Micro-Structures Produced by Crystal Growth from Located Nuclei and Their Transfer Aiming at Functional Surfaces

Hydrothermal processes can produce regular micro-/nano-structures easily; but their placement or position is difficult to control, and the obtainable structures tend to be random. For controlling the crystal growth, two types of definite and regular structures were obtained. The first ones were ZnO...

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Main Authors: Nobuyuki Moronuki, Renato Serizawa
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Journal of Manufacturing and Materials Processing
Subjects:
Online Access:https://www.mdpi.com/2504-4494/4/4/105
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author Nobuyuki Moronuki
Renato Serizawa
author_facet Nobuyuki Moronuki
Renato Serizawa
author_sort Nobuyuki Moronuki
collection DOAJ
description Hydrothermal processes can produce regular micro-/nano-structures easily; but their placement or position is difficult to control, and the obtainable structures tend to be random. For controlling the crystal growth, two types of definite and regular structures were obtained. The first ones were ZnO urchin-like structures synthesized from located ZnO particles as the nuclei. These structures were found to work as gas sensors utilizing a wide surface area. The second one was a vertically aligned TiO<sub>2</sub> nanorod array synthesized on a fluorine-doped tin oxide substrate that has a similar lattice constant to rutile TiO<sub>2</sub>. Super-hydrophobicity after ultraviolet irradiation was then examined. Finally, the synthesized TiO<sub>2</sub> array was peeled off and transferred onto a resin sheet. We determined that the substrate could be subjected to repeated hydrothermal synthesis, thereby demonstrating the reusability of the substrate. These results demonstrate the applicability of these processes for industrial applications.
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spelling doaj.art-999e2b799df3497492009a0fd3674bc92023-11-20T20:02:10ZengMDPI AGJournal of Manufacturing and Materials Processing2504-44942020-11-014410510.3390/jmmp4040105Micro-Structures Produced by Crystal Growth from Located Nuclei and Their Transfer Aiming at Functional SurfacesNobuyuki Moronuki0Renato Serizawa1Faculty of Systems Design, Tokyo Metropolitan University, Tokyo 191-0065, JapanGraduate School of Systems Design, Tokyo Metropolitan University, Tokyo 191-0065, JapanHydrothermal processes can produce regular micro-/nano-structures easily; but their placement or position is difficult to control, and the obtainable structures tend to be random. For controlling the crystal growth, two types of definite and regular structures were obtained. The first ones were ZnO urchin-like structures synthesized from located ZnO particles as the nuclei. These structures were found to work as gas sensors utilizing a wide surface area. The second one was a vertically aligned TiO<sub>2</sub> nanorod array synthesized on a fluorine-doped tin oxide substrate that has a similar lattice constant to rutile TiO<sub>2</sub>. Super-hydrophobicity after ultraviolet irradiation was then examined. Finally, the synthesized TiO<sub>2</sub> array was peeled off and transferred onto a resin sheet. We determined that the substrate could be subjected to repeated hydrothermal synthesis, thereby demonstrating the reusability of the substrate. These results demonstrate the applicability of these processes for industrial applications.https://www.mdpi.com/2504-4494/4/4/105self-organizing processmicrostructureself-assemblycrystal growthnuclei
spellingShingle Nobuyuki Moronuki
Renato Serizawa
Micro-Structures Produced by Crystal Growth from Located Nuclei and Their Transfer Aiming at Functional Surfaces
Journal of Manufacturing and Materials Processing
self-organizing process
microstructure
self-assembly
crystal growth
nuclei
title Micro-Structures Produced by Crystal Growth from Located Nuclei and Their Transfer Aiming at Functional Surfaces
title_full Micro-Structures Produced by Crystal Growth from Located Nuclei and Their Transfer Aiming at Functional Surfaces
title_fullStr Micro-Structures Produced by Crystal Growth from Located Nuclei and Their Transfer Aiming at Functional Surfaces
title_full_unstemmed Micro-Structures Produced by Crystal Growth from Located Nuclei and Their Transfer Aiming at Functional Surfaces
title_short Micro-Structures Produced by Crystal Growth from Located Nuclei and Their Transfer Aiming at Functional Surfaces
title_sort micro structures produced by crystal growth from located nuclei and their transfer aiming at functional surfaces
topic self-organizing process
microstructure
self-assembly
crystal growth
nuclei
url https://www.mdpi.com/2504-4494/4/4/105
work_keys_str_mv AT nobuyukimoronuki microstructuresproducedbycrystalgrowthfromlocatednucleiandtheirtransferaimingatfunctionalsurfaces
AT renatoserizawa microstructuresproducedbycrystalgrowthfromlocatednucleiandtheirtransferaimingatfunctionalsurfaces