A reação de metátese de olefinas: reorganização e ciclização de compostos orgânicos The olefin metathesis reaction: reorganization and ciclization of organic compounds
<abstract language="eng">The olefin metathesis reaction allows the exchange of complex alkyl units between two olefins, with the formation of a new olefinic link and a sub-product olefin usually ethylene. This reaction has found extensive application in the last ten years with the de...
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| Format: | Article |
| Language: | English |
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Sociedade Brasileira de Química
2005-08-01
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| Series: | Química Nova |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422005000400024 |
| _version_ | 1818188735101009920 |
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| author | Daniel Frederico Ursula Brocksom Timothy John Brocksom |
| author_facet | Daniel Frederico Ursula Brocksom Timothy John Brocksom |
| author_sort | Daniel Frederico |
| collection | DOAJ |
| description | <abstract language="eng">The olefin metathesis reaction allows the exchange of complex alkyl units between two olefins, with the formation of a new olefinic link and a sub-product olefin usually ethylene. This reaction has found extensive application in the last ten years with the development of the Grubbs and Schrock catalysts, in total synthesis of complex organic molecules, as opposed to the very important use in the petrochemical industry with relatively simple molecules. This review intends to trace a historical and mechanistic pathway from industry to academy, before illustrating the more recent advances. |
| first_indexed | 2024-12-11T23:31:39Z |
| format | Article |
| id | doaj.art-9a0bd04c2bfd4d0faa078cb33c4efca1 |
| institution | Directory Open Access Journal |
| issn | 0100-4042 1678-7064 |
| language | English |
| last_indexed | 2024-12-11T23:31:39Z |
| publishDate | 2005-08-01 |
| publisher | Sociedade Brasileira de Química |
| record_format | Article |
| series | Química Nova |
| spelling | doaj.art-9a0bd04c2bfd4d0faa078cb33c4efca12022-12-22T00:46:01ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642005-08-0128469270210.1590/S0100-40422005000400024A reação de metátese de olefinas: reorganização e ciclização de compostos orgânicos The olefin metathesis reaction: reorganization and ciclization of organic compoundsDaniel FredericoUrsula BrocksomTimothy John Brocksom<abstract language="eng">The olefin metathesis reaction allows the exchange of complex alkyl units between two olefins, with the formation of a new olefinic link and a sub-product olefin usually ethylene. This reaction has found extensive application in the last ten years with the development of the Grubbs and Schrock catalysts, in total synthesis of complex organic molecules, as opposed to the very important use in the petrochemical industry with relatively simple molecules. This review intends to trace a historical and mechanistic pathway from industry to academy, before illustrating the more recent advances.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422005000400024olefin metathesisring-closing metathesiscross metathesis |
| spellingShingle | Daniel Frederico Ursula Brocksom Timothy John Brocksom A reação de metátese de olefinas: reorganização e ciclização de compostos orgânicos The olefin metathesis reaction: reorganization and ciclization of organic compounds Química Nova olefin metathesis ring-closing metathesis cross metathesis |
| title | A reação de metátese de olefinas: reorganização e ciclização de compostos orgânicos The olefin metathesis reaction: reorganization and ciclization of organic compounds |
| title_full | A reação de metátese de olefinas: reorganização e ciclização de compostos orgânicos The olefin metathesis reaction: reorganization and ciclization of organic compounds |
| title_fullStr | A reação de metátese de olefinas: reorganização e ciclização de compostos orgânicos The olefin metathesis reaction: reorganization and ciclization of organic compounds |
| title_full_unstemmed | A reação de metátese de olefinas: reorganização e ciclização de compostos orgânicos The olefin metathesis reaction: reorganization and ciclization of organic compounds |
| title_short | A reação de metátese de olefinas: reorganização e ciclização de compostos orgânicos The olefin metathesis reaction: reorganization and ciclization of organic compounds |
| title_sort | reacao de metatese de olefinas reorganizacao e ciclizacao de compostos organicos the olefin metathesis reaction reorganization and ciclization of organic compounds |
| topic | olefin metathesis ring-closing metathesis cross metathesis |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422005000400024 |
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