An effective, recyclable, eco-friendly 3-(2-aminoethyl)-1-methyl-1H-imidazol-3-ium bromide [Aemim]Br: Solvent, base free synthesis of carbonyl compound catalyst by FeCl3/TEMPO
We first report a novel solvent, base free synthesis of carbonyl compound catalyst by FeCl3/TEMPO at 40 °C with high-rate. In this article, we examine the mechanism of this catalytic system and compare the reactivity of aromatic alcohols. Furthermore, the efficacy of 3-(2-aminoethyl)-1-methyl-1H-imi...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2024-06-01
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| Series: | Journal of Ionic Liquids |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2772422023000253 |
| _version_ | 1797450928875372544 |
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| author | Sakthinarayanan Jayaraman Selvarasu Uthayanila Kasi Venkatesan Ramasamy ShanmugaPriya Parasuraman Karthikeyan |
| author_facet | Sakthinarayanan Jayaraman Selvarasu Uthayanila Kasi Venkatesan Ramasamy ShanmugaPriya Parasuraman Karthikeyan |
| author_sort | Sakthinarayanan Jayaraman |
| collection | DOAJ |
| description | We first report a novel solvent, base free synthesis of carbonyl compound catalyst by FeCl3/TEMPO at 40 °C with high-rate. In this article, we examine the mechanism of this catalytic system and compare the reactivity of aromatic alcohols. Furthermore, the efficacy of 3-(2-aminoethyl)-1-methyl-1H-imidazol-3-ium bromide [Aemim]Br could be maintained after seven recycling cycles. High catalyst productivity and reaction rate (5.53 to 22.50) have been accomplished with the use of an enhanced procedure. |
| first_indexed | 2024-03-09T14:46:39Z |
| format | Article |
| id | doaj.art-9a5995ae66bc4887a720773cfb17aa55 |
| institution | Directory Open Access Journal |
| issn | 2772-4220 |
| language | English |
| last_indexed | 2024-03-09T14:46:39Z |
| publishDate | 2024-06-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Ionic Liquids |
| spelling | doaj.art-9a5995ae66bc4887a720773cfb17aa552023-11-27T04:15:18ZengElsevierJournal of Ionic Liquids2772-42202024-06-0141100073An effective, recyclable, eco-friendly 3-(2-aminoethyl)-1-methyl-1H-imidazol-3-ium bromide [Aemim]Br: Solvent, base free synthesis of carbonyl compound catalyst by FeCl3/TEMPOSakthinarayanan Jayaraman0Selvarasu Uthayanila1Kasi Venkatesan2Ramasamy ShanmugaPriya3Parasuraman Karthikeyan4PG and Research Department of Chemistry, Pachaiyappas College Campus, University of Madras Chennai, Tamil Nadu 600 030, IndiaDepartment of Chemistry, Pachaiyappas College for Women Campus, University of Madras, Kanchipuram, Tamil Nadu 631501, IndiaDepartment of Humanities and Sciences, CVR College of Engineering, Telangana 501510 IndiaDepartment of Chemistry, Dhanalakshmi Srinivasan College of Arts and Science for Women, Perambalur, Tamil Nadu 621 212, IndiaPG and Research Department of Chemistry, Pachaiyappas College Campus, University of Madras Chennai, Tamil Nadu 600 030, India; Corresponding author.We first report a novel solvent, base free synthesis of carbonyl compound catalyst by FeCl3/TEMPO at 40 °C with high-rate. In this article, we examine the mechanism of this catalytic system and compare the reactivity of aromatic alcohols. Furthermore, the efficacy of 3-(2-aminoethyl)-1-methyl-1H-imidazol-3-ium bromide [Aemim]Br could be maintained after seven recycling cycles. High catalyst productivity and reaction rate (5.53 to 22.50) have been accomplished with the use of an enhanced procedure.http://www.sciencedirect.com/science/article/pii/S2772422023000253Ionic liquidOxidationAlcoholEco-friendly |
| spellingShingle | Sakthinarayanan Jayaraman Selvarasu Uthayanila Kasi Venkatesan Ramasamy ShanmugaPriya Parasuraman Karthikeyan An effective, recyclable, eco-friendly 3-(2-aminoethyl)-1-methyl-1H-imidazol-3-ium bromide [Aemim]Br: Solvent, base free synthesis of carbonyl compound catalyst by FeCl3/TEMPO Journal of Ionic Liquids Ionic liquid Oxidation Alcohol Eco-friendly |
| title | An effective, recyclable, eco-friendly 3-(2-aminoethyl)-1-methyl-1H-imidazol-3-ium bromide [Aemim]Br: Solvent, base free synthesis of carbonyl compound catalyst by FeCl3/TEMPO |
| title_full | An effective, recyclable, eco-friendly 3-(2-aminoethyl)-1-methyl-1H-imidazol-3-ium bromide [Aemim]Br: Solvent, base free synthesis of carbonyl compound catalyst by FeCl3/TEMPO |
| title_fullStr | An effective, recyclable, eco-friendly 3-(2-aminoethyl)-1-methyl-1H-imidazol-3-ium bromide [Aemim]Br: Solvent, base free synthesis of carbonyl compound catalyst by FeCl3/TEMPO |
| title_full_unstemmed | An effective, recyclable, eco-friendly 3-(2-aminoethyl)-1-methyl-1H-imidazol-3-ium bromide [Aemim]Br: Solvent, base free synthesis of carbonyl compound catalyst by FeCl3/TEMPO |
| title_short | An effective, recyclable, eco-friendly 3-(2-aminoethyl)-1-methyl-1H-imidazol-3-ium bromide [Aemim]Br: Solvent, base free synthesis of carbonyl compound catalyst by FeCl3/TEMPO |
| title_sort | effective recyclable eco friendly 3 2 aminoethyl 1 methyl 1h imidazol 3 ium bromide aemim br solvent base free synthesis of carbonyl compound catalyst by fecl3 tempo |
| topic | Ionic liquid Oxidation Alcohol Eco-friendly |
| url | http://www.sciencedirect.com/science/article/pii/S2772422023000253 |
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