Bis(4,6-dimethylpyrimidine-2-thiolato)dimethyltin(IV)
The asymmetric unit of the title complex, [Sn(CH3)2(C6H7N2S)2], contains two independent molecules with similar configurations. In each, the SnIV cation is coordinated by two methyl and two 4,6-dimethylpyrimidine-2-thiolate anions in a distorted SnS2C2 tetrahedral geometry. In the two molecules, the...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-09-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810030412 |
| _version_ | 1818938058226008064 |
|---|---|
| author | Yang Shi Ru-Fen Zhang Chun-Lin Ma |
| author_facet | Yang Shi Ru-Fen Zhang Chun-Lin Ma |
| author_sort | Yang Shi |
| collection | DOAJ |
| description | The asymmetric unit of the title complex, [Sn(CH3)2(C6H7N2S)2], contains two independent molecules with similar configurations. In each, the SnIV cation is coordinated by two methyl and two 4,6-dimethylpyrimidine-2-thiolate anions in a distorted SnS2C2 tetrahedral geometry. In the two molecules, the S—Sn—S bond angles are 87.70 (5) and 88.93 (4)°, while the C—Sn—C bond angles are 125.7 (3) and 125.9 (2)°. Weak C—H...N hydrogen bonding is present in the crystal structure. |
| first_indexed | 2024-12-20T06:01:49Z |
| format | Article |
| id | doaj.art-9a563b87d1f44a96b08c3fcefa753c82 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T06:01:49Z |
| publishDate | 2010-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9a563b87d1f44a96b08c3fcefa753c822022-12-21T19:50:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1174m117410.1107/S1600536810030412Bis(4,6-dimethylpyrimidine-2-thiolato)dimethyltin(IV)Yang ShiRu-Fen ZhangChun-Lin MaThe asymmetric unit of the title complex, [Sn(CH3)2(C6H7N2S)2], contains two independent molecules with similar configurations. In each, the SnIV cation is coordinated by two methyl and two 4,6-dimethylpyrimidine-2-thiolate anions in a distorted SnS2C2 tetrahedral geometry. In the two molecules, the S—Sn—S bond angles are 87.70 (5) and 88.93 (4)°, while the C—Sn—C bond angles are 125.7 (3) and 125.9 (2)°. Weak C—H...N hydrogen bonding is present in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536810030412 |
| spellingShingle | Yang Shi Ru-Fen Zhang Chun-Lin Ma Bis(4,6-dimethylpyrimidine-2-thiolato)dimethyltin(IV) Acta Crystallographica Section E |
| title | Bis(4,6-dimethylpyrimidine-2-thiolato)dimethyltin(IV) |
| title_full | Bis(4,6-dimethylpyrimidine-2-thiolato)dimethyltin(IV) |
| title_fullStr | Bis(4,6-dimethylpyrimidine-2-thiolato)dimethyltin(IV) |
| title_full_unstemmed | Bis(4,6-dimethylpyrimidine-2-thiolato)dimethyltin(IV) |
| title_short | Bis(4,6-dimethylpyrimidine-2-thiolato)dimethyltin(IV) |
| title_sort | bis 4 6 dimethylpyrimidine 2 thiolato dimethyltin iv |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810030412 |
| work_keys_str_mv | AT yangshi bis46dimethylpyrimidine2thiolatodimethyltiniv AT rufenzhang bis46dimethylpyrimidine2thiolatodimethyltiniv AT chunlinma bis46dimethylpyrimidine2thiolatodimethyltiniv |