Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-Benzoquinone
A reactivity difference based on the position of substituents on cyclohexa-1,3- diene was observed for the title reaction. The effect of water as solvent was more distinct for 1-methyl-4-isopropylcyclohexa-1,3-diene than for 2-methyl-5-isopropylcyclohexa- 1,3-diene or non-substituted cyclohexa-1,3-d...
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| Format: | Article |
| Language: | English |
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MDPI AG
2005-01-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/10/1/244/ |
| _version_ | 1818017772413648896 |
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| author | Chiaki Kuroda Takeshi Sunakawa |
| author_facet | Chiaki Kuroda Takeshi Sunakawa |
| author_sort | Chiaki Kuroda |
| collection | DOAJ |
| description | A reactivity difference based on the position of substituents on cyclohexa-1,3- diene was observed for the title reaction. The effect of water as solvent was more distinct for 1-methyl-4-isopropylcyclohexa-1,3-diene than for 2-methyl-5-isopropylcyclohexa- 1,3-diene or non-substituted cyclohexa-1,3-diene. The effect of NaCl (salting-out) and guanidium chloride (salting-in) was also large for 1-methyl-4-isopropylcyclohexa-1,3- diene. |
| first_indexed | 2024-04-14T07:31:17Z |
| format | Article |
| id | doaj.art-9a7c92dd86674641aa54f9434752e4ae |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-04-14T07:31:17Z |
| publishDate | 2005-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-9a7c92dd86674641aa54f9434752e4ae2022-12-22T02:05:52ZengMDPI AGMolecules1420-30492005-01-0110124425010.3390/10010244Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-BenzoquinoneChiaki KurodaTakeshi SunakawaA reactivity difference based on the position of substituents on cyclohexa-1,3- diene was observed for the title reaction. The effect of water as solvent was more distinct for 1-methyl-4-isopropylcyclohexa-1,3-diene than for 2-methyl-5-isopropylcyclohexa- 1,3-diene or non-substituted cyclohexa-1,3-diene. The effect of NaCl (salting-out) and guanidium chloride (salting-in) was also large for 1-methyl-4-isopropylcyclohexa-1,3- diene.http://www.mdpi.com/1420-3049/10/1/244/Diels-Alder reactionaqueouscyclohexadienesubstrate dependence |
| spellingShingle | Chiaki Kuroda Takeshi Sunakawa Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-Benzoquinone Molecules Diels-Alder reaction aqueous cyclohexadiene substrate dependence |
| title | Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-Benzoquinone |
| title_full | Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-Benzoquinone |
| title_fullStr | Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-Benzoquinone |
| title_full_unstemmed | Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-Benzoquinone |
| title_short | Substrate Dependence in Aqueous Diels-Alder Reactions of Cyclohexadiene Derivatives with 1,4-Benzoquinone |
| title_sort | substrate dependence in aqueous diels alder reactions of cyclohexadiene derivatives with 1 4 benzoquinone |
| topic | Diels-Alder reaction aqueous cyclohexadiene substrate dependence |
| url | http://www.mdpi.com/1420-3049/10/1/244/ |
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