HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials
Surface water contamination by synthetic dyes generates human and wildlife adverse health effects and causes photosynthesis decrease due to intense sun-light absorption of these pollutants. 50% of total discharged industrial effluents contain azo dyes. Congo Red is a benzidine based anionic azo dye...
Main Authors: | , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Estfalia
2020-12-01
|
Series: | Romanian Journal of Ecology & Environmental Chemistry |
Subjects: | |
Online Access: | http://www.rjeec.ro/Read/69?id=HPLC%20detection%20of%20synthetic%20dyes%20in%20residual%20waters%20from%20wastewater%20treatment%20using%20adsorption%20on%20magnetic%20materials |
_version_ | 1797633149589520384 |
---|---|
author | Alina Tatarus Claudia Maria Simionescu Roxana Elena Scutariu Vasile Ion Iancu Florinela Pirvu Diana Puiu Toma Galaon |
author_facet | Alina Tatarus Claudia Maria Simionescu Roxana Elena Scutariu Vasile Ion Iancu Florinela Pirvu Diana Puiu Toma Galaon |
author_sort | Alina Tatarus |
collection | DOAJ |
description | Surface water contamination by synthetic dyes generates human and wildlife adverse health effects and causes photosynthesis decrease due to intense sun-light absorption of these pollutants. 50% of total discharged industrial effluents contain azo dyes. Congo Red is a benzidine based anionic azo dye that is usually employed in rubber, paper and plastic industries. Congo Red can cause eye and skin irritation and is potentially carcinogenic in nature. This study explores the development of a new HPLC method to detect synthetic dyes in residual waters coming from wastewater treatment technologies based on magnetic material adsorption. Cobalt ferrite (CoFe2O4) and chitosan coated cobalt ferrite (CoFe2O4-Chit) prepared by a simple co-precipitation method were tested as adsorbents for Congo Red (CR). Effect of contact time, solution pH, and initial dye concentration were studied with respect to Congo Red adsorption efficiency. The adsorption experiments were performed at pH = 4.5 and 10.8. Highest value for the removal efficiency using magnetic material of cobalt ferrite coated with chitosan (CoFe2O4-Chit) was obtained at pH 10.8. |
first_indexed | 2024-03-11T11:49:57Z |
format | Article |
id | doaj.art-99995e632cc74f659079ab99a671e1eb |
institution | Directory Open Access Journal |
issn | 2668-5418 2668-8530 |
language | English |
last_indexed | 2024-03-11T11:49:57Z |
publishDate | 2020-12-01 |
publisher | Estfalia |
record_format | Article |
series | Romanian Journal of Ecology & Environmental Chemistry |
spelling | doaj.art-99995e632cc74f659079ab99a671e1eb2023-11-09T10:23:57ZengEstfaliaRomanian Journal of Ecology & Environmental Chemistry2668-54182668-85302020-12-01222229https://doi.org/10.21698/rjeec.2020.203HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materialsAlina Tatarus0Claudia Maria Simionescu1Roxana Elena Scutariu2https://orcid.org/0000-0001-7753-2206Vasile Ion Iancu3https://orcid.org/0000-0002-7980-0371Florinela Pirvu4https://orcid.org/0000-0002-8556-8943Diana Puiu5https://orcid.org/0000-0003-4510-747XToma Galaon6https://orcid.org/0000-0001-8621-922XNational Research and Development Institute for Industrial Ecology ECOINDUniversity Politehnica of BucharestNational Research and Development Institute for Industrial Ecology ECOINDNational Research and Development Institute for Industrial Ecology ECOINDNational Research and Development Institute for Industrial Ecology ECOINDNational Research and Development Institute for Industrial Ecology ECOINDNational Research and Development Institute for Industrial Ecology ECOINDSurface water contamination by synthetic dyes generates human and wildlife adverse health effects and causes photosynthesis decrease due to intense sun-light absorption of these pollutants. 50% of total discharged industrial effluents contain azo dyes. Congo Red is a benzidine based anionic azo dye that is usually employed in rubber, paper and plastic industries. Congo Red can cause eye and skin irritation and is potentially carcinogenic in nature. This study explores the development of a new HPLC method to detect synthetic dyes in residual waters coming from wastewater treatment technologies based on magnetic material adsorption. Cobalt ferrite (CoFe2O4) and chitosan coated cobalt ferrite (CoFe2O4-Chit) prepared by a simple co-precipitation method were tested as adsorbents for Congo Red (CR). Effect of contact time, solution pH, and initial dye concentration were studied with respect to Congo Red adsorption efficiency. The adsorption experiments were performed at pH = 4.5 and 10.8. Highest value for the removal efficiency using magnetic material of cobalt ferrite coated with chitosan (CoFe2O4-Chit) was obtained at pH 10.8.http://www.rjeec.ro/Read/69?id=HPLC%20detection%20of%20synthetic%20dyes%20in%20residual%20waters%20from%20wastewater%20treatment%20using%20adsorption%20on%20magnetic%20materialsadsorptionhplcmagnetic materialssynthetic dyeswastewater treatment |
spellingShingle | Alina Tatarus Claudia Maria Simionescu Roxana Elena Scutariu Vasile Ion Iancu Florinela Pirvu Diana Puiu Toma Galaon HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials Romanian Journal of Ecology & Environmental Chemistry adsorption hplc magnetic materials synthetic dyes wastewater treatment |
title | HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials |
title_full | HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials |
title_fullStr | HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials |
title_full_unstemmed | HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials |
title_short | HPLC detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials |
title_sort | hplc detection of synthetic dyes in residual waters from wastewater treatment using adsorption on magnetic materials |
topic | adsorption hplc magnetic materials synthetic dyes wastewater treatment |
url | http://www.rjeec.ro/Read/69?id=HPLC%20detection%20of%20synthetic%20dyes%20in%20residual%20waters%20from%20wastewater%20treatment%20using%20adsorption%20on%20magnetic%20materials |
work_keys_str_mv | AT alinatatarus hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials AT claudiamariasimionescu hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials AT roxanaelenascutariu hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials AT vasileioniancu hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials AT florinelapirvu hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials AT dianapuiu hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials AT tomagalaon hplcdetectionofsyntheticdyesinresidualwatersfromwastewatertreatmentusingadsorptiononmagneticmaterials |