Long-Term Testing of WC–Ni–Fe Coating as an Inert Anode in a Low-Temperature Electrolyte for Aluminum Production

The behaviour of WC-Ni-Fe coating on 2Cr13 and X3CrNiMo18-12-3 stainless steel substrates was investigated in the context of their application as inert anode materials in a low-temperature (850 °C) electrolyte (50 wt.% AlF3-45 wt.% KF-5 wt.% Al2O3) by long-term testing around 50 h for aluminum produ...

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Main Authors: Chuhua LIU, Yudong WANG, Bin YANG, Yongnian DAI
Format: Article
Language:English
Published: Kaunas University of Technology 2019-12-01
Series:Medžiagotyra
Subjects:
Online Access:http://matsc.ktu.lt/index.php/MatSc/article/view/21574
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author Chuhua LIU
Yudong WANG
Bin YANG
Yongnian DAI
author_facet Chuhua LIU
Yudong WANG
Bin YANG
Yongnian DAI
author_sort Chuhua LIU
collection DOAJ
description The behaviour of WC-Ni-Fe coating on 2Cr13 and X3CrNiMo18-12-3 stainless steel substrates was investigated in the context of their application as inert anode materials in a low-temperature (850 °C) electrolyte (50 wt.% AlF3-45 wt.% KF-5 wt.% Al2O3) by long-term testing around 50 h for aluminum production. The results show that the materials were corroded in a controlled manner and the extrapolated corrosion rates of WC–Ni–Fe/X3CrNiMo18-12-3 anode was 5.8 cm per year, which is acceptable from an industrial perspective. The total contamination level of anode constituents in the deposited metal was as low as 0.283 wt.%. These encouraging results seemed to be related in part to the X3CrNiMo18-12-3 substrate that allows only very slow penetration of oxygen atoms into the inner part. Post-electrolysis examination of the anodes indicates that the substrate material is one of the most important factors that determine the erosion resistance of coating inert anode. The results of electrolysis using 2Cr13 and X3CrNiMo18-12-3 substrates indicate that the electrical current is another important factor for the erosion resistance of inert anode coatings.
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spelling doaj.art-9a50ed696d3344989046fb1fcf0e9ab02022-12-22T01:23:18ZengKaunas University of TechnologyMedžiagotyra1392-13202029-72892019-12-0126217918410.5755/j01.ms.26.2.2157421574Long-Term Testing of WC–Ni–Fe Coating as an Inert Anode in a Low-Temperature Electrolyte for Aluminum ProductionChuhua LIUYudong WANGBin YANGYongnian DAIThe behaviour of WC-Ni-Fe coating on 2Cr13 and X3CrNiMo18-12-3 stainless steel substrates was investigated in the context of their application as inert anode materials in a low-temperature (850 °C) electrolyte (50 wt.% AlF3-45 wt.% KF-5 wt.% Al2O3) by long-term testing around 50 h for aluminum production. The results show that the materials were corroded in a controlled manner and the extrapolated corrosion rates of WC–Ni–Fe/X3CrNiMo18-12-3 anode was 5.8 cm per year, which is acceptable from an industrial perspective. The total contamination level of anode constituents in the deposited metal was as low as 0.283 wt.%. These encouraging results seemed to be related in part to the X3CrNiMo18-12-3 substrate that allows only very slow penetration of oxygen atoms into the inner part. Post-electrolysis examination of the anodes indicates that the substrate material is one of the most important factors that determine the erosion resistance of coating inert anode. The results of electrolysis using 2Cr13 and X3CrNiMo18-12-3 substrates indicate that the electrical current is another important factor for the erosion resistance of inert anode coatings.http://matsc.ktu.lt/index.php/MatSc/article/view/21574carbideceramicscoatingscorrosionoxidationelectrical conductivity
spellingShingle Chuhua LIU
Yudong WANG
Bin YANG
Yongnian DAI
Long-Term Testing of WC–Ni–Fe Coating as an Inert Anode in a Low-Temperature Electrolyte for Aluminum Production
Medžiagotyra
carbide
ceramics
coatings
corrosion
oxidation
electrical conductivity
title Long-Term Testing of WC–Ni–Fe Coating as an Inert Anode in a Low-Temperature Electrolyte for Aluminum Production
title_full Long-Term Testing of WC–Ni–Fe Coating as an Inert Anode in a Low-Temperature Electrolyte for Aluminum Production
title_fullStr Long-Term Testing of WC–Ni–Fe Coating as an Inert Anode in a Low-Temperature Electrolyte for Aluminum Production
title_full_unstemmed Long-Term Testing of WC–Ni–Fe Coating as an Inert Anode in a Low-Temperature Electrolyte for Aluminum Production
title_short Long-Term Testing of WC–Ni–Fe Coating as an Inert Anode in a Low-Temperature Electrolyte for Aluminum Production
title_sort long term testing of wc ni fe coating as an inert anode in a low temperature electrolyte for aluminum production
topic carbide
ceramics
coatings
corrosion
oxidation
electrical conductivity
url http://matsc.ktu.lt/index.php/MatSc/article/view/21574
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AT yudongwang longtermtestingofwcnifecoatingasaninertanodeinalowtemperatureelectrolyteforaluminumproduction
AT binyang longtermtestingofwcnifecoatingasaninertanodeinalowtemperatureelectrolyteforaluminumproduction
AT yongniandai longtermtestingofwcnifecoatingasaninertanodeinalowtemperatureelectrolyteforaluminumproduction