Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO Nanocomposites-Decorated CsPbI<sub>3</sub> Perovskite Active Materials under UV-Light Irradiation for the Enhancement of Crystal-Violet Dye Photodegradation
Ti<sub>3</sub>C<sub>2</sub>-MXene material, known for its strong electronic conductivity and optical properties, has emerged as a promising alternative to noble metals as a cocatalyst for the development of efficient photocatalysts used in environmental cleanup. In this study...
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MDPI AG
2023-11-01
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| Series: | Nanomaterials |
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| Online Access: | https://www.mdpi.com/2079-4991/13/23/3026 |
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| author | Asma A. Alothman Mohammad Rizwan Khan Munirah D. Albaqami Sonaimuthu Mohandoss Zeid A. Alothman Naushad Ahmad Khadraa N. Alqahtani |
| author_facet | Asma A. Alothman Mohammad Rizwan Khan Munirah D. Albaqami Sonaimuthu Mohandoss Zeid A. Alothman Naushad Ahmad Khadraa N. Alqahtani |
| author_sort | Asma A. Alothman |
| collection | DOAJ |
| description | Ti<sub>3</sub>C<sub>2</sub>-MXene material, known for its strong electronic conductivity and optical properties, has emerged as a promising alternative to noble metals as a cocatalyst for the development of efficient photocatalysts used in environmental cleanup. In this study, we investigated the photodegradation of crystal-violet (CV) dye when exposed to UV light using a newly developed photocatalyst known as Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO nanocomposite-decorated CsPbI<sub>3</sub> perovskite, which was synthesized through a hydrothermal method. Our research investigation into the structural, morphological, and optical characteristics of the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite using techniques such as FTIR, XRD, TEM, SEM–EDS mapping, XPS, UV–Vis, and PL spectroscopy. The photocatalytic efficacy of the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite was assessed by evaluating its ability to degrade CV dye in an aqueous solution under UV-light irradiation. Remarkably, the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite displayed a significant improvement in both the degradation rate and stability of CV dye when compared to the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO nanocomposite and CsPbI<sub>3</sub> perovskite materials. Furthermore, the UV–visible absorption spectrum of the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite demonstrated a reduced band gap of 2.41 eV, which is lower than that of Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO (3.10 eV) and Ti<sub>3</sub>C<sub>2</sub>-MXene (1.60 eV). In practical terms, the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite achieved an impressive 92.8% degradation of CV dye within 90 min of UV light exposure. We also confirmed the significant role of photogenerated holes and radicals in the CV dye removal process through radical scavenger trapping experiments. Based on our findings, we proposed a plausible photocatalytic mechanism for the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite. This research may open up new avenues for the development of cost-effective and high-performance MXene-based perovskite photocatalysts, utilizing abundant and sustainable materials for environmental remediation. |
| first_indexed | 2024-03-09T01:46:11Z |
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| institution | Directory Open Access Journal |
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| language | English |
| last_indexed | 2024-03-09T01:46:11Z |
| publishDate | 2023-11-01 |
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| series | Nanomaterials |
| spelling | doaj.art-9a3325fd316f492a8d89ea76642853632023-12-08T15:22:56ZengMDPI AGNanomaterials2079-49912023-11-011323302610.3390/nano13233026Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO Nanocomposites-Decorated CsPbI<sub>3</sub> Perovskite Active Materials under UV-Light Irradiation for the Enhancement of Crystal-Violet Dye PhotodegradationAsma A. Alothman0Mohammad Rizwan Khan1Munirah D. Albaqami2Sonaimuthu Mohandoss3Zeid A. Alothman4Naushad Ahmad5Khadraa N. Alqahtani6Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaSchool of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of KoreaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaTi<sub>3</sub>C<sub>2</sub>-MXene material, known for its strong electronic conductivity and optical properties, has emerged as a promising alternative to noble metals as a cocatalyst for the development of efficient photocatalysts used in environmental cleanup. In this study, we investigated the photodegradation of crystal-violet (CV) dye when exposed to UV light using a newly developed photocatalyst known as Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO nanocomposite-decorated CsPbI<sub>3</sub> perovskite, which was synthesized through a hydrothermal method. Our research investigation into the structural, morphological, and optical characteristics of the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite using techniques such as FTIR, XRD, TEM, SEM–EDS mapping, XPS, UV–Vis, and PL spectroscopy. The photocatalytic efficacy of the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite was assessed by evaluating its ability to degrade CV dye in an aqueous solution under UV-light irradiation. Remarkably, the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite displayed a significant improvement in both the degradation rate and stability of CV dye when compared to the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO nanocomposite and CsPbI<sub>3</sub> perovskite materials. Furthermore, the UV–visible absorption spectrum of the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite demonstrated a reduced band gap of 2.41 eV, which is lower than that of Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO (3.10 eV) and Ti<sub>3</sub>C<sub>2</sub>-MXene (1.60 eV). In practical terms, the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite achieved an impressive 92.8% degradation of CV dye within 90 min of UV light exposure. We also confirmed the significant role of photogenerated holes and radicals in the CV dye removal process through radical scavenger trapping experiments. Based on our findings, we proposed a plausible photocatalytic mechanism for the Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO/CsPbI<sub>3</sub> composite. This research may open up new avenues for the development of cost-effective and high-performance MXene-based perovskite photocatalysts, utilizing abundant and sustainable materials for environmental remediation.https://www.mdpi.com/2079-4991/13/23/3026Ti<sub>3</sub>C<sub>2</sub>-MXeneNiOperovskitecrystal violetUV-light irradiationphotodegradation |
| spellingShingle | Asma A. Alothman Mohammad Rizwan Khan Munirah D. Albaqami Sonaimuthu Mohandoss Zeid A. Alothman Naushad Ahmad Khadraa N. Alqahtani Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO Nanocomposites-Decorated CsPbI<sub>3</sub> Perovskite Active Materials under UV-Light Irradiation for the Enhancement of Crystal-Violet Dye Photodegradation Nanomaterials Ti<sub>3</sub>C<sub>2</sub>-MXene NiO perovskite crystal violet UV-light irradiation photodegradation |
| title | Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO Nanocomposites-Decorated CsPbI<sub>3</sub> Perovskite Active Materials under UV-Light Irradiation for the Enhancement of Crystal-Violet Dye Photodegradation |
| title_full | Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO Nanocomposites-Decorated CsPbI<sub>3</sub> Perovskite Active Materials under UV-Light Irradiation for the Enhancement of Crystal-Violet Dye Photodegradation |
| title_fullStr | Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO Nanocomposites-Decorated CsPbI<sub>3</sub> Perovskite Active Materials under UV-Light Irradiation for the Enhancement of Crystal-Violet Dye Photodegradation |
| title_full_unstemmed | Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO Nanocomposites-Decorated CsPbI<sub>3</sub> Perovskite Active Materials under UV-Light Irradiation for the Enhancement of Crystal-Violet Dye Photodegradation |
| title_short | Ti<sub>3</sub>C<sub>2</sub>-MXene/NiO Nanocomposites-Decorated CsPbI<sub>3</sub> Perovskite Active Materials under UV-Light Irradiation for the Enhancement of Crystal-Violet Dye Photodegradation |
| title_sort | ti sub 3 sub c sub 2 sub mxene nio nanocomposites decorated cspbi sub 3 sub perovskite active materials under uv light irradiation for the enhancement of crystal violet dye photodegradation |
| topic | Ti<sub>3</sub>C<sub>2</sub>-MXene NiO perovskite crystal violet UV-light irradiation photodegradation |
| url | https://www.mdpi.com/2079-4991/13/23/3026 |
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