Anthraquinone derivative as high-performance anode material for sodium-ion batteries using ether-based electrolytes
Organic materials, especially the carbonyl compounds, are promising anode materials for room temperature sodium-ion batteries owing to their high reversible capacity, structural diversity as well as eco-friendly synthesis from bio-mass. Herein, we report a novel anthraquinone derivative, C14H6O4Na2...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
KeAi Communications Co., Ltd.
2018-01-01
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| Series: | Green Energy & Environment |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2468025717301206 |
| _version_ | 1818731987886669824 |
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| author | Linqin Mu Yaxiang Lu Xiaoyan Wu Yuejun Ding Yong-Sheng Hu Hong Li Liquan Chen Xuejie Huang |
| author_facet | Linqin Mu Yaxiang Lu Xiaoyan Wu Yuejun Ding Yong-Sheng Hu Hong Li Liquan Chen Xuejie Huang |
| author_sort | Linqin Mu |
| collection | DOAJ |
| description | Organic materials, especially the carbonyl compounds, are promising anode materials for room temperature sodium-ion batteries owing to their high reversible capacity, structural diversity as well as eco-friendly synthesis from bio-mass. Herein, we report a novel anthraquinone derivative, C14H6O4Na2 composited with carbon nanotube (C14H6O4Na2-CNT), used as an anode material for sodium-ion batteries in ether-based electrolyte. The C14H6O4Na2-CNT electrode delivers a reversible capacity of 173 mAh g−1 and an ultra-high initial Coulombic efficiency of 98% at the rate of 0.1 C. The capacity retention is 82% after 50 cycles at 0.2 C and a good rate capability is displayed at 2 C. Furthermore, the average Na insertion voltage of 1.27 V vs. Na+/Na makes it a unique and safety battery material, which would avoid Na plating and formation of solid electrolyte interface. Our contribution provides new insights for designing developed organic anode materials with high initial Coulombic efficiency and improved safety capability for sodium-ion batteries. |
| first_indexed | 2024-12-17T23:26:25Z |
| format | Article |
| id | doaj.art-99af8b4828e04eaa9282ee77d69493c6 |
| institution | Directory Open Access Journal |
| issn | 2468-0257 |
| language | English |
| last_indexed | 2024-12-17T23:26:25Z |
| publishDate | 2018-01-01 |
| publisher | KeAi Communications Co., Ltd. |
| record_format | Article |
| series | Green Energy & Environment |
| spelling | doaj.art-99af8b4828e04eaa9282ee77d69493c62022-12-21T21:28:46ZengKeAi Communications Co., Ltd.Green Energy & Environment2468-02572018-01-0131637010.1016/j.gee.2017.09.002Anthraquinone derivative as high-performance anode material for sodium-ion batteries using ether-based electrolytesLinqin MuYaxiang LuXiaoyan WuYuejun DingYong-Sheng HuHong LiLiquan ChenXuejie HuangOrganic materials, especially the carbonyl compounds, are promising anode materials for room temperature sodium-ion batteries owing to their high reversible capacity, structural diversity as well as eco-friendly synthesis from bio-mass. Herein, we report a novel anthraquinone derivative, C14H6O4Na2 composited with carbon nanotube (C14H6O4Na2-CNT), used as an anode material for sodium-ion batteries in ether-based electrolyte. The C14H6O4Na2-CNT electrode delivers a reversible capacity of 173 mAh g−1 and an ultra-high initial Coulombic efficiency of 98% at the rate of 0.1 C. The capacity retention is 82% after 50 cycles at 0.2 C and a good rate capability is displayed at 2 C. Furthermore, the average Na insertion voltage of 1.27 V vs. Na+/Na makes it a unique and safety battery material, which would avoid Na plating and formation of solid electrolyte interface. Our contribution provides new insights for designing developed organic anode materials with high initial Coulombic efficiency and improved safety capability for sodium-ion batteries.http://www.sciencedirect.com/science/article/pii/S2468025717301206AnthraquinoneC14H6O4Na2-CNTAnode materialEther-based electrolyteSodium-ion batteries |
| spellingShingle | Linqin Mu Yaxiang Lu Xiaoyan Wu Yuejun Ding Yong-Sheng Hu Hong Li Liquan Chen Xuejie Huang Anthraquinone derivative as high-performance anode material for sodium-ion batteries using ether-based electrolytes Green Energy & Environment Anthraquinone C14H6O4Na2-CNT Anode material Ether-based electrolyte Sodium-ion batteries |
| title | Anthraquinone derivative as high-performance anode material for sodium-ion batteries using ether-based electrolytes |
| title_full | Anthraquinone derivative as high-performance anode material for sodium-ion batteries using ether-based electrolytes |
| title_fullStr | Anthraquinone derivative as high-performance anode material for sodium-ion batteries using ether-based electrolytes |
| title_full_unstemmed | Anthraquinone derivative as high-performance anode material for sodium-ion batteries using ether-based electrolytes |
| title_short | Anthraquinone derivative as high-performance anode material for sodium-ion batteries using ether-based electrolytes |
| title_sort | anthraquinone derivative as high performance anode material for sodium ion batteries using ether based electrolytes |
| topic | Anthraquinone C14H6O4Na2-CNT Anode material Ether-based electrolyte Sodium-ion batteries |
| url | http://www.sciencedirect.com/science/article/pii/S2468025717301206 |
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