Bis(4,6-dimethylpyrimidine-2-thiolato)dimethyltin(IV)
The asymmetric unit of the title complex, [Sn(CH3)2(C6H7N2S)2], contains two independent molecules with similar configurations. In each, the SnIV cation is coordinated by two methyl and two 4,6-dimethylpyrimidine-2-thiolate anions in a distorted SnS2C2 tetrahedral geometry. In the two molecules, the...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810030412 |
| Summary: | The asymmetric unit of the title complex, [Sn(CH3)2(C6H7N2S)2], contains two independent molecules with similar configurations. In each, the SnIV cation is coordinated by two methyl and two 4,6-dimethylpyrimidine-2-thiolate anions in a distorted SnS2C2 tetrahedral geometry. In the two molecules, the S—Sn—S bond angles are 87.70 (5) and 88.93 (4)°, while the C—Sn—C bond angles are 125.7 (3) and 125.9 (2)°. Weak C—H...N hydrogen bonding is present in the crystal structure. |
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| ISSN: | 1600-5368 |