Isotope Mass Spectrometry as a Tool for Identifying Organic Tomatoes (Solanum lycopersicum L.)

Tomatoes (Solanum lycopersicum L.) are one of the most popular vegetables in the world. These days, Russian consumers prefer tomatoes labeled as organic. However, the agricultural industry often lacks instrumental methods to confirm the organic status of tomatoes. Isotope mass spectrometry is a prom...

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Main Authors: Lev A. Oganesyants, Alexander L. Panasyuk, Elena I. Kuzmina, Dmitry A. Sviridov, Mikhail Yu. Ganin, Alexei A. Sсhilkin
Format: Article
Language:Russian
Published: Kemerovo State University 2023-09-01
Series:Техника и технология пищевых производств
Subjects:
Online Access:https://fptt.ru/en/issues/22025/22018/
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author Lev A. Oganesyants
Alexander L. Panasyuk
Elena I. Kuzmina
Dmitry A. Sviridov
Mikhail Yu. Ganin
Alexei A. Sсhilkin
author_facet Lev A. Oganesyants
Alexander L. Panasyuk
Elena I. Kuzmina
Dmitry A. Sviridov
Mikhail Yu. Ganin
Alexei A. Sсhilkin
author_sort Lev A. Oganesyants
collection DOAJ
description Tomatoes (Solanum lycopersicum L.) are one of the most popular vegetables in the world. These days, Russian consumers prefer tomatoes labeled as organic. However, the agricultural industry often lacks instrumental methods to confirm the organic status of tomatoes. Isotope mass spectrometry is a promising method that can detect tomatoes that fail to meet organic standards. Isotopic values of total nitrogen and total carbon can be used to identify tomatoes as those grown on the field or as those cultivated in greenhouses enriched with carbon dioxide. The research featured 16 samples of tomatoes, 14 of which were purchased in Russian retail chains. Two samples were grown on the field without chemical fertilizers. The composition of stable carbon and nitrogen isotopes in the samples was determined using an IRMS Delta V Advantage isotope mass spectrometer with additional auxiliary modules. In the greenhouse tomatoes, δ13C values ranged from –44 to –32‰. In the samples obtained from a conventional greenhouse, δ13C values ranged from –30 to –24‰. Six samples proved to have been grown in artificial carbon dioxide atmosphere. Three samples demonstrated borderline values of δ13C and δ15N; they were impossible to identify as organic or conventional, both in terms of artificial carbon dioxide and fertilizers. Isotope mass spectrometry proved to be efficient in detecting falsified organic products. Tomatoes grown with carbon dioxide enrichment had lower isotope values of total carbon than organic tomatoes. The obtained values also made it possible to tell between organic and chemical fertilizers.
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spelling doaj.art-99d17664feac47b8b1b2820fefb2ea112023-12-20T06:18:21ZrusKemerovo State UniversityТехника и технология пищевых производств2074-94142313-17482023-09-0153361262010.21603/2074-9414-2023-3-2461Isotope Mass Spectrometry as a Tool for Identifying Organic Tomatoes (Solanum lycopersicum L.)Lev A. Oganesyants0https://orcid.org/0000-0001-8195-4292Alexander L. Panasyuk1https://orcid.org/0000-0002-5502-7951Elena I. Kuzmina2https://orcid.org/0000-0001-7623-440XDmitry A. Sviridov3https://orcid.org/0000-0002-5595-0455Mikhail Yu. Ganin4https://orcid.org/0000-0003-0518-1181Alexei A. Sсhilkin5https://orcid.org/0000-0003-1223-0703All-Russian Research Institute of Brewing, Non-Alcoholic and Wine Industry, Moscow, RussiaAll-Russian Research Institute of Brewing, Non-Alcoholic and Wine Industry, Moscow, RussiaAll-Russian Research Institute of Brewing, Non-Alcoholic and Wine Industry, Moscow, RussiaAll-Russian Research Institute of Brewing, Non-Alcoholic and Wine Industry, Moscow, RussiaAll-Russian Research Institute of Brewing, Non-Alcoholic and Wine Industry, Moscow, RussiaAll-Russian Research Institute of Brewing, Non-Alcoholic and Wine Industry, Moscow, RussiaTomatoes (Solanum lycopersicum L.) are one of the most popular vegetables in the world. These days, Russian consumers prefer tomatoes labeled as organic. However, the agricultural industry often lacks instrumental methods to confirm the organic status of tomatoes. Isotope mass spectrometry is a promising method that can detect tomatoes that fail to meet organic standards. Isotopic values of total nitrogen and total carbon can be used to identify tomatoes as those grown on the field or as those cultivated in greenhouses enriched with carbon dioxide. The research featured 16 samples of tomatoes, 14 of which were purchased in Russian retail chains. Two samples were grown on the field without chemical fertilizers. The composition of stable carbon and nitrogen isotopes in the samples was determined using an IRMS Delta V Advantage isotope mass spectrometer with additional auxiliary modules. In the greenhouse tomatoes, δ13C values ranged from –44 to –32‰. In the samples obtained from a conventional greenhouse, δ13C values ranged from –30 to –24‰. Six samples proved to have been grown in artificial carbon dioxide atmosphere. Three samples demonstrated borderline values of δ13C and δ15N; they were impossible to identify as organic or conventional, both in terms of artificial carbon dioxide and fertilizers. Isotope mass spectrometry proved to be efficient in detecting falsified organic products. Tomatoes grown with carbon dioxide enrichment had lower isotope values of total carbon than organic tomatoes. The obtained values also made it possible to tell between organic and chemical fertilizers.https://fptt.ru/en/issues/22025/22018/tomatoesisotope mass spectrometryisotopes of carbonoxygenhydrogenidentificationplace of originfalsificationplant cultivation
spellingShingle Lev A. Oganesyants
Alexander L. Panasyuk
Elena I. Kuzmina
Dmitry A. Sviridov
Mikhail Yu. Ganin
Alexei A. Sсhilkin
Isotope Mass Spectrometry as a Tool for Identifying Organic Tomatoes (Solanum lycopersicum L.)
Техника и технология пищевых производств
tomatoes
isotope mass spectrometry
isotopes of carbon
oxygen
hydrogen
identification
place of origin
falsification
plant cultivation
title Isotope Mass Spectrometry as a Tool for Identifying Organic Tomatoes (Solanum lycopersicum L.)
title_full Isotope Mass Spectrometry as a Tool for Identifying Organic Tomatoes (Solanum lycopersicum L.)
title_fullStr Isotope Mass Spectrometry as a Tool for Identifying Organic Tomatoes (Solanum lycopersicum L.)
title_full_unstemmed Isotope Mass Spectrometry as a Tool for Identifying Organic Tomatoes (Solanum lycopersicum L.)
title_short Isotope Mass Spectrometry as a Tool for Identifying Organic Tomatoes (Solanum lycopersicum L.)
title_sort isotope mass spectrometry as a tool for identifying organic tomatoes solanum lycopersicum l
topic tomatoes
isotope mass spectrometry
isotopes of carbon
oxygen
hydrogen
identification
place of origin
falsification
plant cultivation
url https://fptt.ru/en/issues/22025/22018/
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