Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds
Several lower-rim perfluoroalkylated (fluorous) calix[4]arenes have been synthesized by O-alkylation of the parent calix[4]arene. The compounds are formed in the cone conformation. They are soluble in several fluorous solvents and show promise for use in sensing, selective extractions and other appl...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2008-10-01
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| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.4.36 |
| _version_ | 1818641709158891520 |
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| author | Maksim Osipov Qianli Chu Steven J. Geib Dennis P. Curran Stephen G. Weber |
| author_facet | Maksim Osipov Qianli Chu Steven J. Geib Dennis P. Curran Stephen G. Weber |
| author_sort | Maksim Osipov |
| collection | DOAJ |
| description | Several lower-rim perfluoroalkylated (fluorous) calix[4]arenes have been synthesized by O-alkylation of the parent calix[4]arene. The compounds are formed in the cone conformation. They are soluble in several fluorous solvents and show promise for use in sensing, selective extractions and other applications. |
| first_indexed | 2024-12-16T23:31:28Z |
| format | Article |
| id | doaj.art-999ab9bd930b4ef7bde332e03d2483e2 |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-16T23:31:28Z |
| publishDate | 2008-10-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-999ab9bd930b4ef7bde332e03d2483e22022-12-21T22:11:52ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972008-10-01413610.3762/bjoc.4.361860-5397-4-36Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffoldsMaksim Osipov0Qianli Chu1Steven J. Geib2Dennis P. Curran3Stephen G. Weber4Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, Fax: +1-412-624-9861; Tel: +1-412-624-8240Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, Fax: +1-412-624-9861; Tel: +1-412-624-8240Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, Fax: +1-412-624-9861; Tel: +1-412-624-8240Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, Fax: +1-412-624-9861; Tel: +1-412-624-8240Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, Fax: +1-412-624-9861; Tel: +1-412-624-8240Several lower-rim perfluoroalkylated (fluorous) calix[4]arenes have been synthesized by O-alkylation of the parent calix[4]arene. The compounds are formed in the cone conformation. They are soluble in several fluorous solvents and show promise for use in sensing, selective extractions and other applications.https://doi.org/10.3762/bjoc.4.36calixarenefluoroushydrofluoroethersorganofluorine(perfluoroalkyl)alkyl aryl ethers |
| spellingShingle | Maksim Osipov Qianli Chu Steven J. Geib Dennis P. Curran Stephen G. Weber Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds Beilstein Journal of Organic Chemistry calixarene fluorous hydrofluoroethers organofluorine (perfluoroalkyl)alkyl aryl ethers |
| title | Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds |
| title_full | Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds |
| title_fullStr | Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds |
| title_full_unstemmed | Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds |
| title_short | Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds |
| title_sort | synthesis of deep cavity fluorous calix 4 arenes as molecular recognition scaffolds |
| topic | calixarene fluorous hydrofluoroethers organofluorine (perfluoroalkyl)alkyl aryl ethers |
| url | https://doi.org/10.3762/bjoc.4.36 |
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