synthetic%20dyes%20in%20residual%20waters%20from%20wastewater%20treatment%20using%20adsorption%20on%20magnetic%20materials
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AT roxanaelenascutariu hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials
AT vasileioniancu hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials
AT florinelapirvu hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials
AT dianapuiu hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials
AT tomagalaon hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials