Mineralogy and geochemical characterization of geophagic clays consumed in parts of southern Nigeria

This study seeks to determine health risk associated with consumption of clay in different areas in southern Nigeria. Different clay samples sold for consumption were purchased from Mowe, Ikorodu and Onitsha Markets in southern Nigeria. The clays were subjected to mineralogical and geochemical chara...

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Main Authors: Olusegun Gbenga Olisa, Jerry Olugbenga Olajide-Kayode, Blessing Oluwaseunfunmi Adebayo, Oluwapamilerin Atinuke Ajayi, Kingsley Odukoya, Anuoluwa Ayoyimika Olalemi, Tamara Doubra-Mary Uyakunmor
Format: Article
Language:English
Published: Elsevier 2023-06-01
Series:Journal of Trace Elements and Minerals
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2773050623000174
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author Olusegun Gbenga Olisa
Jerry Olugbenga Olajide-Kayode
Blessing Oluwaseunfunmi Adebayo
Oluwapamilerin Atinuke Ajayi
Kingsley Odukoya
Anuoluwa Ayoyimika Olalemi
Tamara Doubra-Mary Uyakunmor
author_facet Olusegun Gbenga Olisa
Jerry Olugbenga Olajide-Kayode
Blessing Oluwaseunfunmi Adebayo
Oluwapamilerin Atinuke Ajayi
Kingsley Odukoya
Anuoluwa Ayoyimika Olalemi
Tamara Doubra-Mary Uyakunmor
author_sort Olusegun Gbenga Olisa
collection DOAJ
description This study seeks to determine health risk associated with consumption of clay in different areas in southern Nigeria. Different clay samples sold for consumption were purchased from Mowe, Ikorodu and Onitsha Markets in southern Nigeria. The clays were subjected to mineralogical and geochemical characterization using X-Ray Diffractometry (XRD), Fourier Transform Infrared (FTIR) and Inductively Coupled Plasma-Atomic EmissionSpectrometry. Potential health risk assessment was calculated using a standardized Hazard Quotient (HQ) and Total Hazard Index (THI). XRD and FTIR results revealed the clay contains varying percentage of quartz, kaolinite, anatase, halite, pyrite, goethite, smectite and palygorskite while geochemical analysis result revealed wide range of elemental concentration (ppm). Mean concentration (ppm) of Cu, Pb, Zn, Cr, Ni and Co from the markets are 5.8 – 8; 17.4 – 29.6; 32.4 – 95.8;111.6 – 103.4; 18.6 – 39.4 and 4 – 16.6 respectively while As was below detection limit in most of the samples. HQ values were used to calculate the THI. THI values for children and adults for Mowe market samples range from 0.9 to 2.1 and 0.5–1.1 respectively, for Ikorodu market samples, THI for children and adult ranges from 1.0- 1.8 and 0.6–1.0 respectively, while THI for children and adults for Onitsha market samples ranges from 1.5 to 2.6 and 0.8–1.84 respectively. In conclusion, children that consume clay from the markets are more exposed to non-carcinogenic risks than adults. It is therefore advisable that the clays should not be consumed for a long period of time to avoid health problems.
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spelling doaj.art-99bec0b7f2b24aacb30b60d7aacbbd512023-06-19T04:30:45ZengElsevierJournal of Trace Elements and Minerals2773-05062023-06-014100063Mineralogy and geochemical characterization of geophagic clays consumed in parts of southern NigeriaOlusegun Gbenga Olisa0Jerry Olugbenga Olajide-Kayode1Blessing Oluwaseunfunmi Adebayo2Oluwapamilerin Atinuke Ajayi3Kingsley Odukoya4Anuoluwa Ayoyimika Olalemi5Tamara Doubra-Mary Uyakunmor6Department of Earth Sciences, Olabisi Onabanjo University, Ago-Iwoye, Nigeria; Corresponding author.Department of Geological Sciences, Osun State University, Ago-Iwoye, NigeriaDepartment of Earth Sciences, Olabisi Onabanjo University, Ago-Iwoye, NigeriaDepartment of Earth Sciences, Olabisi Onabanjo University, Ago-Iwoye, NigeriaDepartment of Earth Sciences, Olabisi Onabanjo University, Ago-Iwoye, NigeriaDepartment of Earth Sciences, Olabisi Onabanjo University, Ago-Iwoye, NigeriaDepartment of Earth Sciences, Olabisi Onabanjo University, Ago-Iwoye, NigeriaThis study seeks to determine health risk associated with consumption of clay in different areas in southern Nigeria. Different clay samples sold for consumption were purchased from Mowe, Ikorodu and Onitsha Markets in southern Nigeria. The clays were subjected to mineralogical and geochemical characterization using X-Ray Diffractometry (XRD), Fourier Transform Infrared (FTIR) and Inductively Coupled Plasma-Atomic EmissionSpectrometry. Potential health risk assessment was calculated using a standardized Hazard Quotient (HQ) and Total Hazard Index (THI). XRD and FTIR results revealed the clay contains varying percentage of quartz, kaolinite, anatase, halite, pyrite, goethite, smectite and palygorskite while geochemical analysis result revealed wide range of elemental concentration (ppm). Mean concentration (ppm) of Cu, Pb, Zn, Cr, Ni and Co from the markets are 5.8 – 8; 17.4 – 29.6; 32.4 – 95.8;111.6 – 103.4; 18.6 – 39.4 and 4 – 16.6 respectively while As was below detection limit in most of the samples. HQ values were used to calculate the THI. THI values for children and adults for Mowe market samples range from 0.9 to 2.1 and 0.5–1.1 respectively, for Ikorodu market samples, THI for children and adult ranges from 1.0- 1.8 and 0.6–1.0 respectively, while THI for children and adults for Onitsha market samples ranges from 1.5 to 2.6 and 0.8–1.84 respectively. In conclusion, children that consume clay from the markets are more exposed to non-carcinogenic risks than adults. It is therefore advisable that the clays should not be consumed for a long period of time to avoid health problems.http://www.sciencedirect.com/science/article/pii/S2773050623000174ClayHealth risk assessmentKaolinSmectite
spellingShingle Olusegun Gbenga Olisa
Jerry Olugbenga Olajide-Kayode
Blessing Oluwaseunfunmi Adebayo
Oluwapamilerin Atinuke Ajayi
Kingsley Odukoya
Anuoluwa Ayoyimika Olalemi
Tamara Doubra-Mary Uyakunmor
Mineralogy and geochemical characterization of geophagic clays consumed in parts of southern Nigeria
Journal of Trace Elements and Minerals
Clay
Health risk assessment
Kaolin
Smectite
title Mineralogy and geochemical characterization of geophagic clays consumed in parts of southern Nigeria
title_full Mineralogy and geochemical characterization of geophagic clays consumed in parts of southern Nigeria
title_fullStr Mineralogy and geochemical characterization of geophagic clays consumed in parts of southern Nigeria
title_full_unstemmed Mineralogy and geochemical characterization of geophagic clays consumed in parts of southern Nigeria
title_short Mineralogy and geochemical characterization of geophagic clays consumed in parts of southern Nigeria
title_sort mineralogy and geochemical characterization of geophagic clays consumed in parts of southern nigeria
topic Clay
Health risk assessment
Kaolin
Smectite
url http://www.sciencedirect.com/science/article/pii/S2773050623000174
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