Estimation of structural and mechanical properties of Cadmium Sulfide/PVA nanocomposite films
Cadmium Sulfide (CdS) nanoparticles have been synthesized by hydrothermal method, and dispersed in varying amounts by weight, in Poly Vinyl Alcohol (PVA) matrix. Subsequently, PVA/CdS nanocomposite films have been characterized and analyzed to estimate CdS nanoparticles effect on the properties of P...
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| Format: | Article |
| Language: | English |
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Elsevier
2019-06-01
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| Series: | Heliyon |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844019308266 |
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| author | Jammula Koteswararao Suggala Venkata Satyanarayana Gattumane Motappa Madhu Vuppala Venkatesham |
| author_facet | Jammula Koteswararao Suggala Venkata Satyanarayana Gattumane Motappa Madhu Vuppala Venkatesham |
| author_sort | Jammula Koteswararao |
| collection | DOAJ |
| description | Cadmium Sulfide (CdS) nanoparticles have been synthesized by hydrothermal method, and dispersed in varying amounts by weight, in Poly Vinyl Alcohol (PVA) matrix. Subsequently, PVA/CdS nanocomposite films have been characterized and analyzed to estimate CdS nanoparticles effect on the properties of PVA films. Both mechanical and structural properties have been considered for the analysis. From the FTIR (Fourier Transform Infrared Spectroscopy) analysis it's found that stretching of C-H, CO, COC and COS were observed at different peaks that may be due to different functional groups. X-ray diffraction (XRD) results showed that the matrix contain pure nano CdS particles. The images obtained by Scanning Electron Microscopy (SEM) showed the presence of varying degree of agglomerated CdS nanoparticles distributed homogeneously in the PVA/CdS nanocomposite. Thermal properties are found using DSC (Differential Scanning Calorimetry) was used to investigate. PVA/CdS samples were tested by Universal Testing Machine (UTM) and the results indicated improvement in mechanical properties when compared with neat PVA film, viz. Young's modulus (from 33.20 to 94.30 MPa), ultimate tensile stress (from 17.03 to 27.60 MPa), toughness (from 2.18 to 17.62 MPa) and flexural strength (from 4.43 to 7.66 Mpa) with increase in the CdS content in the nanocomposite film. |
| first_indexed | 2024-12-11T15:57:38Z |
| format | Article |
| id | doaj.art-99f8bd8a46a14c91be40bc9680514864 |
| institution | Directory Open Access Journal |
| issn | 2405-8440 |
| language | English |
| last_indexed | 2024-12-11T15:57:38Z |
| publishDate | 2019-06-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Heliyon |
| spelling | doaj.art-99f8bd8a46a14c91be40bc96805148642022-12-22T00:59:22ZengElsevierHeliyon2405-84402019-06-0156e01851Estimation of structural and mechanical properties of Cadmium Sulfide/PVA nanocomposite filmsJammula Koteswararao0Suggala Venkata Satyanarayana1Gattumane Motappa Madhu2Vuppala Venkatesham3Department of Chemical Engineering, M S Ramaiah Institute of Technology, Bangalore, 560 054, Karnataka, IndiaDepartment of Chemical Engineering, Jawaharlal Nehru Technological University Anantapur, Anantapuramu, 515 002, Andhra Pradesh, IndiaDepartment of Chemical Engineering, M S Ramaiah Institute of Technology, Bangalore, 560 054, Karnataka, India; Corresponding author.Department of Chemical Engineering, M S Ramaiah Institute of Technology, Bangalore, 560 054, Karnataka, IndiaCadmium Sulfide (CdS) nanoparticles have been synthesized by hydrothermal method, and dispersed in varying amounts by weight, in Poly Vinyl Alcohol (PVA) matrix. Subsequently, PVA/CdS nanocomposite films have been characterized and analyzed to estimate CdS nanoparticles effect on the properties of PVA films. Both mechanical and structural properties have been considered for the analysis. From the FTIR (Fourier Transform Infrared Spectroscopy) analysis it's found that stretching of C-H, CO, COC and COS were observed at different peaks that may be due to different functional groups. X-ray diffraction (XRD) results showed that the matrix contain pure nano CdS particles. The images obtained by Scanning Electron Microscopy (SEM) showed the presence of varying degree of agglomerated CdS nanoparticles distributed homogeneously in the PVA/CdS nanocomposite. Thermal properties are found using DSC (Differential Scanning Calorimetry) was used to investigate. PVA/CdS samples were tested by Universal Testing Machine (UTM) and the results indicated improvement in mechanical properties when compared with neat PVA film, viz. Young's modulus (from 33.20 to 94.30 MPa), ultimate tensile stress (from 17.03 to 27.60 MPa), toughness (from 2.18 to 17.62 MPa) and flexural strength (from 4.43 to 7.66 Mpa) with increase in the CdS content in the nanocomposite film.http://www.sciencedirect.com/science/article/pii/S2405844019308266Mechanical engineeringNanotechnologyMaterials scienceMechanical propertiesNanocompositesStress |
| spellingShingle | Jammula Koteswararao Suggala Venkata Satyanarayana Gattumane Motappa Madhu Vuppala Venkatesham Estimation of structural and mechanical properties of Cadmium Sulfide/PVA nanocomposite films Heliyon Mechanical engineering Nanotechnology Materials science Mechanical properties Nanocomposites Stress |
| title | Estimation of structural and mechanical properties of Cadmium Sulfide/PVA nanocomposite films |
| title_full | Estimation of structural and mechanical properties of Cadmium Sulfide/PVA nanocomposite films |
| title_fullStr | Estimation of structural and mechanical properties of Cadmium Sulfide/PVA nanocomposite films |
| title_full_unstemmed | Estimation of structural and mechanical properties of Cadmium Sulfide/PVA nanocomposite films |
| title_short | Estimation of structural and mechanical properties of Cadmium Sulfide/PVA nanocomposite films |
| title_sort | estimation of structural and mechanical properties of cadmium sulfide pva nanocomposite films |
| topic | Mechanical engineering Nanotechnology Materials science Mechanical properties Nanocomposites Stress |
| url | http://www.sciencedirect.com/science/article/pii/S2405844019308266 |
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